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Preparation and structure of [Sn8W18O66]8? ? a 26-nuclear stannotungstate with a hexagonal belt of six Sn(ii) ions with outward-looking lone pairs

Maxim N. Sokolov⧫、Natalya V. Izarova、A.V. Virovets 等 6 位作者2003-01-01Dalton Transactions

Sn(II) acts as template in reaction with WO42− in formate buffer, inducing the formation of decanuclear [SnW9O33]10− and further linking them by six Sn(II) centers to give orange 26-nuclear stannotungstate [Sn8W18O66]8−. Crystalline [Na12(OH)4(H2O)28][Sn8W18O66]·18H2O (1) was isolated and structurally characterized.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials

作者信息未提供2003-01-01OpenAlex

Conference proceedings front matter may contain various advertisements, welcome messages, committee or program information, and other miscellaneous conference information. This may in some cases also include the cover art, table of contents, copyright statements, title-page or half title-pages, blank pages, venue maps…

Synthesis and properties of polymersMicrowave Dielectric Ceramics SynthesisMaterial Properties and Applications

A discussion on activation mechanism of atom groups in serpentine

Xue Li2003-01-01Acta Petrologica Et Mineralogica

According to the characteristics of serpentine in such aspects as its chemical composition, crystal structure and chemical bond, the authors have divided the activated atom group in serpentine into five classes, i.e. unsaturated Si—O—Si,O—Si—O, OH—Mg—OH(O) ,OH -,and O—H—O. With these unsaturated chemical bonds, serpen…

Porphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Crystal Structure and Transport Properties of .GAMMA.-NaxCoO2 (x = 0.67-0.75)

Yasuhiro Ono、Nobuhiko Kato、Yoshinobu Ishii 等 5 位作者2003-01-01Journal of the Japan Society of Powder and Powder Metallurgy

Crystal structure and transport properties of γ-NaxCoO2 have been studied in the range of x=0.67-0.75. Single-phase samples were prepared by sintering mixture of raw materials, Na2CO3 (99.5%) and Co3O4 (99.9%). Na/Co composition ratio (x) was determined by inductively coupled plasma (ICP) analysis. The crystal structu…

Advanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and DevicesThermal Expansion and Ionic Conductivity

Quasilocal defects in regular planar networks: Categorization for molecular cones

Douglas J. Klein2003-01-01International Journal of Quantum Chemistry

Abstract Graphical networks are cast into structural equivalence classes, with special focus on ones related to two‐dimensional regular translationally symmetric nets (or lattices). A quasilocal defect in a regular net is defined as consisting of a finite subnet surrounded outside this region by an infinitely extended…

Bone Tissue Engineering MaterialsSupramolecular Self-Assembly in MaterialsQuasicrystal Structures and Properties

Surface modifications of EVA copolymers induced by low pressure RF plasmas from different gases and their relation to adhesion properties

C.M. Cepeda-Jiménez、Rosa Torregrosa-Maciá、José Miguel Martín‐Martínez2003-01-01Journal of Adhesion Science and Technology

Two ethylene vinyl acetate (EVA) copolymers (12 and 20 wt% of vinyl acetate,VA, content) have been treated with low pressure RF plasmas from non-oxidizing gases (Ar, N2) and oxidizing gases (air, a mixture of 4N2: 6O2 (v/v), O2 and CO2). The formation of polar moieties on both EVAs was more noticeable by treatment wit…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsSilicone and Siloxane Chemistry

Influence of the Al content on the phase transformations in Cu-Al-Ag alloys

A. T. Adorno、Assis Vicente Benedetti、R. A. G. da Silva 等 4 位作者2003-01-01Eclética Química

The influence of the Al content on the phase transformations in Cu-Al-Ag alloys was studied by classical differential thermal analysis (DTA), optical microscopy (OM) and X-ray diffractometry (XRD). The results indicated that the increase in the Al content and the presence of Ag decrease the rate of the <FONT FACE=S…

Aluminum Alloy Microstructure PropertiesIntermetallics and Advanced Alloy PropertiesMetallurgical and Alloy Processes

Functional silanes: crosslinkers for silicone elastomers

J. M. Pujol、Christiane Prébet2003-01-01Journal of Adhesion Science and Technology

Hydrolyzable functional silanes are used as silicone elastomer crosslinkers. The hydrolysis, triggered by air moisture, leads to crosslinking of linear polymer chains to three-dimensional networks. The properties of these elastomers depend on the silane structure. The influence of the structure has been studied for RS…

Advanced Sensor and Energy Harvesting MaterialsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Dielectric spectroscopy and thermally stimulated discharge current in PEEK film

Walter Katsumi Sakamoto2003-01-01Eclética Química

The complex permittivity of films of polyether ether ketone (PEEK) has been investigated over a wide range of frequency. There is no relaxation peak in the range of 1Hz to 10(5) Hz but in the low-frequency side (10-4 Hz) there is an evidence of a peak that also can be observed by thermally stimulated discharge current…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Chiral Phases Induced by Doping Nonmesogenic Component into Mesogenic Esters

Jayrang S. Dave、Meera Menon、Pratik Patel2003-01-01Molecular Crystals and Liquid Crystals

We have prepared and studied four binary systems by doping a nonmesogenic optically active compound, namely 6-methoxy-2',4"-dibenzoylerythromycin, in various mesogenic compounds, namely 4-(4'-n-alkoxybenzoyloxy)phenylazo-4"-isoamyloxybenzenes (C 8 , C 10 ) and 4-(4'-n-alkoxybenzoyloxy)benzylidine-4"-isoamyloxy aniline…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Biaxial Discotic Gay-Berne Mesogens and Biaxial Nematics

Roberto Berardi、Claudio Zannoni2003-01-01Molecular Crystals and Liquid Crystals

We investigate the thermotropic liquid crystal phases formed in a system of biaxial discotic mesogenic Gay-Berne particles with strong in-plane interactions when the attractive and repulsive biaxialities have the same or the opposite sign. We find that a biaxial nematic phase is obtained when the shape and well depth…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Physical and Chemical Molecular Interactions

Oxidation behavior and strength degradation of CVD-SiC coated C/C composites at high temperature in air

Satoshi KOBAYASHI、Shuichi WAKAYAMA、Takuya Aoki 等 4 位作者2003-01-01Advanced Composite Materials

Simple tensile tests and tensile tests after high temperature exposure of carbon fiber reinforced carbon matrix (C/C) composites have been carried out at high temperature (1000-1400 °C) in air. Types of specimens were bare, notched bare and CVD-SiC coated C/C composites. The CVD-SiC coated C/C composites were mechanic…

Advanced ceramic materials synthesisSemiconductor materials and devicesAdvanced materials and composites

Electron Holography of Nanocrystalline Magnetic Materials

Daisuke Shindo2003-01-01MATERIALS TRANSACTIONS

Electron holography study on magnetic domain structures of nanocrystalline magnetic materials was overviewed mainly based on the experimental results recently obtained by the author and his colleagues. Electron holography system which was established by modifying a conventional analytical electron microscope, i.e., in…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

8th International IUFRO Wood Drying Conference: Brasov-Romania, August 24-29, 2003

Patrick Perré、Mihaela Câmpean2003-01-01Maderas Ciencia y tecnología

Americanae nace como un proyecto conjunto que surge dentro de la Red Europea de Información y Documentación sobre América Latina (REDIAL), y que ha afrontado la Biblioteca de la Agencia Española de Cooperación Internacional para el Desarrollo (AECID). Esta nueva biblioteca virtual hace más accesibles los libros digita…

Wood Treatment and PropertiesTextile materials and evaluations

Preparation of the conducting nanocomposites using molded inorganic matrix: fibrous cerium( iv ) hydrogenphosphate as a self-supported pyrrole polymerization agent

Carla Veríssimo、Oswaldo Luiz Alves2003-01-01Journal of Materials Chemistry

New supported polypyrrole nanocomposites have been prepared and studied in this work. Self-supported sheets of fibrous cerium(IV) hydrogenphosphate (CePf) were used as the inorganic matrix, since the fibrous morphology presented by this material makes molding possible, giving a desired shape to the final polypyrrole/C…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Thermoelectric Properties of Na<SUB>x</SUB>Co<SUB>2</SUB>O<SUB>4</SUB> Prepared by the Polymerized Complex Method and Spark Plasma Sintering

Tomoya Nagira、Mikio Ito、Shigeru Katsuyama 等 4 位作者2003-01-01MATERIALS TRANSACTIONS

NaxCo2O4 powders were synthesized using the polymerized complex (PC) method and then the polycrystalline samples were prepared by the spark plasma sintering (SPS) method. The microstructure and thermoelectric properties of these samples were evaluated, and their differences due to the preparation process of the polycr…

Advanced Thermoelectric Materials and DevicesAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Dissipativity of a conserved phase-field system with memory

Federico M. G. Vegni2003-01-01Discrete and Continuous Dynamical Systems

We analyze a conserved phase-field system, characterized by heat memory terms: memory kernels $a$ and $b$ account for relaxation effects in the energy constitutive equation and in the Gurtin-Pipkin heat conduction law, respectively. This model consists of a hyperbolic integrodifferential equation for the temperature $…

Solidification and crystal growth phenomenaStability and Controllability of Differential EquationsAdvanced Mathematical Modeling in Engineering

Cyanidverbrückte Dreikernkomplexe mit zentralen M(Cyclam)‐Einheiten

R. Appelt、Heinrich Vahrenkamp2003-01-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Durch Umsetzung von Metall‐Cyclam‐Komplexen M(Cyclam)X n mit metallorganischen Cyaniden L n M′‐CN wurden Dreikernkomplexe L n M′‐CN‐M(Cyclam)‐NC‐M′L n mit M = Mn, Fe, Co, Ni und M′ = Cr, Fe, Ru erhalten. Mit strukturanalytischen, spektroskopischen und elektrochemischen Methoden wurden sie auf elektronische We…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Digestibility of Cereals, Oil Meals, Brans and Hays in Thoroughbreds

Hisao Takagi、Yasushi Hashimoto、Chisato Yonemochi 等 6 位作者2003-01-01Journal of Equine Science

The digestibility of nutrients and nutritive values of cereals (barley, corn, naked oat, oat and quinor), oil meals (cotton seed meal, linseed meal and soybean meal), brans (defatted rice bran, wheat bran and wheat bran with flour) and hays (Italian ryegrass and orchardgrass) were determined by the chromic oxide index…

Agriculture, Soil, Plant ScienceMetallurgy and Material Science

Ferroelectric Loop Modelling Based on Experimental Preisach Density Determined by FORC Method

Lionel Cima、Éric Labouré2003-01-01Ferroelectrics

In this article a Preisach type density will be used to reconstruct the capacitive effects associated to a ferroelectric loop. This density will be experimentally determined using the FORC method. The small-signal capacitance, which can not be modelled by a Preisach type density, is measured simultaneously and must be…

Semiconductor materials and devicesMagnetic Properties and ApplicationsFerroelectric and Negative Capacitance Devices