Materials Literature
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Single crystals of molybdenum-incorporated tris(thiourea)zinc(II) sulfate (MoZTS) are grown by the slow evaporation solution growth technique. Crystal composition as determined by single-crystal X-ray diffraction analysis reveals that it belongs to the orthorhombic system with space group Pca21 and cell parameters a =…
초임계 유체 기술을 이용한 폴리락티드 스테레오 콤플렉스 제조는 폴리락티드의 열적 및 기계적 물성을 향상시키는 좋은 방법이다. 이 연구에서는 초임계 유체인 디메틸에테르를 이용하여 고분자량 폴리락티드를 높은 수율로 100% 스테레오 콤플렉스화를 시켰다. 폴리락티드에 대한 디메틸에테르의 높은 용해성은 이 공정의 핵심요소로 250 bar, <TEX>$70^{\circ}C$</TEX>, 1.5시간에 반응이 종료되었다. 폴리락티드의 스테레오 콤플렉스 연구는 압력, 온도, 시간, 농도 및 분자량을 변화시키며 진행하였다. 스테레오 콤플렉스화는 온도와 압력이 증가할 때 높아졌다.…
Reduced complexity in production of large-scale, flexible surface enhancement Raman spectroscopy (SERS) active substrate has been implemented at the water surface, when polydimethylsiloxane (PDMS) solution having lower density than the water meets with self-assembled polystyrene (PS) nanoparticles (NPs). Through tunin…
Aperiodic composite crystals present long-range order without translational symmetry. These materials may be described as the intersection in three dimensions of a crystal which is periodic in a higher-dimensional space. In such materials, symmetry breaking must be described as structural changes within these crystall…
Defects-induced local symmetry breaking has led to unusual properties in nonferromagnetic ferroelastic materials upon suppressing their martensitic transformation. Thus, it is of interest to discover additional properties by local symmetry breaking in one important class of the ferroelastic materials, i.e., the ferrom…
The most high-strength aluminum alloys based on the Al – Zn – Mg – (Cu) system have a significant tendency to form hot cracks during solidification. Additional alloying of 7xxx series alloys with the eutectic forming elements (Fe and Ni) that are slightly soluble in an (Al) solid solution w…
Chemical pesticides are resistant to biodegradation beside carcinogenic in nature even at trace levels. Effort to remove pesticide by conventional methods has several inherent disadvantages of longer time or cost and this bottleneck can be avoided by utilizing nanoparticles as it can mineralise at a faster rate. Nanop…
We have prepared graphene-veiled-nanoparticle hybrids by depositing a bilayer graphene film on silver nanoparticles with large particle sizes, ∼200 nm. The hybrids possess good thermal stability and exhibit great surface-enhanced Raman scattering with enhancement factors of 49- and 21-fold for the G and 2D peaks, resp…
We use a combination of global back-gating and local top-gating to define nanoscale devices in the two-dimensional electron gas at the LaAlO3-SrTiO3 interface, demonstrating an efficient way for much finer spatial control over the properties of the interface, as compared to back-gating alone. The devices show indicati…
We report a method for accelerated nanoscale nuclear magnetic resonance imaging by detecting several signals in parallel. Our technique relies on phase multiplexing, where the signals from different nuclear spin ensembles are encoded in the phase of an ultrasensitive magnetic detector. We demonstrate this technique by…
Anisotropic diamagnetism of pristine graphite and graphene is well known. Here, evidence of significant induced ferromagnetism in multilayer graphene (MLG) decorated with ferrimagnetic Fe3O4 particles is reported. This MLG-Fe3O4 nano-composite was prepared by a one-step ultrasonic treatment at 75 °C in the surfactant…
Using first-principles calculations, it is shown that the work function of graphene on copper can be adjusted by varying the concentration of intercalated alkali metals. Using density functional theory, we calculate the modulation of work function when Li, Na, or K are intercalated between graphene and a Cu(111) surfa…
The effects of Li2O–B2O3–SiO2(LBS) glass additive on the microstructural development and gyromagnetic properties of low-temperature sintered LiZnTi ferrites were investigated. The aim was to assess the potential applications of LiZnTi ferrites in low-temperature cofired ceramic (LTCC) technology, and to produce LTCC p…
The highest symmetry in which piezoelectricity was thought to occur is cubic. Here, it is shown that third rank piezoelectricity can occur in isotropic chiral solids. Polarization is coupled via an isotropic third rank tensor to the antisymmetric part of the stress. Asymmetric stress can occur if balanced by moments d…
This paper details the fabrication of n-ZnO single microwire (SMW)-based high-purity ultraviolet light-emitting diodes (UV-LEDs) with an added SiO2 barrier layer on the p-Si substrate. However, the current-voltage (I-V) curve exhibited non-ideal rectifying characteristics. Under forward bias, both UV and visible emiss…
High contact resistance between graphene and metal is a major huddle for high performance electronic device applications of graphene. In this work, a method to improve the contact resistance of graphene is investigated by varying the ratio of peripheral length and area of graphene pattern under a metal contact. The co…
A green photoinduced method for the modification of a biodegradable and biocompatible polymer, Poly(3-hydroxybutyrate- co -3-hydroxyvalerate) (PHBHV) has been successfully carried out using two types of monomers with potential antibacterial effects, i.e., 2-[(methacryloyloxy)-ethyl] trimethylammonium chloride (META) a…
In this paper, we studied the magnetic properties of the Heusler-type NiMnGa glass-covered microwires. We observed that annealing conditions strongly affect the temperature dependence of magnetization and Curie temperature of microwires. After long (6 h) annealing of the microwires at 773 K, a ferromagnetic ordering i…
Super-large-period Aurivillius thin films with a pseudo-period of ten were grown on (0 0 1) SrTiO3 substrates using the pulsed laser deposition method. The as-grown films are found to be coherently strained to the substrate and atomically smooth. X-ray diffraction indicates an average periodicity of ten, while analysi…
In this study, a 2-D finite element formulation in the frame of nonlocal integral elasticity is presented. Subsequently, the bending problem of a nanobeam under different types of loadings and boundary conditions is solved based on classical beam theory and also 3-D elasticity theory using nonlocal finite elements (NL…