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Experimental and theoretical study ofα–Eu2(MoO4)3under compression

C. Guzmán-Afonso、Sergio F. León-Luis、J. A. Sans 等 12 位作者2015-10-26Journal of Physics Condensed Matter

The compression process in the α-phase of europium trimolybdate was revised employing several experimental techniques. X-ray diffraction (using synchrotron and laboratory radiation sources), Raman scattering and photoluminescence experiments were performed up to a maximum pressure of 21 GPa. In addition, the crystal s…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Extraordinary light absorptance in graphene superlattices

Yu‐Hsiang Cheng、C.H. Chen、Kun-Chieh Yu 等 4 位作者2015-10-26Optics Express

Extraordinary absorption decrease in graphene superlattices in the visible range is presented. Due to competition between loss and resonant reflection at resonance, the absorption displays non-monotonic behavior. As the period number increases above a certain critical value, absorption decreases with the increase in t…

Graphene research and applicationsMetamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Lattice dynamics and thermoelectric properties of nanocrystalline silicon–germanium alloys

Tania Claudio、Niklas Stein、Nils Petermann 等 9 位作者2015-10-26physica status solidi (a)

Abstract The lattice dynamics and thermoelectric properties of sintered phosphorus‐doped nanostructured silicon–germanium alloys obtained by gas‐phase synthesis were studied. Measurements of the density of phonon states by inelastic neutron scattering were combined with measurements of the elastic constants and the lo…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsSemiconductor materials and interfaces

Nanoporous Silicon Combustion: Observation of Shock Wave and Flame Synthesis of Nanoparticle Silica

Collin R. Becker、Greg Gillen、Matthew E. Staymates 等 4 位作者2015-10-26ACS Applied Materials & Interfaces

The persistent hydrogen termination present in nanoporous silicon (nPS) is unique compared to other forms of nanoscale silicon (Si) which typically readily form a silicon dioxide passivation layer. The hydrogen terminated surface combined with the extremely high surface area of nPS yields a material capable of powerfu…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchSilicon Nanostructures and Photoluminescence

Nanophase separation in CoSb‐based half‐Heusler thermoelectrics: A multiscale simulation study

Joaquin Miranda Mena、Heiko G. Schoberth、Thomas Gruhn 等 4 位作者2015-10-26physica status solidi (a)

Abstract If cooled down from high temperatures, some half‐Heusler alloys based on CoTiSb show a spontaneous phase separation into coexisting domains. In thermoelectric applications, this domain structure is beneficial for the efficiency because it reduces the lattice thermal conductivity, which increases the figure of…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic properties

Semiempirical Approach for Predicting the Mean Size of Solid-Stabilized Emulsions

Èmir Tsabet、Louis Fradette2015-10-26Industrial & Engineering Chemistry Research

The final mean droplet size of concentrated solid-stabilized emulsions was predicted using a semiempirical approach. The first step was to estimate the coverage and interface generation potentials. The coverage potential was predicted from the properties of the particles while the interface generation potential was pr…

Fluid Dynamics and MixingMinerals Flotation and Separation TechniquesPickering emulsions and particle stabilization

Plasma Polymerization at Atmospheric Pressure with a New Type of DBD Reactor for Combinatorial Studies: Classification of Precursor Concentration Dependencies

Jens Philipp、Andreas K. Czerny、C.‐P. Klages2015-10-26Plasma Processes and Polymers

Design and first applications of a new kind of reactor for plasma treatments or plasma-assisted chemical vapor deposition (PACVD) processes based on dielectric barrier discharges (DBD) at atmospheric pressure are presented. Inserting a combination of two modules, gradient mixer and homogenizer, into the gas-supply lin…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPlasma Applications and Diagnostics

Anti-corrosion behavior of thiadiazole derivatives for silver strip in hydrogen sulfide solutions

Lin Liu、Xiaona Pan、Jinjuan Xing 等 4 位作者2015-10-26Anti-Corrosion Methods and Materials

Purpose – This paper aims to evaluate the inhibition efficiency of thiadiazole derivatives, such as 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 5-methly-2-mercapto-1,3,4-thiadiazole (MMTD) and 2,5-dithiododecyl-1,3,4-thiadiazole (DDTD), in 50 mg/L hydrogen sulfide for silver strip. Design/methodology/approach – Evaluatio…

Corrosion Behavior and InhibitionGas Sensing Nanomaterials and SensorsElectrochemical Analysis and Applications

Immobilization of silver nanoparticles on exfoliated mica nanosheets to form highly conductive nanohybrid films

Chih‐Wei Chiu、Gang-Bo Ou、Yu‐Hsuan Tsai 等 4 位作者2015-10-26Nanotechnology

Highly electrically conductive films were prepared by coating organic/inorganic nanohybrid solutions with a polymeric dispersant and exfoliated mica nanosheets (Mica) on which silver nanoparticles (AgNPs) had been dispersed in various components. Transmission electronic microscopy showed that the synthesized AgNPs had…

Graphene research and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing Technologies

The effects of microstructure on crackling noise during martensitic transformation in Cu-Al-Ni

Eilon Faran、Hanuš Seiner、Michal Landa 等 4 位作者2015-10-26Applied Physics Letters

Martensitic phase transformations often exhibit crackling noise response of the emitted energy. This type of behavior implies that the phase transformation proceeds through numerous events that do not exhibit any characteristic scale. On the other hand, the twinned microstructure along the phase boundary exhibits a ch…

Microstructure and Mechanical Properties of SteelsShape Memory Alloy TransformationsMagnetic Properties and Applications

Nano-morphology induced additional surface plasmon resonance enhancement of SERS sensitivity in Ag/GaN nanowall network

S Sharvani、Kishor Upadhayaya、Gayatri Kumari 等 5 位作者2015-10-26Nanotechnology

The GaN nanowall network, formed by opening the screw dislocations by kinetically controlled MBE growth, possesses a large surface and high conductivity. Sharp apexed nanowalls show higher surface electron concentration in the band-tail states, in comparison to blunt apexed nanowalls. Uncapped silver nanoparticles are…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

Polymerization of epoxidized triglycerides with fluorosulfonic acid

Atanu Biswas、Zengshe Liu、H. N. Cheng2015-10-26International Journal of Polymer Analysis and Characterization

The use of triglycerides as agri-based renewable raw materials for the development of new products is highly desirable in view of uncertain future petroleum prices. A new method of polymerizing epoxidized soybean oil has been devised with the use of fluorosulfonic acid. Depending on the reaction conditions, one can ge…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingCarbon dioxide utilization in catalysis

Ab initio phonon‐coupled nonadiabatic relaxation dynamics of [Au25(SH)18]− clusters

Xue Chen、Oleg V. Prezhdo、Zeyao Ma 等 6 位作者2015-10-26physica status solidi (b)

Nanoscale gold clusters exhibit unique electronic and optical properties. Here, we study the excited state dynamics and electron–phonon coupling of [Au25(SH)18]– nanoclusters by using quantum‐classical molecular dynamics combined with time‐dependent density‐functional theory. Our result reproduces the experimental mea…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Cell differentiation on disk‐ and string‐shaped hydrogels fabricated from Ca2+‐responsive self‐assembling peptides

Kazuto Fukunaga、Hiroshi Tsutsumi、Hisakazu Mihara2015-10-26Biopolymers

We recently developed a self-assembling peptide, E1Y9, that self-assembles into nanofibers and forms a hydrogel in the presence of Ca(2+) . E1Y9 derivatives conjugated with functional peptide sequences derived from extracellular matrices (ECMs) reportedly self-assemble into peptide nanofibers that enhance cell adhesio…

Hydrogels: synthesis, properties, applications3D Printing in Biomedical ResearchSupramolecular Self-Assembly in Materials

Structural Properties of Picene–Perfluoropentacene and Picene–Pentacene Blends: Superlattice Formation versus Limited Intermixing

J. Dieterle、Katharina Broch、Alexander Hinderhofer 等 10 位作者2015-10-26The Journal of Physical Chemistry C

The structure and morphology of mixed thin films of picene (C 22 H 14, PIC) and perfluoropentacene (C 22 F 14, PFP) as well as mixed thin films of PIC and pentacene (C 22 H 14, PEN) grown by simultaneous coevaporation is investigated using X-ray diffraction, atomic force microscopy, and near-edge X-ray absorption spec…

Organic Electronics and PhotovoltaicsBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Monoanionic Dipyrrin–Pyridine Ligands: Synthesis, Structure and Photophysical Properties

Clémence Ducloiset、Pauline Jouin、Elisa Paredes 等 8 位作者2015-10-26European Journal of Inorganic Chemistry

Abstract A novel monoanionic tetradentate N4 ligand (F5DPPy) based on a dipyrromethene skeleton as a molecular platform and decorated with pyridine rings at the 1‐ and 9‐positions of the dipyrrin motif has been prepared and characterized. Interestingly, although this ligand is weakly fluorescent, it presents a chelati…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Can model Hamiltonians describe the electron–electron interaction inπ-conjugated systems?: PAH and graphene

G. Chiappe、E. Louis、Emilio San‐Fabián 等 4 位作者2015-10-26Journal of Physics Condensed Matter

Model Hamiltonians have been, and still are, a valuable tool for investigating the electronic structure of systems for which mean field theories work poorly. This review will concentrate on the application of Pariser-Parr-Pople (PPP) and Hubbard Hamiltonians to investigate some relevant properties of polycyclic aromat…

Advanced Chemical Physics StudiesGraphene research and applicationsMolecular Junctions and Nanostructures

Characterization of dielectric materials by the extension of voltage response method

Zoltán Ádám Tamus、D Csábi、Gergely Márk Csányi2015-10-26Journal of Physics Conference Series

The voltage response method measures the decay and return voltages on a charged and shorted dielectric and from the slopes of these voltages the specific conductivity and the polarization conductivity of the material can be determined. These two numbers can characterize the main dielectric processes, namely the conduc…

High voltage insulation and dielectric phenomenaStructural Health Monitoring TechniquesPower Transformer Diagnostics and Insulation

Observation of charge separation and gas discharge during sliding friction between metals and insulators

Takashi Miura2015-10-26Journal of Physics Conference Series

Charge generation due to friction between stainless steel and fused quartz in a vacuum was measured, and it was found that the density of the charge separation at the friction contact was 4 × 10 -4 C/m 2 In experiments in ambient gas, reduction of the separated charge caused by microgap gas discharge was observed. The…

High voltage insulation and dielectric phenomenaVacuum and Plasma ArcsElectrical Contact Performance and Analysis

The protection and monitoring of a distribution piping network for potable water supply

Juliusz Orlikowski、K. Darowicki、Agata Jażdżewska 等 4 位作者2015-10-26Anti-Corrosion Methods and Materials

Purpose – The purpose of this paper is to implement the corrosion protection method for steel pipes used in a municipal water-pipe network. Results of an inhibitor protection system installed on the system are presented. Inhibitor protection was required due to the high corrosivity of the water collected by a surface…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability