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Effect of oxygen annealing on the electrical properties ofLa1−xSrxMnO3+δsingle crystals around the compositional metal-insulator transition

R. Shiozaki、K. Takenaka、Y. SAWAKI 等 4 位作者2001-04-18Physical review. B, Condensed matter

We have prepared ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3+\ensuremath{\delta}}$ single crystals for not only oxygen-deficient $(\ensuremath{\delta}<0)$ but also oxygen-excess $(\ensuremath{\delta}>0)$ regions. Although resistivity $\ensuremath{\rho}(T)$ is less sensitive to $\ensuremat…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Cyano-Bridged Aqua(N,N-Dimethylacetamide)(cyanoiron)lanthanides from Samarium, Gadolinium, or Holmium Nitrate and Potassium Hexacyanoferrate: Crystal Structures and Magnetochemistry

Bing Yan、Zhida Chen2001-04-18Helvetica Chimica Acta

Three cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanide complexes were synthesized by the reaction of K3Fe(CN)6, Ln(NO3)3⋅6 H2O (Ln=Sm, Gd, Ho), and N,N-dimethylacetamide (DMA). The obtained complexes 1 – 3 exhibit different coordination geometries and crystal structures. The polymeric {[Sm(DMA)2(H2O)4Fe(…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Sorption and transport of linear alkane hydrocarbons in biaxially oriented polyethylene terephthalate

Sushil N. Dhoot、Benny D. Freeman、Mark Stewart 等 4 位作者2001-04-18Journal of Polymer Science Part B Polymer Physics

Abstract Equilibrium sorption and uptake kinetics of n ‐butane and n ‐pentane in uniform, biaxially oriented, semicrystalline polyethylene terephthalate films were examined at 35 °C and for pressures ranging from 0 to approximately 76 cmHg. Sorption isotherms were well described by the dual‐mode sorption model. Sorpti…

Polymer crystallization and propertiesMembrane Separation and Gas TransportMuon and positron interactions and applications

Effects of mixing time on phase structure and mechanical properties of poly(ethylene terephthalate)/ polycarbonate blends

María Concepción García、J. I. Eguiazábal、J. Nazábal2001-04-18Journal of Applied Polymer Science

Abstract The effects of interchange reactions on the solid‐state structure and mechanical properties of a 70/30 poly(ethylene terephthalate) (PET)/bisphenol A polycarbonate (PC) blend were studied. Increasing reaction levels were obtained by means of lower screw speeds in the extruder. The progressive production of co…

Polymer crystallization and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Infrared study of charge delocalization induced by pressure in theLa0.75Ca0.25MnO3manganite

A. Congeduti、P. Postorino、P. Dore 等 9 位作者2001-04-18Physical review. B, Condensed matter

We measured the pressure dependence of the room-temperature infrared absorption spectrum of the pseudocubic ${\mathrm{La}}_{0.75}{\mathrm{Ca}}_{0.25}{\mathrm{MnO}}_{3}$ manganite. On increasing pressure up to 10 Gpa we observe the increase of a broad band associated with polaronic absorption, which partially screens t…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Phase Separation in AlxGa1-xAs Nanowhiskers Grown by the Solution−Liquid−Solid Mechanism

Paul D. Markowitz、Michael Zäch、P. C. Gibbons 等 5 位作者2001-04-18Journal of the American Chemical Society

Low-temperature growth of AlxGa1-xAs by the solution-liquid-solid mechanism affords nanowhiskers having two specific overall compositions: x = 0.1 and 0.8. Intermediate compositions (0.1 < x < 0.8) are inaccessible by the method employed. Examination of the nanowhiskers by transmission electron microscopy, photolumine…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Preparation and physical properties of N‐defunctionalized derivatives of poly(aspartic acid)

Alan R. Katritzky、Jiangchao Yao、Ming Qi 等 9 位作者2001-04-18Journal of Applied Polymer Science

Abstract A number of N ‐substituted poly(aspartic acid)s was prepared under mild conditions using the silylation–alkylation technique. Their physical properties were studied. Free swelling capacity (FSC) tests were performed for polymers obtained by crosslinking the parent poly(aspartic acid) as well as its defunction…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesAntimicrobial agents and applications

Influence of rubber composition on migration behaviors of antiozonants in carbon black‐filled rubber vulcanizates composed of NR, SBR, and BR

Sung‐Seen Choi2001-04-18Journal of Applied Polymer Science

Abstract Migration behaviors of antiozonants in carbon black‐filled rubber vulcanizates with different rubber compositions of natural rubber (NR), styrene–butadiene rubber (SBR), and butadiene rubber (BR) were studied at constant temperatures of 40–100°C and outdoors. Three single rubber‐based vulcanizates, three bibl…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Interlayer coupling and magnetoresistance of MnGa-based trilayers with semiconducting, antiferromagnetic, and ferrimagnetic spacer layers

W. Van Roy、Hiroyuki Akinaga、S. Miyanishi2001-04-18Physical review. B, Condensed matter

We have studied the influence of the magnetic structure of the spacer layer on the interlayer exchange coupling and on the correlation between the coupling and magnetoresistance in MnGa-based trilayers with antiferromagnetic $({\mathrm{Mn}}_{2}\mathrm{As}),$ ferrimagnetic $({\mathrm{Mn}}_{2}\mathrm{Sb}),$ and semicond…

Physics of Superconductivity and MagnetismMagnetic properties of thin filmsZnO doping and properties

Conductivity improvement of Li-Co-Yb ferrite

M.A. Ahmed、Samiha T. Bishay2001-04-18Journal of Physics D Applied Physics

The effect of γ-irradiation on some physical properties of rare earth ferrite of the general formula Li 0.5 + z Co z Yb x Fe 2.5-2 z - x O 4 , ( z = 0.1, x = 0.00, 0.025, 0.050,...,0.200) was discussed. The temperature dependence of the polarization and resistance was studied in the range (300 K⩽ T ⩽700 K) at differen…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsMagneto-Optical Properties and Applications

An investigation of water crosslinking reactions of silane‐grafted LDPE

Yeong‐Tarng Shieh、Jia‐Sheng Liau、Tzung‐Kai Chen2001-04-18Journal of Applied Polymer Science

Abstract Factors—including time, temperature, morphology, and thickness of sample, the extent of silane grafting, and water concentration—that affect the rate and degree of water crosslinking reactions of the silane‐grafted LDPE are investigated. The gel content of the water‐crosslinked sample increases with increasin…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Effect of Nonionic Surfactants on the Kinetics of Disproportion of Copper Sulfide Nanoparticles in the Aqueous Sols

Roshan H. Kore、Jaideep S. Kulkarni、Santosh K. Haram2001-04-18Chemistry of Materials

The effect of nonionic surfactants on the disproportion kinetics of copper sulfide nanoparticles (aqueous sols) from the golden brown, copper-rich phase (Q-Cu 2 S) to the green covellite phase (Q-CuS) has been presented. The transformation follows a first-order rate law. There is a substantial decrease in the rate of…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Crystal Structure of the Lytic Transglycosylase from Bacteriophage Lambda in Complex with Hexa-N-acetylchitohexaose,

Adelaine Kwun-Wai Leung、Henry S. Duewel、John F. Honek 等 4 位作者2001-04-18Biochemistry

The three-dimensional structure of the lytic transglycosylase from bacteriophage lambda, also known as bacteriophage lambda lysozyme, complexed to the hexasaccharide inhibitor, hexa-N-acetylchitohexaose, has been determined by X-ray crystallography at 2.6 A resolution. The unit cell contains two molecules of the lytic…

Protein Structure and DynamicsBacteriophages and microbial interactionsEnzyme Structure and Function

Cure and mechanical properties of filled SMR L/ENR 25 and SMR L/SBR blends

B. T. Poh、H. Ismail、E. H. Quah 等 4 位作者2001-04-18Journal of Applied Polymer Science

Abstract The effect of blend ratio of natural rubber/epoxidized natural rubber (SMR L/ENR 25) and natural rubber/styrene‐butadiene rubber (SMR L/SBR) blends on scorch time ( t 2 ), cure time ( t 90 ), resilience, hardness, and fatigue properties were studied in the presence of carbon black and silica. An accelerated s…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Measurement and simulation of electrical tree growth and partial discharge activity in epoxy resin

М. Д. Носков、M. Sack、A. Malinovski 等 4 位作者2001-04-18Journal of Physics D Applied Physics

Electrical treeing in an epoxy resin under an ac voltage for a point-to-plane gap configuration has been investigated using a phase-resolved partial discharge measurement system and shadow survey and light emission registration techniques. A self-consistent model based on the concepts of energy and electric field has…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Dielectric properties and phase transitions of[Pb(Zn1/3Nb2/3)O3]0.905(PbTiO3)0.095:Influence of pressure

G. A. Samara、E. L. Venturini、V. Hugo Schmidt2001-04-18Physical review. B, Condensed matter

Studies of the influences of temperature, hydrostatic pressure, dc biasing field, and frequency on the dielectric constant $({\ensuremath{\varepsilon}}^{\ensuremath{'}})$ and loss $(\mathrm{tan}\ensuremath{\delta})$ of single crystal ${[\mathrm{P}\mathrm{b}(\mathrm{Z}\mathrm{n}}_{1/3}{\mathrm{Nb}}_{2/3}{)\mathrm{O}}_{…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

4 Dispersive kinetics

Andrzej Płonka2001-04-18Annual Reports Section C (Physical Chemistry)

The first page of this article is displayed as the abstract.

Material Dynamics and PropertiesPhotochemistry and Electron Transfer StudiesQuantum Electrodynamics and Casimir Effect

Rheological behavior and processability of polypropylene blends with rubber ethylene propylene diene terpolymer

Miguel A. López‐Manchado、J. Biagiotti、J. M. Kenny2001-04-18Journal of Applied Polymer Science

Abstract A study of the dynamic complex and steady shear viscosity of isotactic polypropylene (iPP), ethylene–propylene diene terpolymer rubber (EPDM) and three different blends of both polymers are presented over a range of temperatures and frequencies. Moreover, the processability of these materials is studied throu…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Density functional study of the Σ3 (111) [1bar10] symmetrical tilt grain boundary in SrTiO3

Susanne Hutt、Sibylle Köstlmeier、Christian Elsässer2001-04-18Journal of Physics Condensed Matter

Density functional supercell calculations were carried out by a mixed-basis pseudopotential method for the Σ3 (111) [1 0] symmetrical tilt grain boundary in strontium titanate, SrTiO 3 , as a prototype planar defect in an electro-ceramic material. A low grain boundary energy of 0.52 J m -2 was obtained. Minor structur…

Physics of Superconductivity and MagnetismElectronic and Structural Properties of OxidesSurface and Thin Film Phenomena

Enzyme‐catalyzed transesterification of vinyl esters on cellulose solids

Jiangbing Xie、You‐Lo Hsieh2001-04-18Journal of Polymer Science Part A Polymer Chemistry

Abstract Enzyme‐catalyzed transesterification of several cellulose solids in organic media have been investigated. Several protease enzymes were made soluble in organic media through ion‐paired enzyme–surfactant complexes. Subtilisin Carsberg was found to be catalytically active in the transesterification of cellulose…

Enzyme Catalysis and ImmobilizationAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties