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Effects of .ALPHA./.GAMMA. phase ratio and N addition on the corrosion resistance of Si-bearing duplex stainless steel in nitric acid.

Haruhiko Kajimura、Kazuhiro Ogawa、Hiroo Nagano1991-01-01ISIJ International

Duplex stainless steel is widely used in various service conditions due to its high mechanical properties and high corrosion resistance. However, there have been few studies on the corrosion resistance of duplex stainless steel in highly oxidizing nitric acid, such as hot nitric acid containing Cr6+ ions. In this stud…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

The Dynamic Mechanical Response of Carpets: An Alternative Measurement Technique

J. I. Dunlop、Jie Sun1991-01-01Journal of the Textile Institute

The dynamic-compression properties of carpet are expected to play an important role in their mechanical performance, but it is difficult to measure these properties at frequencies and pressures corresponding to those occurring in carpet wear. A new vibration technique has been developed which enables the dynamic modul…

Textile materials and evaluationsEffects of Vibration on HealthMechanical Engineering and Vibrations Research

Structural properties of the oxide superconductors: the critical role of defects

J. D. Jorgensen、Philip Lightfoot、Shiyou Pei1991-01-01Superconductor Science and Technology

Structural data have contributed greatly to the understanding of the oxide superconductors. However, it is increasingly clear that a knowledge of the average structure is not sufficient. Structural defects, which are present in essentially all of these systems, have a profound effect on the superconducting properties.

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Variable Step-Counting Times for Rietveld Analysis, or, Getting the Most Out of Your Experiment Time

Ian C. Madsen、R. J. Hill1991-01-01Advances in X-ray Analysis

Abstract The magnitudes of the peak intensities in a powder diffraction pattern are not uniformly distributed as a function of diffraction angle. The Lorentz-polarization factor, X-ray form-factor and the thermal vibration parameters all conspire to progressively decrease the intensities of the peaks as sinθ/λ increas…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Constant-current corona charging of Teflon PFA

Xia Zhang-Fu、Ding Hai、Yang Guo-Mao 等 5 位作者1991-01-01IEEE Transactions on Electrical Insulation

Experiments in which 25- mu m-thick films of tetrafluoroethylene-per-fluoromethoxyethylene copolymer (Teflon PFA) were charged positively and negatively with a constant-current corona at different temperatures and subsequently discharged are discussed. The time behaviors of surface potential, total current, and conduc…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Diffusion of bis(2-ethylhexyl) phthalate above and below the glass transition temperature of poly(vinyl chloride)

Robson F. Storey、Kenneth A. Mauritz、Brian B. Cole1991-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDiffusion of bis(2-ethylhexyl) phthalate above and below the glass transition temperature of poly(vinyl chloride)Robson F. Storey, Kenneth A. Mauritz, and Brian B. ColeCite this: Macromolecules 1991, 24, 2, 450–454Publication Date (Print):January 1, 1991Publication History P…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Science and PVC

Nitrosyl–nitro redox couples with metal phthalocyanines: synthesis and characterization of nitro derivatives of cobalt and iron phthalocyanine, dioxygen activation, oxygen-atom transfer and stoichiometric and catalytic oxidation of terminal olefins

Claudio Ercolani、A. Paoletti、Giovanna Pennesi 等 4 位作者1991-01-01Journal of the Chemical Society Dalton Transactions

The complexes [Co(pc)(NO2)(py)]·dce, [Co(pc)(NO2)(py)]·thf, and [Fe(pc)(NO2)(py)](pc = phthalocyaninate, py = pyridine, dce = 1,2-dichloroethane and thf = tetrahydrofuran) have been isolated as stable crystalline materials. Their molecular and electronic structures have been investigated by IR and UV/VIS spectra, X-ra…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Hydrodynamic properties of polystyrene in dilute n-butyl chloride solution

M. Lewis、Shouyan Nan、Jimmy W. Mays1991-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHydrodynamic properties of polystyrene in dilute n-butyl chloride solutionMichael E. Lewis, Shouyan Nan, and Jimmy W. MaysCite this: Macromolecules 1991, 24, 1, 197–200Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 J…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Science and PVC

Hydrometallation of alkenes and alkynes by the combination of cobalt(II) porphyrins, NaBH4 and oxidizing agents

Jun‐ichiro Setsune、Yoshihiro Ishimaru、Tohru Moriyama 等 4 位作者1991-01-01Journal of the Chemical Society Chemical Communications

Various organocobalt(III) porphyrins have been synthesized in good yields through the hydrometallation of a hypothetical hydridocobalt(III) porphyrin intermediate.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsSurface Chemistry and Catalysis

Copper(II) oxide supported on alumina: interaction of copper ions with hydroxyl groups of alumina

Édouard Garbowski、Michel Primet1991-01-01Journal of the Chemical Society Chemical Communications

The state of CuO deposited on alumina depends on the copper loading: at low loadings (CuO content smaller than 6 wt%), copper is present in the form of Cu2+ ions formed by exchange with the hydrogen atoms of the alumina hydroxyl groups, whereas at high loadings, the formation of bulk copper oxide is observed and the h…

Copper-based nanomaterials and applicationsChemical and Physical Properties of Materials

Mechanical constraints on aperture form in gastropods

Rihito Morita1991-01-01Journal of Morphology

Gastropod apertures reflect expanded states of their mantle edge under variable boundary conditions. The apertures are divided into two groups: apertures without distinct overlap zones (e.g., whorl overlap) and those with overlap zones. Each group follows a unique morphological rule. Apertures without overlap zones ar…

Diatoms and Algae ResearchMarine Biology and Environmental ChemistryModular Robots and Swarm Intelligence

Porphyrinatoiron-catalysed reduction of styrene with sodium borohydride: proposed σ-alkyliron( III ) complex as an intermediate

Koji Kano、Masayuki Takeuchi、Shizunobu Hashimoto 等 4 位作者1991-01-01Journal of the Chemical Society Chemical Communications

5,10,15,20-Tetrakis(para-substituted phenyl)porphyrinatoiron(III) chloride complexes catalyse the reduction of styrene with NaBH4 to ethylbenzene and 2,3-diphenylbutane and the precursor is assumed to be the σ-alkyl complex (Xtpp)FeIII–PhCHMe.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryHemoglobin structure and function

Enhancement of Magnetic Properties of Sm(Fe, Co, Ti)<SUB>12</SUB> Melt-Spun Ribbons by Refining Crystallized Grains

Satoshi Sugimoto、Akihiko Kojima、Masuo Okada 等 4 位作者1991-01-01Materials Transactions JIM

Present works describe the improvement of the magnetic properties of Sm(Fe, Ti)12 melt-spun ribbons with ThMn12-type structure. In order to increase the remanence, the Ti content was decreased and the heat treatment temperature and time were lowered and shortened, respectively. As a result, the maximum energy products…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Synthesis and study of thermal and electrical behaviour of some polyaromatic amines

Beena Rawat、S. Kansara、H. S. Rama1991-01-01Polymer International

Abstract Samples of polyaromatic amines were synthesised by chemical and electrochemical methods, using different amounts of electrolytes for the purpose of doping the polymer. These polymers were found to show electrical conductivity in the range 10 −12 –10 −6 S/cm. A study of conductivity at various temperatures ind…

Fuel Cells and Related MaterialsConducting polymers and applicationsSynthesis and properties of polymers

Crystallization behaviour of isotactic polypropylene/linear low density polyethylene blends

Long Yu、Z. H. Stachurski、Robert A. Shanks1991-01-01Polymer International

Abstract Crystallization behaviour of isotactic polypropylene/linear low density polyethylene (iPP/LLDPE) blends has been investigated by optical microscopy and DSC. Crystallization of iPP depends upon blend composition and thermal history. When blended with LLDPE, the crystallization temperature of iPP, T c , decreas…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

PPP‐VB Theory of π‐Electron Systems: Electron Delocalization, Molecular Symmetry, and Resonance

Josef Paldus、Xiangzhu Li1991-01-01Israel Journal of Chemistry

Abstract Relying on a semiempirical Pariser‐Parr‐Pople (PPP) model, it is shown that classical valence bond (VB) theory, using only a few covalent structures, can provide highly correlated energies and wave functions and thus a useful description of a molecular electronic structure, assuming that it is based on approp…

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchInorganic Fluorides and Related Compounds

Effects of frequency, molecular weight and thermal oxidation on the dynamic mechanical response of poly (ethylene oxide)

Stephen W. Bigger、John Scheirs、O. Delatycki 等 4 位作者1991-01-01Polymer International

Abstract The technique of dynamic mechanical thermal analysis (DMTA), operated in the dual cantilever mode, was used to characterize the effects of frequency, crystallinity, molecular weight (MW) and the extent of thermal oxidation on the dynamic mechanical response of poly(ethylene oxide) (PEO). The glass transition…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

New interpretation of the IR reflectance spectra of SiO2-rich films on soda-lime glass

F. Geotti‐Bianchini、L. Riu、Gagliardi, Giovanni 等 5 位作者1991-01-01TIB Repositorium

A new interpretation of the reflectance spectra of weathered or silica-coated soda-lime glass between 1250 and 900 cm<sup>-1</sup> is suggested. Traditionally, the presence and intensity of each spectral band observed were attributed to the concentration of a given chemical species in the film. Contributions due to th…

Glass properties and applications

Results of the Fracture Toughness Test Round Robin on Ceramics

Hideo Awaji、Tatsuya Yamada、Hiroshi Okuda1991-01-01Journal of the Ceramic Society of Japan

This report describes the results of VAMAS international round robin test for evaluating fracture toughness of ceramics. Thirteen laboratories in Japan, France, Germany, UK, Canada, Belgium and CEC (JRC Petten) took part in the test. The values of fracture toughness obtained by the SEPB, the IF and the IS methods were…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsInnovative concrete reinforcement materials