Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Photosensitized oxidation of trimethyl[2.2.1]bicycloheptane thioketones by (1)O2 can yield more photoproducts than exclusively ketones and sulfines. Moreover, the ketone/sulfine ratio can be reversed when protic conditions and high thioketone concentrations are used, conversely to earlier results reporting ketones as…
A hexaphenylbenzene (HPB)-based derivative bearing thiol groups has been designed and synthesized that undergoes aggregation-induced emission enhancement in mixed aqueous media to form rodlike fluorescent aggregates. These rodlike aggregates behave as a "not quenched" probe for the detection of silver ions and further…
The aim of the present study was to examine the apoptosis of the hepatocellular carcinoma cell line, HepG2, induced by treatment with folic acid-conjugated silica-coated gold nanorods (GNRs@SiO2-FA) in combination with radiotherapy, and to determine the involvement of apoptosis-related proteins. An MTT colorimetric as…
A high-speed manufacturing process for multiwalled carbon nanotube (MWNT) buckypaper is presented, and its application as an embedded strain sensor for composite materials is demonstrated. This manufacturing method enables the production of sizable carbon nanotube (CNT) membranes with significantly reduced processing…
Achieving selective C-H bond cleavage is critical for developing catalytic processes that transform small alkanes to value-added products. The present study clarifies the molecular-level origin for an exceptionally strong preference for propane to dissociate on the crystalline PdO(101) surface via primary C-H bond cle…
Amphiphilic polymers are tunable systems to construct supramolecular hierarchically self-assembled structures. Six families of heterocyclic polymethacrylates (PMTAs) bearing 1,3-thiazole and 1,2,3-triazole pendant groups with alkyl and succinate spacers were chemically modified by quaternization reaction of the azole…
In this study, nanocrystalline ferrite powders with the composition $Ni_{0.5}Zn_{0.5}Fe_2O_4$ were prepared by the autocombustion method. The obtained powders were sintered at $800^{\circ}C$ , $900^{\circ}C$ and $1,000^{\circ}C$ for 4 h in air atmosphere. The as-prepared and the sintered powders were characterized by…
Small streams and shallow ponds represent sensitive ecosystems and attached diatoms can serve as integrative indicator with fast response to environmental changes. Development of methods for ecological monitoring throughout Europe and their calibration for particular ecoregions are not finished yet and databases need…
A method for polydimethylsiloxane grafting of alumina powders is described which involves chemical modification of the surface of mesoporous (5 nm) γ-alumina flakes with a linker (3-aminopropyltriethoxysilane: APTES), either by a solution phase (SPD) or a vapour phase (VPD) reaction, followed by PDMS grafting. The sys…
A model for the thermodynamic stability of amorphous silicon oxycarbide (SiCO) is presented. It builds upon the reasonably accepted model of SiCO which is conceived as a nanodomain network of graphene. The domains are expected to be filled with SiO2 molecules, while the interface with graphene is visualized to contain…
By modifying the molecular dipole moments with lateral monofluorine substituent, improved mesophase stabilities were obtained for novel benzoxazole derivatives, 2-(4ʹ-alkoxy-3-fluorobiphenyl-4-yl)-benzoxazole liquid crystals (coded as nPPF(3)Bx). The series of nPPF(3)Bx with lateral monofluorine substituent ortho to b…
Hybrid composites containing endless glass fiber reinforcement and surface‐functionalized carbon nanotubes (CNTs) dispersed in the matrix phase were produced by resin transfer molding (RTM). An efficient surface modification of the nanotubes enhances the compatibility with the matrix system and the dispersion quality,…
The Sommerfeld halfspace problem is revisited allowing for multilayer and plasmonic media, with a focus on the surface field computation. Alternative field representations are discussed and an improved Sommerfeld-Norton groundwave formula is developed. The role of the Zenneck wave and surface plasmon polariton in the…
Cryogenic etching processes in SF 6 and SF 6 /C 4 F 8 plasmas were successfully applied to porous organosilicate glasses. Such materials are low- k candidates for advanced interconnects. Their integration is very challenging because of plasma induced damage. These two chemistries (SF 6 and SF 6 /C 4 F 8 ) have demonst…
Volume 5B addresses the subject of organic protective coatings, the most widely used preventative in the battle with rust and corrosion. It covers the entire spectrum of organic coating materials from acrylics, alkyds, and epoxies to powder coats, waxes, and zinc-rich blends. It compares and contrasts coating properti…
In this paper, a series of new Schiff bases with different substituents were prepared via condensation reaction of vanillin and different diamines. These monomers were converted to polyurethane derivatives using aliphatic and aromatic diisocyanates as co-monomer via step-polymerization reactions. Photophysical, electr…
A methodology was developed for the prediction of the electrical properties of carbon nanotube-polymer nanocomposites via Monte Carlo computational simulations. A two-dimensional microstructure that takes into account waviness, fiber length and diameter distributions is used as a representative volume element. Fiber i…
Colloidal ultrasmall superparamagnetic iron oxide nanoparticles (USNPs) with better control of their surface chemistry have been considered as a biocompatible alternative to clinically used gadolinium-based contrast agents for in vivo bright magnetic resonance imaging (MRI). Herein, we report a versatile mussel-inspir…
Spectroscopic ellipsometry and Raman scattering measurements of single-crystal Li x CoO 2 ( x = 0.33, 0.43, 0.50, 0.53, 0.72, and 0.87) are reported. The room temperature optical absorption spectra for x values in the range of 0.33–0.72 exhibit three bands near 1.60, 3.35, and 5.20 eV. On the basis of first-principles…
A polarization-mediated heterointerface is designed to research the thermal stability of magnetic metal/oxide interfaces. Using polarization engineering, the thermal stability of the interface between BiFeO3 and CoFeB can be improved by about 100°C. This finding provides new insight into the chemistry of the metal/oxi…