Materials Literature
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Malate dehydrogenases (MDH, L-malate:NAD oxidoreductase, EC 1.1.1.37), catalyze the NAD/NADH-dependent interconversion of the substrates malate and oxaloacetate. This reaction plays a key part in the malate/aspartate shuttle across the mitochondrial membrane, and in the tricarboxylic acid cycle within the mitochondria…
A simple method to fabricate high-quality nanoparticles including spherical carbon onions and elongated fullerene-like nanoparticles similar to nanotubes in large quantities without the use of vacuum equipment is reported. The nanoparticles are obtained in the form of floating powder on the water surface following an…
Abstract This paper describes a test procedure for determining the total surface area of fine-grained soils using the Ethylene Glycol Monoethyl Ether (EGME). The test involves saturating a soil sample with EGME and then removing the excess EGME in a vacuum desiccator, until the EGME forms a monomolecular layer on the…
We study experimentally and numerically the electromagnetic resonances in split ring resonators (SRRs), around 1 GHz. For an individual SRR, we show that both electric and magnetic fields can induce resonances, the magnetic one being the strongest. The utilization of such resonant structures as efficient microwave fil…
Presents a technique to directly excite Luttinger liquid collective modes in carbon nanotubes at gigahertz frequencies. By modeling the nanotube as a nano-transmission line with distributed kinetic and magnetic inductance as well as distributed quantum and electrostatic capacitance, we calculate the complex frequency-…
The calibration of two popular density functionals (B3LYP and BP86) for the prediction of isomer shifts (IS) in 57Fe Mössbauer (MB) spectra is reported. A linear correlation between non-relativistically calculated theoretical electron densities and experimentally measured ISs is established. Both functionals lead to a…
Fundamental features of microbial cellulose utilization are examined at successively higher levels of aggregation encompassing the structure and composition of cellulosic biomass, taxonomic diversity, cellulase enzyme systems, molecular biology of cellulase enzymes, physiology of cellulolytic microorganisms, ecologica…
The title compound, C(21)H(37)NO(2), is a new amphiphilic pyrrole with a long hydrocarbon chain, which will be used as a precursor for the synthesis of Langmuir-Blodgett films of porphyrins. Molecules related by an inversion centre are joined head-to-head into dimers by strong N-H.O hydrogen bonds. The dimers pack in…
The spectral and lasing parameters of solid laser elements made of a nanoporous glass — polymer composite doped with phenalemine dyes are studied. A high conversion efficiency (35%— 40%) of second-harmonic nanosecond pulses from a Nd 3+ :YAG laser to the 600 — 660-nm region was obtained and a large operating life of t…
A cationic iron(III) complex [Fe III (5-OMe-sal 2 trien] + (where [H 2 (5-OMe-sal) 2 trien] was derived from triethylenetetramine and substituted salicylaldehyde), designed to undergo spin crossover, has been inserted in the layered MnPS 3 host lattice. The magnetic properties of the resulting intercalation compound […
The kinetics of sonochemical oxidation of CS 2 and the effects of process parameters (e.g., concentration, pH, temperature, ultrasonic intensity, irradiation medium, dissolved gas and time, etc.) on the degradation rates and product distributions were studied in a batch reactor at 20 kHz. Sonochemical oxidation was fo…
The title compound (systematic name: 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0(3,11).0(5,9)]dodecane), C(6)H(6)N(4)O(8), exhibits the highest density among known N-nitramines, due to its close-packed crystal structure. It may be regarded as consisting of a distorted hexagonal close-packed lattice for…
The mesoporous melamine−formaldehyde resin was synthesized in the process of polymerization in the presence of fumed silica as an inorganic template. To differentiate the surface properties, the polymer sample was modified by applying 2-methyl-1-butanol. The surface and structural characteristics of obtained sorbents…
Data on the structure, polymorphism, phase equilibria, growth techniques, properties and applications of single crystals of the low-temperature modification of barium borate are analysed. The bibliography includes 201 references.
The preparation of two new compounds containing the cluster [Ni(21)(cit)(12)(OH)(10)(H(2)O)(10)](16-) is presented, together with a detailed magnetic investigation of one of the compounds. We found that this cluster shows an unexpected stability and that it exists as different stereoisomers. Compound 1 contains the ac…
The integer quantum Hall effect (QHE) and one-dimensional Anderson localization (AL) are limiting special cases of a more general phenomenon, directed localization (DL), predicted to occur in disordered one-dimensional wave guides called "quantum railroads" (QRR). Here we explain the surprising results of recent measu…
Palladium 15-20 nm particles stabilized by a Keggin-type polyoxometalate were prepared by reduction of K(5)PPdW(11)O(39) with H(2). The nanoparticles were shown to be effective catalysts for Suzuki-, Heck-, and Stille-type carbon-carbon coupling and carbon-nitrogen coupling reactions of bromoarenes in aqueous media. C…
The chemisorption of atomic hydrogen on the single-walled armchair carbon nanotube is studied with ab initio calculations. A single H atom is found to be chemisorbed on both the inside and outside wall of the nanotube. The binding energy of H adsorption at the exterior of the nanotube is much greater than that at the…
In this study, we report structural, vibrational, and magnetic data providing evidence of random ion displacement in the core of CdSe quantum dots on the Cd(2+) sites by Co(2+) ions (between x = 0 and 0.30). Structural evidence for core doping is obtained by analyzing the powder X-ray diffraction (pXRD), data which ex…
Reduction of platinum acetylacetonate and thermodecomposition of cobalt carbonyl in the presence of 1-adamantanecarboxylic acid were employed in different coordinating mixtures to produce monodisperse, highly crystalline CoPt(3) nanoparticles. The mean particle size can be varied from 1.5 to 7.2 nm by controlling the…