Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
A hybrid nanomaterial composed of ZnO nanoparticles (NPs) and CuTCNQ (copper 7,7,8,8-tetracyanoquinodimethane) nanowires (NWs) was successfully fabricated in a simple solution method. The electron field emission properties of the hybrid NWs were dramatically improved over those of raw CuTCNQ NWs. The maximum current d…
Ball-in-shell structured TiO 2 nanospheres were successfully made by flame synthesis—a single-step, continuous, and scalable process. The morphology and structure were systematically characterized by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, transmission electron microscop…
We have demonstrated that nanostructures, and in particular nanorings incorporating a homodimeric enzyme, can be prepared by chemically induced self-assembly of dihydrofolate reductase (DHFR)-histidine triad nucleotide binding 1 (Hint1) fusion proteins. The dimensions of the nanorings were found by static light scatte…
Amphiphilic triblock copolymers of methoxy-poly(ethylene glycol)-poly(L-lactide)-poly(L-lysine) (MPEG-b-PLLA-b-PLL) (Mn=8540-22 240) were synthesized through the ring-opening polymerization of Nepsilon-(Z)-lysine-N-carboxyanhydrides (N(epsilon)-(Z)-Lys-NCA) using MPEG-b-PLLA-NH2 as a macroinitiator. The triblock copol…
The temperature dependence of continued single-walled carbon nanotube (SWNT) growth on an iron cluster is investigated using quantum chemical molecular dynamics simulations based on the density functional tight-binding method. As a model system for continued SWNT growth, a (5,5) armchair-type SWNT seed attached to an…
In a model reaction to demonstrate the presence and reactivity of sp 2 C−H, the primary particles (∼5 nm) of detonation nanodiamond (DND) were arylcarbonylated with 2,4,6-trimethylphenoxybenzoic acid in polyphosphoric acid (PPA) via a Friedel−Crafts reaction. The possibility of grafting primary DND particle was suppor…
Transparent polymer nanocomposites with high ZnS nanophase contents were prepared by a facile one-pot route. Compared with other methods, this method is easier to control. The structure, morphology, thermal and optical properties of the obtained nanocomposites were characterized. The results showed that the ZnS nanopa…
A novel semiconducting polybenzanthrone, with relatively high electrical conductivity and excellent thermal stability, was successfully electrosynthesized by direct anodic oxidation of its monomer benzanthrone in acetonitrile solution containing Bu(4)NBF(4) or boron trifluoride diethyl etherate (BFEE) acting as the su…
Water-soluble sulfonated monomer based on 3,4-propylenedioxythiophene (ProDOT-sultone) was synthesized and characterized for the first time via the O - alkylation of the corresponding unreactive β,β-disubstituted hydroxyl group with propane sultone in the presence of a catalytic amount of 1,4-diazabicyclo[2.2.2]octane…
Herein we present a novel approach for fabricating metallic micro- and nano-structures in thin films viaspin-coating solutions of diblock copolymer vesicles. A simple concept was developed, which is based on the metallization and self-assembly diblock copolymers. Firstly, vesicles incorporating the inorganic component…
In this paper, we demonstrate that metamaterials represent model systems for longitudinal and transverse magnetic coupling in the optical domain. In particular, such coupling can lead to fully parallel or antiparallel alignment of the magnetic dipoles at the lowest frequency resonance. Also, we present the design sche…
To realize the solid materials with higher emission quantum yield from the rhodamine 6G (R6G) monomers, typical laser-dye, we hybridized both alkyltrimethylammonium (C n TMA + ) and R6G cations into the laponite (Lap) interlayer nanospace and investigated their photoemission and nanostructure. The hybrid solid materia…
From red to black porphyrins: “Black” porphyrins absorb visible light effectively at all wavelengths and are available by conjugation of four benzoquinone units to a porphyrin core. These robust molecular components are likely to be useful in optoelectronic devices as they absorb a large fraction of the visible light.
This paper describes the fabrication of plasmonic focusing, free-standing rod-sheath hetero-nanostructures based on electrochemical templated synthesis and selective chemical etching. These hetero-nanostructures take advantage of plasmon interference together with field enhancements due to sharp junction structures to…
Silicon (Si)-doped multiwalled boron nitride nanotubes (BNNTs) were synthesized via thermal chemical vapor deposition. Electron energy-loss spectroscopy revealed that 5% of Si atoms were homogeneously doped into the BNNTs. X-ray absorption and photoelectron spectroscopy measurements demonstrated that the Si−B and Si−N…
The Pr(3+)-doped NaNbO(3) perovskite is introduced as a new red phosphor excitable in the near UV region at around 350 nm. A bright single red emission is observed at room temperature and ascribed to transitions between the (1)D(2) excited state and the ground state (3)H(4) of Pr(3+) ions. This peculiar behavior is re…
Taking into account the general interest in photoswitchable nanomagnets, we present an original synthetic route to well-defined photoswitchable heterotrimetallic complexes. Our strategy demonstrates the feasibility of using a "molybdenum-copper" switchable complex with terminal cyanide ligands as relevant synthons for…
A Platonic relationship: Calcite single and mesocrystals with two platonic shapes and minimal surfaces are formed by a unified polymer-controlled nanoparticle aggregation. The shapes of the crystals (see picture for example) are tuned by the reactant concentration. The morphogenesis follows a nonclassical mechanism. A…
This investigation deals with the effect of growth temperature on the microstructure, nitrogen content, and crystallinity of C-N nanotubes. The X-ray photoelectron spectroscopic (XPS) study reveals that the atomic percentage of nitrogen content in nanotubes decreases with an increase in growth temperature. Transmissio…
Depolymerization of polycarbonate waste by glycolysis using ethylene glycol without catalyst was explored in order to get the monomer bisphenol A (BPA). The depolymerized products were identified by GC/MS and FTIR spectroscopy. The effects of operation variables such as reaction time, reaction temperature, ethylene gl…