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Deformation mechanism of nanoporous materials upon water freezing and melting

Maxim Erko、Dirk Wallacher、Oskar Paris2012-10-29Applied Physics Letters

Temperature-induced non-monotonous reversible deformation of water-filled nanoporous silica materials is investigated experimentally using in-situ small-angle x-ray scattering. The influence of freezing and melting in the nanopores on this deformation is treated quantitatively by introducing a simple model based on th…

Mesoporous Materials and CatalysisAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Positive colossal magnetoresistance observed in Co doped amorphous carbon/silicon heterostructures

Yucheng Jiang、Ju Gao2012-10-29Applied Physics Letters

Heterostructures of Co-doped amorphous carbon (Co-C)/silicon were fabricated by growing Co-C films on n-type Si substrates using pulsed laser deposition. The heterostructures exhibited a positive colossal magnetoresistance (CMR) effect over a temperature range of 55-240 K. The magnetoresistance (MR) for the reverse bi…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchMagnetic and transport properties of perovskites and related materials

Enhancing interfacial adhesion performance by using poly(vinyl alcohol) in (low‐density polyethylene)/(natural rubber)/(water hyacinth fiber) composites

A.G. Supri、Sin Jin Tan、H. Ismail 等 4 位作者2012-10-29Journal of Vinyl and Additive Technology

The effects of (a) the chemical modification of water hyacinth fiber by poly(vinyl alcohol) (WHF‐ PVA ) and (b) loading on the properties of low‐density polyethylene (LDPE)/(natural rubber (NR))/(water hyacinth fiber (WHF)) composites were studied. Mechanical properties, water absorption behavior, morphology, and ther…

Natural Fiber Reinforced CompositesFiber-reinforced polymer compositesMaterial Properties and Processing

HFCVD growth of various carbon nanostructures on SWCNT paper controlled by surface treatment

M. Varga、Mário Kotlár、Viliam Vretenár 等 9 位作者2012-10-29physica status solidi (b)

Abstract In this article, we investigate the nanocomposite material formation, particularly the deposition of nanocrystalline diamond and carbon nanowalls (CNWs) on single‐wall carbon nanotubes buckypaper (BP). One part of the buckypaper substrate was nucleated by nanodiamond powder. The growth was carried out in a ho…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Potential solvent for reconditioning polyolefin waste materials

Arkan J. Hadi、Ghazi Faisal Najmuldeen、Iqbal Ahmed2012-10-29Journal of Polymer Engineering

Abstract Waste polymer reconditioning was examined by a method of dissolution/reprecipitation on low- and high-density polyethylene (PE) and polypropylene (PP). Toluene and petroleum ether, in different proportions, were used as solvents, and n-hexane was used as a non-solvent. Commercial polymer products used on an e…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Affine development of closed curves in Weitzenböck manifolds and the Burgers vector of dislocation mechanics

Arkadaş Özakın、Arash Yavari2012-10-29Mathematics and Mechanics of Solids

In the theory of dislocations, the Burgers vector is usually defined by referring to a crystal structure. Using the notion of affine development of curves on a differential manifold with a connection, we give a differential geometric definition of the Burgers vector directly in the continuum setting, without making us…

Microstructure and mechanical propertiesElasticity and Material ModelingNonlocal and gradient elasticity in micro/nano structures

The Synthesis of Organometallic Coordination Polymer Flowers of Prussian Blue with Ultrathin Petals by Using Crystallization‐Assisted Interface Coordination Polymerization (CAICP)

Suping Bao、Tingting Liu、Guodong Liang 等 6 位作者2012-10-29Chemistry - A European Journal

Tiny flowers: A conceptually new method for fabricating polymer/Prussian blue (PB) hybrid flowers with ultrathin petals by using a CAICP technique has been developed. The PB hybrid flowers exhibit enhanced thermal stability, emit deep-blue light, and are electrochemically active. Their intriguing microstructure and en…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsPolyoxometalates: Synthesis and Applications

The design, synthesis, and nonlinear optical properties of novel X‐type polyurethane containing dicyanovinylnitroresorcinoxy group with enhanced SHG thermal stability

Mi Young Song、Byeongman Jeon、Hak Jin Kim 等 4 位作者2012-10-29Journal of Polymer Science Part A Polymer Chemistry

Abstract Novel X‐type polyurethane 5 containing 4‐(2′,2′‐dicyanovinyl)‐6‐nitroresorcinoxy groups as nonlinear optical (NLO) chromophores, which constitute parts of the polymer backbone, was prepared and characterized. Polyurethane 5 is soluble in common organic solvents such as acetone and N , N ‐dimethylformamide. It…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesSynthesis and properties of polymers

INFLUENCE OF La2O3 ADDITIONS ON CHEMICAL DURABILITY AND DIELECTRIC PROPERTIES OF BOROALUMINOSILICATE GLASSES

X. H. Zhang、Yun Yue、Haitao Wu2012-10-29Surface Review and Letters

Boroaluminosilicate glasses containing La 2 O 3 were prepared by the normal quenching method. The glass transition temperatures (T g ) were measured by differential scanning calorimetry (DSC). The structural role of RO was investigated by nuclear magnetic resonance (NMR). Chemical durability was evaluated by weight lo…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Biodistribution of intact fluorescent CdSe/CdS/ZnS quantum dots coated by mercaptopropionic acid after intravenous injection into mice

Yana Loginova、Natalia I. Kazachkina、Victoria V. Zherdeva 等 10 位作者2012-10-29Journal of Biophotonics

Semiconductor quantum dots (QD) have been widely used for fluorescent bioimaging. However their biosafety has attracted increasing attention, since the data about their in vivo behavior in biological systems are still limited. In this paper we have investigated the short- and long-term biodistribution of intact fluore…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesAdvanced Biosensing Techniques and Applications

Mixed-layered structure formation during trans-vacant Al-rich illite partial dehydroxylation

V. A. Drits、Douglas K. McCarty、Arkadiusz Derkowski2012-10-29American Mineralogist

The <1 μm fraction of a trans-vacant 1M illite (RM30) was studied by conventional and synchrotron X-ray diffraction (XRD) techniques, combined with thermogravimetric (TG, DTG) methods to investigate the structural transformation of illite at different temperatures and degrees of dehydroxylation (D T ). The oriented…

Glass properties and applicationsClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

Low Carbon High Nitrogen Low Nickel Stainless Steel

Saeed Ghali2012-10-29steel research international

Abstract This article aims to investigate the effect of soluble and insoluble nitrogen on mechanical properties of stainless steels. Reference steel contains about 14.42%Ni and 0.012%N. Two developed steels have the same base chemical composition of the reference steel except Ni and N contents. One of the developed st…

Corrosion Behavior and InhibitionMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Edgrewite Ca9(SiO4)4F2-hydroxyledgrewite Ca9(SiO4)4(OH)2, a new series of calcium humite-group minerals from altered xenoliths in the ignimbrite of Upper Chegem caldera, Northern Caucasus, Kabardino-Balkaria, Russia

Evgeny V. Galuskin、B. Lazić、Thomas Armbruster 等 11 位作者2012-10-29American Mineralogist

Members of the edgrewite Ca 9 (SiO 4 ) 4 F 2 -hydroxyledgrewite Ca 9 (SiO 4 ) 4 (OH) 2 series, structural analogues of clinohumite-hydroxylclinohumite series, Mg 9 (SiO 4 ) 4 (F,OH) 2 , were discovered in xenoliths of carbonate-silicate rock altered to skarn within ignimbrites of the Upper Chegem volcanic structure, K…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

Charging of nanostructured and partially reduced graphene oxide sheets

Yue Shen、Shouwu Guo、Jun Hu 等 4 位作者2012-10-29Applied Physics Letters

We report on the charging of individual graphene oxide (GO) sheets with varied degrees of reduction by using electrically biased atomic force microscope (AFM) tips. AFM measurements indicate that the apparent height of reduced GO (rGO) sheets increases sharply after charging, while the charging ability is enhanced whe…

Advancements in Battery MaterialsGraphene research and applicationsMolecular Junctions and Nanostructures

Selective Cell Recruitment and Spatially Controlled Cell Attachment on Instructive Chitosan Surfaces Functionalized with Antibodies

Catarina A. Custódio、A. M. Frias、Aránzazu del Campo 等 5 位作者2012-10-29Biointerphases

Bioactive constructs to guide cellular mobilization and function have been proposed as an approach for a new generation of biomaterials in functional tissue engineering. Adult mesenchymal stem cells have been widely used as a source for cell based therapeutic strategies, namely tissue engineering. This is a heterogene…

Bone Tissue Engineering MaterialsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Tunable bandgap and ferromagnetism in sputtered epitaxial Sn1−xMgxO2 thin films

Baozeng Zhou、Ping Wu、Wei Zhou2012-10-29Applied Physics Letters

Room-temperature magnetic behavior and tunable bandgap of epitaxial Sn1−xMgxO2 films were investigated. The Mg dopants can enhance the ferromagnetism and the largest saturation magnetization of 7.0 emu/cm3 has been observed in Sn0.94Mg0.06O2 film which has the narrowest bandgap. The ferromagnetism decreases with furth…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Contribution of a New Generation Field-Emission Scanning Electron Microscope in the Understanding of a 2099 Al-Li Alloy

Nicolas Brodusch、Michel L. Trudeau、Pierre Michaud 等 6 位作者2012-10-29Microscopy and Microanalysis

Aluminum-lithium alloys are widespread in the aerospace industry. The new 2099 and 2199 alloys provide improved properties, but their microstructure and texture are not well known. This article describes how state-of-the-art field-emission scanning electron microscopy (FE-SEM) can contribute to the characterization of…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesElectron and X-Ray Spectroscopy Techniques

Primary energy dependence of secondary electron emission from graphene adsorbed on Ni(111)

P. Riccardi、A. Cupolillo、Michele Pisarra 等 5 位作者2012-10-29Applied Physics Letters

We measured energy distribution and yields of electrons emitted from graphene adsorbed on a Ni(111) surface under the impact of 200–1200 eV electrons. The adsorption of graphene results in significant changes of the spectra of emitted electrons but not of the total emission yields. The electronic structure of the grap…

Graphene research and applicationsElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

An overview of impurity states and the basis for hole mobility in polyethylene

Ahmed Huzayyin、S.A. Boggs、Ramamurthy Ramprasad2012-10-29IEEE Electrical Insulation Magazine

This study concentrates on the energy states introduced into the band gap of polyethylene by chemical impurities and the resulting implications for hole mobility in PE. The thermal activation energies of polyethylene with iodine impurity, PE, and polypropylene can be predicted from the energy of iodine and carbonyl im…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrostatic Discharge in Electronics

General One-Step Self-Assembly of Isostructural Intermetallic CoII3LnIII Cubane Aggregates

Pei Wang、Santiranjan Shannigrahi、N.L. Yakovlev 等 4 位作者2012-10-29Inorganic Chemistry

A new family of Co/rare-earth intermetallic cubane aggregates [Co3Ln(hmp)4(OAc)5H2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co3Ln] core. Magnetic studies showed that the Dy, Er,…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research