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Imaging Nitrogen in Individual Carbon Nanotubes

Jigang Zhou、Jian Wang、Hao Liu 等 6 位作者2010-05-17The Journal of Physical Chemistry Letters

Semiquantitative chemical imaging of the spatial distribution of nitrogen in a carbon matrix, adsorbed/intercalated N 2, and highly concentrated N 2 in nitrogen-doped carbon nanotubes (N-CNTs) with a spatial resolution of 30 nm has been obtained by scanning transmission X-ray microscopy (STXM). The local electronic st…

Electrocatalysts for Energy ConversionCarbon Nanotubes in CompositesGraphene research and applications

Electronic correlations and unusual superconducting response in the optical properties of the iron chalcogenideFeTe0.55Se0.45

C. C. Homes、Ana Akrap、Jinsheng Wen 等 7 位作者2010-05-17Physical Review B

The in-plane complex optical properties of the iron-chalcogenide superconductor ${\text{FeTe}}_{0.55}{\text{Se}}_{0.45}$ have been determined above and below the critical temperature ${T}_{c}=14\text{ }\text{K}$. At room temperature the conductivity is described by a weakly interacting Fermi liquid; however, below 100…

Iron-based superconductors research

Stripes of increased diamagnetic susceptibility in underdoped superconductingBa(Fe1−xCox)2As2single crystals: Evidence for an enhanced superfluid density at twin boundaries

Beena Kalisky、J. R. Kirtley、James G. Analytis 等 7 位作者2010-05-17Physical Review B

Superconducting quantum interference device microscopy shows stripes of increased diamagnetic susceptibility in the superconducting state of twinned, orthorhombic, underdoped crystals of $\text{Ba}{({\text{Fe}}_{1\ensuremath{-}x}{\text{Co}}_{x})}_{2}{\text{As}}_{2}$, but not in tetragonal overdoped crystals. These str…

Rare-earth and actinide compoundsCorporate Taxation and AvoidanceIron-based superconductors research

Colloidal Synthesis of Non‐Equilibrium Wurtzite‐Type MnSe

Ian T. Sines、Rajiv Misra、P. Schiffer 等 4 位作者2010-05-17Angewandte Chemie International Edition

Stabilizing an elusive phase: The wurtzite polymorph of the magnetic semiconductor MnSe, which is also the x=1 end member of the widely studied Zn1−xMnxSe solid solution, was synthesized in high yield for the first time as colloidal nanoparticles using a solution chemistry technique at low temperature (see pictures).…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Chemistry on Electrospun Polymeric Nanofibers: Merely Routine Chemistry or a Real Challenge?

Seema Agarwal、Joachim H. Wendorff、Andreas Greiner2010-05-17Macromolecular Rapid Communications

Nanofiber-based non-wovens can be prepared by electrospinning. The chemical modification of such nanofibers or chemistry using nanofibers opens a multitude of application areas and challenges. A wealth of chemistry has been elaborated in recent years on and with electrospun nanofibers. Known methods as well as new met…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

TEMPO Electromediated Oxidation of Some Polysaccharides Including Regenerated Cellulose Fiber

Takuya Isogai、Tsuguyuki Saito、Akira Isogai2010-05-17Biomacromolecules

Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of the C6 primary hydroxyls of Curdlan and amylodextrin were converted to sodium carboxylate groups by this method. Molecul…

Advanced Cellulose Research StudiesEnzyme-mediated dye degradationDyeing and Modifying Textile Fibers

Improved electroluminescence from n-ZnO/AlN/p-GaN heterojunction light-emitting diodes

Jingbi You、X. W. Zhang、S. G. Zhang 等 12 位作者2010-05-17Applied Physics Letters

n-ZnO/p-GaN heterojunction light-emitting diodes with and without a sandwiched AlN layer were fabricated. The electroluminescence (EL) spectrum acquired from the n-ZnO/p-GaN displays broad emission at 650 nm originating from ZnO and weak emission at 440 nm from GaN, whereas the n-ZnO/AlN/p-GaN exhibits strong violet e…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Phase Behavior of Nonfrustrated ABC Triblock Copolymers: Weak and Intermediate Segregation

Jian Qin、Frank S. Bates、David C. Morse2010-05-17Macromolecules

The phase behavior of ABC triblock copolymer melts is studied using weak segregation theory and numerical self-consistent field theory (SCFT). We focus on nonfrustrated systems, with interaction parameters χ AB ≃ χ BC < χ AC . Phase behavior of completely symmetric systems, with χ AB = χ BC and equal A and C volume fr…

Theoretical and Computational PhysicsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Electrochemical investigation of high-performance silane sol–gel films containing clay nanoparticles

F. Deflorian、Stefano Rossi、Michele Fedel 等 4 位作者2010-05-17Progress in Organic Coatings

Silane sol–gel coatings are widely used as adhesion promoters between inorganic substrates, such as metals, and organic coatings. The aim of these pre-treatments is to enhance the corrosion protection performance of the organic coating improving the adhesion to the substrate and acting as a barrier against water and a…

Corrosion Behavior and InhibitionAnalytical Chemistry and SensorsConcrete Corrosion and Durability

Large exchange bias field in the Ni–Mn–Sn Heusler alloys with high content of Mn

Haicheng Xuan、Q. Q. Cao、C. L. Zhang 等 7 位作者2010-05-17Applied Physics Letters

The exchange bias properties have been investigated in bulk Mn50Ni40−xSn10+x (x=0, 0.5, and 1) Heusler alloys with high content of Mn, in which the largest exchange bias field is up to 910 Oe for Mn50Ni40Sn10 alloy. In these alloys, the excess Mn atoms would occupy not only the Sn sites but also the Ni sites, and the…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

notRoles of lattice distortion in (1−x)(Bi0.5Na0.5)TiO3-xBaTiO3 ceramics

Y. S. Sung、J. M. Kim、J. H. Cho 等 6 位作者2010-05-17Applied Physics Letters

Structure property relations in (1−x)(Bi0.5Na0.5)TiO3-xBaTiO3 ceramics were investigated at x=0–10 mol %. A solid solution with either rhombohedral or tetragonal symmetry was confirmed with a morphotropic phase boundary (MPB) at x=5–7 mol %. Grains became small with increasing x possibly due to grain boundary pinning…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Pressure independence of granular flow through an aperture

Maria Alejandra Aguirre、Juan G. Grande、Adriana Calvo 等 5 位作者2010-05-17arXiv

We experimentally demonstrate that the flow rate of granular material through an aperture is controlled by the exit velocity imposed to the particles and not by the pressure at the base, contrary to what is often assumed in previous works. This result is achieved by studying the discharge process of a dense packing of…

Materials ScienceSoft Condensed Matterphysics.flu-dyn

Molecular Dynamics simulations of concentrated aqueous electrolyte solutions

Carles Calero、Jordi Faraudo、Marcel Aguilella-Arzo2010-05-17arXiv

Transport properties of concentrated electrolytes have been analyzed using classical molecular dynamics simulations with the algorithms and parameters typical of simulations describing complex electrokinetic phenomena. The electrical conductivity and transport numbers of electrolytes containing monovalent (KCl), dival…

Materials ScienceSoft Condensed Matterphysics.bio-phChemical Physics

Epitaxially stabilized iridium spinel oxide without cations in the tetrahedral site

Hiromichi Kuriyama、Jobu Matsuno、Seiji Niitaka 等 10 位作者2010-05-17arXiv

Single-crystalline thin film of an iridium dioxide polymorph Ir2O4 has been fabricated by the pulsed laser deposition of LixIr2O4 precursor and the subsequent Li-deintercalation using soft chemistry. Ir2O4 crystallizes in a spinel (AB2O4) without A cations in the tetrahedral site, which is isostructural to lambda-MnO2…

Materials ScienceStrongly Correlated Electrons

Enhanced microwave performance of cobalt nanoflakes with strong shape anisotropy

Fei Ma、Yong Qin、Yunze Li2010-05-17Applied Physics Letters

Co nanoflakes are synthesized through a low temperature hydrothermal method. The single-phased hexagonal close-packed Co nanoflakes have a diameter of several micrometers and a thickness about 80 nm. Magnetic hysteresis loops are quite different along different directions deviating from the nanoflakes plane, which sho…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Dynamic Monte Carlo versus Brownian dynamics: A comparison for self-diffusion and crystallization in colloidal fluids

Eduardo Sanz、Davide Marenduzzo2010-05-17The Journal of Chemical Physics

Here we present a comparative study of dynamic Monte Carlo and Brownian dynamics simulations of colloidal systems with repulsive interactions. We show that if the Monte Carlo time is rescaled with the acceptance probability, the estimates of the self-diffusion coefficient and of the crystallization times are, respecti…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Terahertz conductivity peak in composite materials containing carbon nanotubes: Theory and interpretation of experiment

G. Ya. Slepyan、М. В. Шуба、С. А. Максименко 等 5 位作者2010-05-17Physical Review B

A model for the effective conductivity of a dilute and disordered composite material containing randomly single-wall carbon nanotube (SWCNT) inclusions was formulated. The modification of electron transport by the surface curvature of SWCNTs and an axial depolarization effect due to the finite length of metallic SWCNT…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsSemiconductor materials and interfaces

Interatomic exchange coupling of BCC iron

Hai Wang、Pui-Wai Ma、C. H. Woo2010-05-17arXiv

We performed first-principle calculations on the exchange interaction (EI) between atoms in BCC-Fe strained volumetrically. Our results show that the volume-dependence of the EI deviates considerably from the Bethe-Slater curve. This behavior is discussed in terms of the on-site and/or inter-site direct exchange inter…

Materials Sciencephysics.comp-ph

The importance of hole concentration in establishing carrier-mediated ferromagnetism in Mn doped Ge

Shengqiang Zhou、Danilo Bürger、W. Skorupa 等 6 位作者2010-05-17Applied Physics Letters

In the present work, we have prepared Mn-doped Ge using different annealing approaches after Mn ion implantation, and obtained samples with hole concentrations ranging from 1018 to 2.1×1020 cm−3, the latter being the highest reported so far. Based on the magnetotransport properties of Mn doped Ge, we argue that the ho…

ZnO doping and propertiesThin-Film Transistor TechnologiesNanowire Synthesis and Applications

Biodegradable protein‐based films from plant resources: A review

Hongkang Zhang、Gauri S. Mittal2010-05-17Environmental Progress & Sustainable Energy

Abstract This review provides an overview of studies on the film‐forming properties of soy protein, wheat gluten and corn zein. Biodegradable films from these proteins have been investigated extensively. Casting is the most often used film‐forming method. Glycerol is added as plasticizer in many studies. The proteins…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications