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An Effective Way to Optimize the Functionality of Graphene-Based Nanocomposite: Use of the Colloidal Mixture of Graphene and Inorganic Nanosheets

Xiaoyan Jin、Kanyaporn Adpakpang、In Young Kim 等 6 位作者2015-06-08Scientific Reports

The best electrode performance of metal oxide-graphene nanocomposite material for lithium secondary batteries can be achieved by using the colloidal mixture of layered CoO2 and graphene nanosheets as a precursor. The intervention of layered CoO2 nanosheets in-between graphene nanosheets is fairly effective in optimizi…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

HLD–NAC and the Formation and Stability of Emulsions Near the Phase Inversion Point

Sumit K. Kiran、Edgar Acosta2015-06-08Industrial & Engineering Chemistry Research

It is well-known that surfactant–oil–water (SOW) emulsions undergo substantial changes in drop size (10-fold or more) and stability (up to 4 orders of magnitude) near the phase inversion point. Predicting these changes is important in numerous applications. However, the complex connection between composition, formulat…

Surfactants and Colloidal SystemsInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

Enhanced Carrier Lifetimes of Pure Iodide Hybrid Perovskite via Vapor-Equilibrated Re-Growth (VERG)

B. Selin Tosun、Hugh W. Hillhouse2015-06-08The Journal of Physical Chemistry Letters

Solution deposition of planar films of the hybrid perovskite (HP) methylammonium (MA) lead iodochloride (MAPbI3-xClx) often results in very low surface coverage, small grain size, and high density of defects, particularly for the pure iodide HP. These decrease the optoelectronic quality of MAPbI3 (minority lifetimes a…

Perovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallography

Delamination in Drilling of Natural Fibre Reinforced Polymer Composites Produced by Compression Moulding

Sampath Aravindh、K. Umanath2015-06-08Applied Mechanics and Materials

Natural fibre composites today are replacing synthetic fibre composites due to superior properties of natural fibres such as low density, high specific strength and modulus, relative no abrasiveness, ease of fibre surface modification, and wide availability .Drilling is often required to facilitate the assembly of the…

Advanced machining processes and optimizationNatural Fiber Reinforced CompositesAdvanced Machining and Optimization Techniques

Focusing on Plates: Controlling Guided Waves using Negative Refraction

F. Philippe、Todd W. Murray、Claire Prada2015-06-08Scientific Reports

Elastic waves are guided along finite structures such as cylinders, plates, or rods through reflection, refraction, and mode conversion at the interfaces. Such wave propagation is ubiquitous in the world around us, and studies of elastic waveguides first emerged in the later part of the 19(th) century. Early work on e…

Metamaterials and Metasurfaces ApplicationsAcoustic Wave Phenomena ResearchUnderwater Acoustics Research

Metal–Organic Nanotube with Helical and Propeller-Chiral Motifs Composed of a C 10 -Symmetric Double-Decker Nanoring

Hiroshi Yamagishi、Takahiro Fukino、Daisuke Hashizume 等 8 位作者2015-06-08Journal of the American Chemical Society

Coassembly of an achiral ferrocene-cored tetratopic pyridyl ligand (FcL) with AgBF4 in CH2Cl2/MeCN (7:3 v/v) containing chiral Bu4N(+) (+)- or (-)-menthylsulfate (MS*(-)) results in the formation of an "optically active" metal-organic nanotube (FcNT) composed of a C10-symmetric double-decker nanoring featuring 10 FcL…

Metal-Organic Frameworks: Synthesis and ApplicationsSynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in Materials

Structural and Ionic Conductivity Studies of CMC Based Polymerelectrolyte Doped with NH4Cl

Nur Hidayah Ahmad、M. I. N. Isa2015-06-08Advanced materials research

The present study aims to investigate the structural and ionic conductivity of carboxymethyl cellulose - ammonium chloride as proton conducting polymer electrolytes. The complexion of polymer electrolyte films has been confirmed via FTIR studies. The conductivity enhancement with the addition of ammonium chloride conc…

Advanced Battery Materials and TechnologiesFuel Cells and Related MaterialsConducting polymers and applications

Characterization and Rockwell-C adhesion properties of chromium-based borided steels

Yusuf Kayalı、Şükrü Taktak2015-06-08Journal of Adhesion Science and Technology

In this study, adhesion properties of boride layers formed on the surface of AISI 52100, AISI 5140, AISI 440C, AISI 420 and AISI 304 steels were investigated. Boronizing treatment was carried out in Ekabor-II powders at the temperatures of 850 and 950 °C for 4 h. The properties of boride layers were evaluated by optic…

Metal and Thin Film MechanicsAdvanced materials and compositesMetal Alloys Wear and Properties

Free-carrier electro-refraction modulation based on a silicon slot waveguide with ITO

Junsu Baek、Jong-Bum You、Kyoungsik Yu2015-06-08Optics Express

Recently, silicon-waveguide-based hybrid modulators with high-performance electro-optic materials have been proposed to overcome the intrinsic limitations of silicon materials. Indium-tin-oxide (ITO) is one of the important candidates for such applications due to its unique features including the ENZ effect and electr…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Structural basis of a Ni acquisition cycle for [NiFe] hydrogenase by Ni-metallochaperone HypA and its enhancer

Satoshi Watanabe、Takumi Kawashima、Yuichi Nishitani 等 9 位作者2015-06-08Proceedings of the National Academy of Sciences

The Ni atom at the catalytic center of [NiFe] hydrogenases is incorporated by a Ni-metallochaperone, HypA, and a GTPase/ATPase, HypB. We report the crystal structures of the transient complex formed between HypA and ATPase-type HypB (HypBAT) with Ni ions. Transient association between HypA and HypBAT is controlled by…

Electrocatalysts for Energy ConversionHydrogen Storage and MaterialsMetalloenzymes and iron-sulfur proteins

DNA interaction of europium(III) complex containing 2,2′-bipyridine and its antimicrobial activity

Shohreh Jahani、Mozhgan Khorasani-Motlagh、Meissam Noroozifar2015-06-08Journal of Biomolecular Structure and Dynamics

The interaction of native fish salmon DNA (FS-DNA) with [Eu(bpy)3Cl2(H2O)]Cl, where bpy is 2,2'-bipyridine, is studied at physiological pH in Tris-HCl buffer by spectroscopic methods, viscometric techniques as well as circular dichroism (CD). These experiments reveal that Eu(III) complex has interaction with FS-DNA. M…

Metal complexes synthesis and propertiesLanthanide and Transition Metal ComplexesProtein Interaction Studies and Fluorescence Analysis

Mechanism of Oxygen Atom Transfer from FeV(O) to Olefins at Room Temperature

Kundan K. Singh、Mrityunjay K. Tiwari、Basab Bijayi Dhar 等 5 位作者2015-06-08Inorganic Chemistry

In biological oxidations, the intermediate Fe(V)(O)(OH) has been proposed to be the active species for catalyzing the epoxidation of alkenes by nonheme iron complexes. However, no study has been reported yet that elucidates the mechanism of direct O-atom transfer during the reaction of Fe(V)(O) with alkenes to form th…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsCO2 Reduction Techniques and Catalysts

Aerosol‐Jet Printed Flexible Organic Photodiodes: Semi‐Transparent, Color Neutral, and Highly Efficient

Ralph Eckstein、Tobias Rödlmeier、Tobias Glaser 等 7 位作者2015-06-08Advanced Electronic Materials

Fully aerosol-printed flexible semitransparent organic photodiodes (OPDs) are presented that have specific detections >1 × 1011 Jones from 400 to 750 nm, spectral response of 0.26 A W−1, and bandwidths up to 300 kHz. The devices are prepared in an inverted architecture without the use of indium tin oxide (ITO) or fabr…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Accelerating magnetic resonance fingerprinting (MRF) using t-blipped simultaneous multislice (SMS) acquisition

Huihui Ye、Dan Ma、Yun Jiang 等 8 位作者2015-06-08Magnetic Resonance in Medicine

PURPOSE: We incorporate simultaneous multislice (SMS) acquisition into MR fingerprinting (MRF) to accelerate the MRF acquisition. METHODS: The t-Blipped SMS-MRF method is achieved by adding a Gz blip before each data acquisition window and balancing it with a Gz blip of opposing polarity at the end of each TR. Thus th…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesNMR spectroscopy and applications

Strain dependence on polarization properties of AlGaN and AlGaN-based ultraviolet lasers grown on AlN substrates

Zachary Bryan、Isaac Bryan、Seiji Mita 等 6 位作者2015-06-08Applied Physics Letters

Since the band ordering in AlGaN has a profound effect on the performance of UVC light emitting diodes (LEDs) and even determines the feasibility of surface emitting lasers, the polarization properties of emitted light from c-oriented AlGaN and AlGaN-based laser structures were studied over the whole composition range…

ZnO doping and propertiesGaN-based semiconductor devices and materialsPlasma Diagnostics and Applications

Plasmon-Electrical Effects on Organic Solar Cells by Incorporation of Metal Nanostructures

Wallace C. H. Choy、Xingang Ren2015-06-08IEEE Journal of Selected Topics in Quantum Electronics

Recently, plasmonic effects of metal nanostructures have been intensively exploited to enhance the performance of organic solar cells (OSCs). The plasmonic-optical effects of localized surface plasmon resonances, scattering effect and propagating surface plasmon resonances, etc., are well recognized in considerably en…

Organic Electronics and PhotovoltaicsQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications

Atomistic and Coarse Grain Topologies for the Cofactors Associated with the Photosystem II Core Complex

Djurre H. de Jong、Nicoletta Liguori、Tom van den Berg 等 6 位作者2015-06-08The Journal of Physical Chemistry B

Electron transfers within and between protein complexes are core processes of the electron transport chains occurring in thylakoid (chloroplast), mitochondrial, and bacterial membranes. These electron transfers involve a number of cofactors. Here we describe the derivation of molecular mechanics parameters for the cof…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies

Fluorescence Enhancement/Quenching Based on Metal Orbital Control: Computational Studies of a 6-Thienyllumazine-Based Mercury Sensor

Akef T. Afaneh、Georg Schreckenbach2015-06-08The Journal of Physical Chemistry A

To understand the sensing behaviors of molecular fluorescent probes, lumazine (Lm) and 6-thienyllumazine (TLm) and their complexation with metal(II) ions ([(L)nM(H2O)m](2+), M = Cd(2+) and Hg(2+)) were examined by scalar relativistic density functional theory (DFT). A red shifting from L to [(L)nM(H2O)m](2+) was found…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSynthesis and Biological Evaluation

In Situ Synthesis of Monodisperse Silver Nanoparticles on Sulfhydryl-Functionalized Poly(glycidyl methacrylate) Microspheres for Catalytic Reduction of 4-Nitrophenol

Wenchao Zhang、Yan Sun、Lin Zhang2015-06-08Industrial & Engineering Chemistry Research

Immobilization of silver nanoparticles (Ag NPs) to improve monodispersity and recyclability is crucial for applications in nanocatalysts. Herein, a novel protocol for stabilizer-free, effective, and in situ synthesis of Ag NPs on sulfhydryl-functionalized poly(glycidyl methacrylate) microspheres (PGMA-SH) was proposed…

Advanced Photocatalysis TechniquesNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Synthesis of lithium polyhydrides above 130 GPa at 300 K

Charles Pépin、Paul Loubeyre、F. Occelli 等 4 位作者2015-06-08Proceedings of the National Academy of Sciences

The prediction of novel lithium hydrides with nontraditional stoichiometries at high pressure has been seminal for highlighting a promising line of research on hydrogen-dense materials. Here, we report the evidences of the disproportionation of LiH above 130 GPa to form lithium hydrides containing H2 units. Measuremen…

Advanced Chemical Physics StudiesHigh-pressure geophysics and materialsHydrogen Storage and Materials