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Catalysis By Gold

Geoffrey C. Bond、Catherine Louis、David T. Thompson2006-08-15OpenAlex

Despite occasional references in the older literature to the ability of gold to catalyze certain reactions, the metal has until recently had the reputation of being one of the least catalytically useful. The recent discovery that some supported gold catalysts can affect the oxidation of carbon monoxide at or below amb…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization Studies

Plasma Methods for the Generation of Chemically Reactive Surfaces for Biomolecule Immobilization and Cell Colonization ‐ A Review

Kim S. Siow、Leanne Britcher、Sunil Kumar 等 4 位作者2006-08-15OpenAlex

Abstract Summary: This review surveys methods for the fabrication, by plasma surface treatments or plasma polymerization, of polymeric surfaces and thin plasma polymer coatings that contain reactive chemical groups useful for the subsequent covalent immobilization, by solution chemical reactions or vapor phase graftin…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Solid-State Kinetic Models: Basics and Mathematical Fundamentals

Ammar Khawam、Douglas R. Flanagan2006-08-15OpenAlex

Many solid-state kinetic models have been developed in the past century. Some models were based on mechanistic grounds while others lacked theoretical justification and some were theoretically incorrect. Models currently used in solid-state kinetic studies are classified according to their mechanistic basis as nucleat…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Transport properties of the thermoelectric layered cobalt oxide Pb–Sr–Co–O single crystals

Wataru Kobayashi、Ichiro Terasaki2006-08-14Applied Physics Letters

The authors have synthesized single-crystal samples of the layered cobalt oxide Pb–Sr–Co–O and measured resistivity, thermopower, and Hall coefficient from 4.2to300K. The resistivity, the thermopower, and the Hall coefficient are 13mΩcm, 150μV∕K, and 1.6×10−2cm3∕C at 300K, respectively, which are typical values for a…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsHeusler alloys: electronic and magnetic properties

Manganese impurities in boron nitride

L. V. C. Assali、W.V.M. Machado、João F. Justo2006-08-14Applied Physics Letters

The authors carried an ab initio investigation on the properties of Mn impurities in BN, presenting results on stability, spin states, magnetic moment, hyperfine parameters, and formation and transition energies. Substitutional Mn in the cation site in BN was compared to that in GaN and GaAs. Due to the small BN latti…

ZnO doping and propertiesDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Nanolithography made from water-based spin-coatable LSMO resist

Chih-Min Chuang、Ming‐Chung Wu、Yu‐Ching Huang 等 7 位作者2006-08-14Nanotechnology

A dual functional and water soluble spin-coatable lanthanum strontium manganese oxide (LSMO) resist has been developed that consists of lanthanum nitrate, strontium nitrate, manganese nitrate, polyvinyl alcohol and water. Energetic nitrates plus polyvinyl alcohol fuel promote autoignition and produce nanopatterns (<60…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Enhanced field emission from imprinted carbon nanotube arrays

Peng Liu、Liang Liu、Yang Wei 等 5 位作者2006-08-14Applied Physics Letters

The authors have fabricated patterned carbon nanotube arrays by a simple postgrowth imprinting method. Patterns with size down to 2μm can be formed with appropriate stamps. The imprinted array exhibited greatly enhanced field emission, the turn-on voltage was reduced to 0.9V∕μm from 2.8V∕μm of the as grown sample, and…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesIon-surface interactions and analysis

Direct measurement of composition of buried quantum dots using aberration-corrected scanning transmission electron microscopy

Peng Wang、Andrew Bleloch、M. Falke 等 6 位作者2006-08-14Applied Physics Letters

The authors present a direct method to quantitatively measure the indium composition of buried InAs quantum dots embedded in a GaAs matrix. In this method, spatially resolved electron-energy-loss spectroscopy combined with aberration-corrected scanning transmission electron microscopy at atomic resolution was employed…

Quantum Dots Synthesis And PropertiesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Electrical-stress-induced conductivity increase in SrTiO3 films

Siegfried Karg、G. I. Meijer、Daniel Widmer 等 4 位作者2006-08-14Applied Physics Letters

The charge transport of polycrystalline SrTiO3 films doped with Cr is investigated by means of temperature- and electric-field-dependent current measurements. In particular, the effect of electrical stress on the conduction mechanism is analyzed to understand the forming process of samples exhibiting resistance-switch…

Ferroelectric and Piezoelectric MaterialsAdvanced Memory and Neural ComputingElectronic and Structural Properties of Oxides

AMP‐forming acetyl‐CoA synthetases in Archaea show unexpected diversity in substrate utilization

Cheryl Ingram‐Smith、Kerry S. Smith2006-08-14Archaea

Adenosine monophosphate (AMP)-forming acetyl-CoA synthetase (ACS; acetate:CoA ligase (AMP-forming), EC 6.2.1.1) is a key enzyme for conversion of acetate to acetyl-CoA, an essential intermediate at the junction of anabolic and catabolic pathways. Phylogenetic analysis of putative short and medium chain acyl-CoA synthe…

Enzyme Catalysis and ImmobilizationMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

High hydrogen content complex hydrides: A density-functional study

Ponniah Vajeeston、P. Ravindran、A. Kjekshus 等 4 位作者2006-08-14Applied Physics Letters

Density-functional-theory calculations within the generalized-gradient approximation are used to establish the ground-state structure, optimized geometry, and electronic structure for Mg(AlH4)2 and Mg(BH4)2. Among 28 structural arrangements used as inputs for structural optimization calculations, the experimentally kn…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsBoron and Carbon Nanomaterials Research

Kink Formation and Motion in Carbon Nanotubes at High Temperatures

Jianyu Huang、Shuo Chen、Zhi Ren 等 9 位作者2006-08-14Physical Review Letters

We report that kink motion is a universal plastic deformation mode in all carbon nanotubes when being tensile loaded at high temperatures. The kink motion, observed inside a high-resolution transmission electron microscope, is reminiscent of dislocation motion in crystalline materials: namely, it dissociates and multi…

Carbon Nanotubes in CompositesGraphene research and applicationsForce Microscopy Techniques and Applications

Hexagonal diamond synthesis on h-GaN strained films

Abha Misra、Pawan Tyagi、Brajesh S. Yadav 等 7 位作者2006-08-14Applied Physics Letters

Chemical vapor deposited diamond films grown on strained gallium nitride-coated quartz substrate are found to display a dominantly hexagonal diamond phase. The phase identification is done using Raman spectroscopy and orientation imaging microscopy (OIM). The presence of a 1324.4cm−1 band in the Raman spectra is attri…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Observation of secondary relaxation in a fragile Pd40Ni10Cu30P20 bulk metallic glass

Zuofeng Zhao、Ping Wen、Wei Hua Wang 等 4 位作者2006-08-14Applied Physics Letters

The dynamic elastic moduli in the temperature domain of a Pd40Ni10Cu30P20 bulk metallic glass were measured with dynamic mechanical spectroscopy at frequencies less than 100Hz. The primary relaxation is characterized by a single loss modulus peak and a rapid drop of storage modulus in the metallic supercooled liquid r…

Material Dynamics and PropertiesTheoretical and Computational PhysicsMetallic Glasses and Amorphous Alloys

Migration and redistribution of oxygen vacancy in barium titanate ceramics

L. Chen、Xiangming Xiong、Hui Meng 等 5 位作者2006-08-14Applied Physics Letters

Degradation of barium titanate based multilayer capacitor mainly results from migration and redistribution of oxygen vacancy. For barium titanate ceramics, the authors observe an internal friction relaxation peak around 70°C due to oxygen vacancy, and its relaxation strength differs greatly for specimen aged at 85°C f…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMicrowave Dielectric Ceramics Synthesis

Pengaruh Perlakuan Alkali terhadap Sifat Tarik Bahan Komposit Serat Rami-Polyester

Kuncoro Diharjo2006-08-14Journal of Mechanical Engineering (Institute of Research and Community Outreach Petra Christian University)

The Natural Composite (NACO) is material that has a good potential to be developed in Indonesia.The mechanical bonding of the composite reinforced natural fiber can be increased by using chemical treatment of fiber or by using the addition of coupling agent.The chemical treatment, for example alkali treatment, is ofte…

Natural Fiber Reinforced CompositesMechanical Engineering and Vibrations ResearchMaterial Selection and Properties

Surface morphologies of homoepitaxial ZnO on Zn- and O-polar substrates by plasma assisted molecular beam epitaxy

Huaizhe Xu、Keita Ohtani、Miyuki Yamao 等 4 位作者2006-08-14Applied Physics Letters

Homoepitaxial ZnO layers are grown on Zn-polar (0001) and O-polar (0001¯) surfaces of single crystal ZnO substrates by plasma assisted molecular beam epitaxy. It is found that the growth conditions to obtain smooth surfaces are significantly different for the two surface polarities. For growth on Zn-polar surface, mod…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Phase stability of epitaxially grown Ti2AlN thin films

Markus Beckers、Norbert Schell、R.M.S. Martins 等 5 位作者2006-08-14Applied Physics Letters

The phase stability of Mn+1AXn phase (M: early transition metal, A: A-group element, and X: C and∕or N) Ti2AlN thin films reactively sputtered onto MgO(111) and Al2O3(0001) substrates has been investigated by in situ x-ray diffraction and Rutherford backscattering. High substrate temperature deposition results in epit…

2D Materials and ApplicationsMetal and Thin Film MechanicsMXene and MAX Phase Materials

Determination of chiral indices of individual single- and double-walled boron nitride nanotubes by electron diffraction

Raúl Arenal、Mathieu Kociak、Annick Loiseau 等 4 位作者2006-08-14Applied Physics Letters

The intensities of electron diffraction patterns from individual (single-, double-walled) boron nitride nanotubes (BNNTs) as well as from bundles of these tubes have been recorded. The helicities have been systematically measured, and the diameter and the chiral indices have been determined. The analysis of 121 nanotu…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Internal and effective stresses in nanocrystalline electrodeposited Ni

S. Van Petegem、Susanne Brandstetter、H. Van Swygenhoven 等 4 位作者2006-08-14Applied Physics Letters

Stress reduction experiments performed during tensile deformation of nanocrystalline electrodeposited Ni demonstrate high values for the effective and the internal stress as compared to coarse grained metals and evidence the existence of a negative creep. The results are interpreted in terms of a thermally activated d…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced materials and composites