Materials Literature
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The paper outlines a method for comparing the tightness of two woven fabrics. The tightness of a woven fabric is determined with reference to the nearest maximum-sett fabric to the given fabric. The purpose is not to categorise woven fabrics in terms of their tightness but to enable fabrics to be designed with referen…
This paper describes the parameters recommended for rational design of amphiphile-based drug carriers. The main advantage of a carrier is its ability to modify the pharmacokinetics and biodistribution of the drug, so that the drug level at the target is sufficient for therapeutic benefits. Three parameters are describ…
Chicken mitochondrial and Escherichia coli aspartate aminotransferases K258H, in which the active site lysine residue has been exchanged for a histidine residue, retain partial catalytic competence [Ziak et al. (1993) Eur. J. Biochem. 211, 475-484]. Mutant PLP and PMP holoenzymes and the complexes of the latter (E. co…
Novel nis(l,3-dithiole) donors ( 4) and ( 5) containing thiophene spacer units have been prepared.The cyclic voltammograms indicate that 4 and 5 are oxidized to mcation radicals and terracations, respectively, and on-site Coulombic repulsion in the dication state is reduced.An electroactive polymer was formed from 4c.…
Abstract A structural study was carried out on poly(α‐butyl β‐ L ‐aspartate), which is a stereoregular nylon‐3 derivative with an alkoxycarbonyl group attached to the β‐carbon of the main‐chain repeating unit. Two crystal forms, namely hexagonal and tetragonal, made of 13/4 and 4/1 helices, respectively, and bearing a…
Amorphous, mesoporous titania–silica aerogels with high Ti dispersion, synthesised using a sol–gel process followed by semicontinuous extraction with supercritical CO2, are shown to be excellent catalysts for the epoxidation of bulky cyclic olefins.
A considerable amount of work has been carried out on stress relaxation phenomenon in polymers, particularly, polymeric fibres. However, there is almost no published work available on a newly observed phenomenon, known as ‘Inverse Relaxation’. The theoretical work on stress relaxation carried out until now has been ba…
We report experimental evidence for the divergence of the collective diffusion coefficient in a quasi-two-dimensional fluid. The system studied is a monolayer of nearly monodisperse self-assembled disks of the diblock copolymer polystyrene-b-polymethylmethacrylate, supported in the air/water interface, and the method…
Bacterial cellulose (BC) is produced by some strains of Acetobacter. The BC has unique network structure of fine fiber. The BC can be obtained with two typical methods, namely static and agitated culture. We have found some structural differences between these two types of BC. We, therefore, investigated the propertie…
Delayed neointimal healing of a fabric vascular prosthesis was investigated in an animal study focusing on the relationship between red thrombus, fibrinolysis, and endothelialization on the luminal surface. Fabric vascular prostheses were implanted into the descending aortas of 72 dogs. Fifty-nine grafts were explante…
The design of a new electrochromic display based on Langmuir-Blodgett (LB) films of the praseodymium bisphthalocyanine complex is reported. In situ UV-VIS spectra of the display show four colour changes, blue→green→yellowish→red, when a potential ranging from –2 to +2 V is applied. The device retains its colouration u…
Measurements of thermally stimulated currents were made on ionomer/polyethylene blends. The objective of this work was to study space charge formation in these materials. Two ionomers were compared; both ionomers contained methacrylic acid, neutralized by zinc in one and by sodium in the other. A large current peak ce…
Two types of trans-4-alkylcyclohexyl-substituted 2,3-difluorobiphenyls that exhibit quite high smectic C (Sc) phase stability are reported. In addition, the analogous trans-4-alkyl-2,2-difluorocyclohexyl-substituted 2,3-difluorobiphenyls are reported and these materials have much lower Sc character. A useful alternati…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnergy-Consuming Micromechanisms in the Fracture of Glassy Polymers. 2. Effect of Molecular Weight on the Fracture of PolystyreneM. Sambasivam, A. Klein, and L. H. SperlingCite this: Macromolecules 1995, 28, 1, 152–159Publication Date (Print):January 1, 1995Publication Histo…
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The effects of ion bombardment and r.f. plasma oxidation of graphite surfaces on subsequent growth and electronic properties of vacuum deposited palladium clusters have been investigated by methods of X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy with X-ray excitation (XAES). Due to the signif…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT.alpha.-Te2MoO7 as an Active Species in the Vapor-Phase Selective Oxidation of Ethyl Lactate to Pyruvate over TeO2-MoO3 CatalystsHiromu Hayashi, Shigeru Sugiyama, Naoki Masaoka, and Naoya ShigemotoCite this: Ind. Eng. Chem. Res. 1995, 34, 1, 135–139Publication Date (Print):J…
The effects of the cation distribution change on the superexchange parameters and magnetic properties of cobalt ferrite powders were investigated. The cation distribution change of cobalt ferrite powders with quenching treatment was confirmed from the Mossbauer experiments. The exchange interaction parameters, i.e. J/…
A kinetic study has been made on the reaction between a silica-containing alumina graphite refractory and low carbon molten steel by measuring mass loss of the refractory heated at 1100-1600°C and Si content of the molten steel at 1600°C where the refractory was immersed.The results are summarized as follows:(1) The r…
Six pregnane glycosides and three cardenolides were isolated as differentiation inducers using mouse myeloid leukemia (Ml) cells from Periplocae Radicis Cortex (bark of Periploca sepium BGE., Asclepiadaceae). The cardenolides showed much higher activities than the pregnane glycosides. Besides these nine compounds, com…