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Effect of different preparation routes on the structure and properties of rigid polyurethane‐layered silicate nanocomposites

Tim Woo、Peter J. Halley、Darren J. Martin 等 4 位作者2006-08-23Journal of Applied Polymer Science

Abstract To identify the effect of reactive preparation on the structure and properties of rigid polyurethane (PU)‐layered silicate nanocomposite, a range of nanocomposites were prepared by combining the various precursors in different sequences. The morphology of the samples was characterized by XRD and TEM. Tensile…

Concrete and Cement Materials ResearchPolymer Nanocomposites and PropertiesPolymer composites and self-healing

New Intermetallic Compounds Nd4Co2Mg3 and Sm4Co2Mg3 – an Intergrowth of AlB2 and CsCl Related Slabs

Selcan Tuncel、Rolf‐Dieter Hoffmann、Birgit Heying 等 5 位作者2006-08-23Zeitschrift für anorganische und allgemeine Chemie

Abstract The new magnesium based intermetallic compounds Nd 4 Co 2 Mg 3 and Sm 4 Co 2 Mg 3 were synthesized by induction melting of the elements in sealed tantalum tubes in a water‐cooled sample chamber. The compounds were studied by X‐ray powder and single crystal diffractometer data: P 2/ m , a = 765.42(14), b = 380…

Rare-earth and actinide compoundsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Isothermal crystallization kinetics of PEEK/Vectra® blends by DSC and time‐resolved synchrotron X‐ray diffraction

Mohammed Naffakh、Marián A. Gómez‐Fatou、Gary Ellis 等 4 位作者2006-08-23Polymer Engineering and Science

Abstract Thermal properties of blends of poly(aryl ether ether ketone), PEEK, with a thermotropic liquid crystalline polymer, Vectra®, were investigated by differential scanning calorimetry and X‐ray diffraction techniques. Isothermal crystallization experiments were performed over a wide range of crystallization temp…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Three-phase electromagnetic filter for zero-sequence harmonics

Fernando Nunes Belchior、J.F.V. Ferreira、José Carlos de Oliveira 等 5 位作者2006-08-23IEEE Transactions on Magnetics

This paper proposes a shunt electromagnetic filter to attenuate zero-sequence harmonic injection into three-phase star-grounded supplies. The device is built on the basis of zigzag windings and a three-leg core-type magnetic arrangement. Physical considerations as well as mathematical modeling and computer implementat…

Power Quality and HarmonicsMagnetic Properties and ApplicationsElectromagnetic Compatibility and Noise Suppression

Preparation and Reactivity of Pendent- --CO2RhIII(phthalocyanine) Bound to a Poly(acrylate) Backbone. Effects of the Hypercoiled Backbone on the Association, Photochemical, and Thermal Redox Reactions of the Pendent Macrocycle

Salini Thomas、Gustavo T. Ruiz、G. Ferraudi2006-08-23Macromolecules

Poly(acrylate) was derivatized with Rh III (pc) (pc = phthalocyanine) and the morphology of the strands was established by AFM microscopy. The strands of the polymer, poly-Rh III (pc), were seen as the strings of spherules expected for an hypercoiled poly(acrylate) backbone. Phthalocyanine pendants in a polymer, poly-…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

Switchable thin‐film surface prepared via a simple grafting‐to method using a polystyrene‐b‐poly(2‐vinylpyridine) copolymer

Ying Wang、Joseph X. Zheng、William J. Brittain 等 4 位作者2006-08-23Journal of Polymer Science Part A Polymer Chemistry

Abstract A polystyrene‐ b ‐poly(2‐vinylpyridine) block copolymer containing a methylhydridosilane linking group was chemically grafted to an 8‐trichlorosilyloctene monolayer via a simple one‐step hydrosilylation reaction. The resulting Y‐shaped thin film exhibited a low grafting density, which was characteristic of th…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Study of the Crystallinity of Polyesters Derived from the Glycolysis of PET

Gaël Colomines、Arie van der Lee、Jean‐Jacques Robin 等 4 位作者2006-08-23Macromolecular Chemistry and Physics

Abstract Summary: The crystallinity of a glycolysate obtained by glycolysis of PET with diethylene glycol (DEG) was qualitatively studied by optical microscopy using a polarizer and quantitatively by X‐ray diffraction. Moreover, the rheological behavior of this glycolysate was also studied in relation with its crystal…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Synergistic efficiency of combined HALS–UV absorber polymerizable stabilizers

Vladimir B. Bojinov2006-08-23Journal of Applied Polymer Science

Abstract The influence of combined 2,2,6,6‐tetra methylpiperidine  2‐hydroxyphenyl‐benzotriazole [1,3,5]triazine polymerizable stabilizers on the photostability of their copolymers with methyl methacrylate as well as the interaction of the photoreactive HALS and UV absorber fragments in the combined molecules have be…

Advanced Polymer Synthesis and CharacterizationSynthesis and properties of polymersPhotopolymerization techniques and applications

Effect of sulfonic group on solubility parameters and solubility behavior of poly(2,6‐dimethyl‐1,4‐phenylene oxide)

Chunli Gong、Rong Guan、Yao‐Chi Shu 等 5 位作者2006-08-23Polymers for Advanced Technologies

Abstract An investigation on the effect of sulfonic group on solubility parameters and solubility behavior of poly(2,6‐dimethyl‐1,4‐phenylene oxide) (PPO) is presented. Sulfonated PPO (SPPO) was prepared using chlorosulfonic acid as a sulfonating agent. The structure of SPPO was confirmed by FT‐IR, and the ion exchang…

Fuel Cells and Related MaterialsConducting polymers and applicationsSynthesis and properties of polymers

Synthesis and characterization of novel hyperbranched polybenzimidazoles based on an AB2 monomer containing four amino groups and one carboxylic group

Z. X. Li、Jing Liu、Shuguang Yang 等 6 位作者2006-08-23Journal of Polymer Science Part A Polymer Chemistry

Abstract A new kind of AB 2 monomer, 4‐[2,6‐bis(3,4‐diaminophenyl)pyridin‐4‐yl]benzoic acid, was synthesized, and several hyperbranched polybenzimidazoles (HPBIs) were prepared through self‐polymerization followed by modification reactions with end‐capping reagents such as 4‐methyl benzoic acid and 3‐[3,5‐bis(trifluor…

Conducting polymers and applicationsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Preparation and characterization of PVA/OMMT composites

Caner Yürüdü、Sevim İşçi、Cüneyt H. Ünlü 等 6 位作者2006-08-23Journal of Applied Polymer Science

Abstract In this study, polyvinyl alcohol/organically modified montmorillonite (HDA/MMT; organoclay) composite was prepared for the intercalation processes. Firstly, the rheological behavior of aqueous montmorillonite dispersions was investigated as a function of solid content. Hexadecylamine (HDA) was added to the mo…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesDielectric materials and actuators

Synthesis and characterization of poly(ϵ‐caprolactone)–poly(L‐lactide) diblock copolymers with an organic amino calcium catalyst

Longhai Piao、Jingru Sun、Zhiyuan Zhong 等 7 位作者2006-08-23Journal of Applied Polymer Science

Abstract The quasiliving characteristics of the ring‐opening polymerization of ϵ‐caprolactone (CL) catalyzed by an organic amino calcium were demonstrated. Taking advantage of this feature, we synthesized a series of poly(ϵ‐caprolactone) (PCL)–poly( L ‐lactide) (PLA) diblock copolymers with the sequential addition of…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

A comparison of single-layer coaxial coil mutual inductance calculations using finite-element and tabulated methods

T.G. Engel、Stacy Rohe2006-08-23IEEE Transactions on Magnetics

Quick and accurate methods to calculate the mutual inductance of coaxial single layer coils remains important to this day in a large variety of engineering and physical disciplines. While modern finite-element electromagnetic field codes can do this accurately, the engineer often requires only a first- or second-order…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsElectromagnetic Compatibility and Noise Suppression

Effect of composite preparation techniques on electrical and mechanical properties and morphology of nylon 6 based conductive polymer composites

Özcan Köysüren、Sertan Yeşil、Göknur Bayram2006-08-23Journal of Applied Polymer Science

Abstract Nylon 6/carbon black conductive composites were prepared using two different methods, masterbatch dilution and melt mixing. Their effect on the size and distribution of carbon black agglomerates in the matrix was studied in terms of electrical and mechanical properties and morphology. The electrical resistivi…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesConducting polymers and applications

Thermally bonded nonwoven filters composed of bi‐component polypropylene/polyester fiber. II. Relationships between fabric area density, air permeability, and pore size distribution

X. Y. Wang、R.H. Gong2006-08-23Journal of Applied Polymer Science

Abstract The relationships between the pore size, fabric area density, and air permeability of the three‐dimensional (3D) nonwoven filter samples produced using a new 3D forming process has been studied. Results indicate that the thermally bonded nonwoven filter samples consist of multiple filtration layers of interco…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesTextile materials and evaluations

Flame retardancy and nondripping properties of ammonium polyphosphate/poly(butylene succinate) composites enhanced by water crosslinking

Chen‐Feng Kuan、Hsu‐Chiang Kuan、M. Chen‐Chi 等 4 位作者2006-08-23Journal of Applied Polymer Science

Abstract Ammonium polyphosphate (APP)/poly(butylene succinate) (PBS) composites were prepared with a unique water‐crosslinking technique to improve the flame retardancy and nondripping properties of the composites and to maintain the main structure of the composites during flame tests. The composites were treated with…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesSilicone and Siloxane Chemistry

MMM: a sequence-to-structure alignment protocol

Brajesh K. Rai、Carlos Madrid-Aliste、J. Eduardo Fajardo 等 4 位作者2006-08-23Bioinformatics

MOTIVATION: Accurate alignment of a target sequence to a template structure continues to be a bottleneck in producing good quality comparative protein structure models. RESULTS: Multiple Mapping Method (MMM) is a comparative protein structure modeling server with an emphasis on a novel alignment optimization protocol.…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Toughening and reinforcement of rigid PVC with silicone rubber/nano‐CACO3 shell‐core structured fillers

Ling Yang、Yuan Hu、Hongxia Guo 等 6 位作者2006-08-23Journal of Applied Polymer Science

Abstract To improve the mechanical properties and structure of poly(vinyl chloride) (PVC)/nano‐CaCO 3 nano composite, a core (nano‐CaCO 3 )/shell (SR) structured filler (40–60 nm) was successfully prepared by refluxing methyl vinyl silicone rubber (SR) and nano‐CaCO 3 particles (coupling agent KH550, KH560, or NDZ‐101…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Processing of Polyacetylene from Aqueous Nanoparticle Dispersions

J. Robert Huber、Stefan Mecking2006-08-23Angewandte Chemie International Edition

Printed circuits: Aqueous polyacetylene dispersions were prepared by catalytic polymerization of acetylene in an aqueous emulsion with a cationic palladium catalyst with a bulky diphosphine ligand. Facile processing is demonstrated by ink-jet printing of the conductive-polymer dispersions to produce a functioning elec…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsPhotochromic and Fluorescence Chemistry

Highly Ordered Functional Organosilicas by Template‐Directed Hydrolysis‐Polycondensation of Chiral Camphorsulfonamide Precursors

Benoît Gadenne、Peter Hesemann、Vivek Polshettiwar 等 4 位作者2006-08-23European Journal of Inorganic Chemistry

Abstract Trialkoxysilylated camphorsulfonamides have been used for the synthesis of functional organosilicas in a template‐directed hydrolysis‐polycondensation with tetraethylorthosilicate (TEOS). The sol–gel transformation leading to the formation of highly ordered materials indicates that trialkoxysilylated camphors…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods