Materials Literature
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A comprehensive study was conducted on mesoporous MCM-41. Spectroscopic examinations demonstrated that three types of silanol groups, i.e., single, (SiO) 3 Si−OH, hydrogen-bonded, (SiO) 3 Si−OH-OH−Si(SiO) 3, and geminal, (SiO) 2 Si(OH) 2, can be observed. The number of silanol groups/nm 2, α OH, as determined by NMR,…
Polyimide-clay hybrid films with four different sizes of clay minerals have been synthesized to investigate the effect of the size of clay minerals to the properties of the hybrids. Hectrite, saponite, montmorillonite, and synthetic mica were used as clay minerals. Those clays consist of stacked silicate sheets about…
Second‐phase particles in Al‐4.4Cu‐15Mg‐0.6 Mn (2024‐T3) were characterized by size and chemistry using scanning electron microscopy and associated electron‐beam microanalysis methods. It was found that approximately 60% of particles greater than about 0.5 to 0.7 μm were (the S phase). This fraction corresponded to 2.…
Results of a data evaluation exercise are presented for a particular specification of sintered alpha‐alumina (mass fraction of Al2O3, ≥0.995; relative density (rho/rhotheoretical), ≥0.98; and nominal grain size, 5 μm). A comprehensive set of material property data is established based on published physical, mechanical…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDendrimers in Supramolecular Chemistry: From Molecular Recognition to Self-AssemblyFanwen Zeng and Steven C. ZimmermanView Author Information Department of Chemistry, 600 South Mathews Avenue, University of Illinois, Urbana, Illinois 61801 Cite this: Chem. Rev. 1997, 97, 5,…
Aqueous solutions containing a high yield of suspended gold nanorods have been successfully synthesized via an electrochemical method. The control of preparing gold nanorods with different aspect ratios can be attained. Their absorption spectral features show a dominant surface plasma band corresponding to the longitu…
A large amount of work world-wide has been directed towards obtaining an understanding of the fundamental characteristics of porous Si. Much progress has been made following the demonstration in 1990 that highly porous material could emit very efficient visible photoluminescence at room temperature. Since that time, a…
A brief review of the effect of Newton's macroscopic dynamic shear viscosity on the rotation of a cylinder and a ball in a viscous fluid is presented. The approximate nature of some of Stokes' formulae is discussed, and formulae from elementary viscosity theory are given. The concept of molecular viscosity is introduc…
A systematic account is given of the known data on polytypism in nonmetallic substances with various structures. The existing hypotheses concerning the nature of polytypism are discussed. It is shown that polytype formation in nonmetallic crystals is a solid-state relaxation rearrangement accompanied by the formation…
The current state of research into the oxo-acidity in alkali metal nitrate, sulfate, and halide melts is analysed on the basis of the proposed classification of oxo-acidity reactions (Lux–Flood acid–base interactions). It is established that a considerable proportion of literature data on homogeneous acid–base equilib…
The Industrial Drying Of Foods: An Overview. Drying Fundamentals. Through-Flow Dryers for Agricultural Crops. Fluidized Bed Dryers. Spray Dryers. Contact Dryers. Freeze Dryers. Dielectric Dryers. Specialized Drying Systems. Solar Dryers. Dryer Selection. Sensors, Control and Operation. References. Index
Various formation models for fullerenes and other carbon nanostructures are reviewed. The formation models considered include fullerene assembling from graphite sheets, 'nautilus' model, assemblage from clusters, 'fullerene road', and carbon cluster annealing. The selection of magic fullerenes and fullerene isomers is…
An alcoholic–aqueous solution of LiBr·H2O is a useful solvent for silk fibroin, if the ratio of alcohol content to water content therein is 1 or more. The mixed solvents consisting of ethanol, water, and LiBr·H2O showed a higher solubility if they contained a lesser amount of water. They further proved able to easily…
The lightly sulfonated polystyrene ionomer is only soluble in some organic solvents, such as toluene and tetrahydrofurnan (THF). The mixture of its organic solution with water normally leads to macroscopic phase separation, namely precipitation. In this study, using the steady-state fluorescence, the nonradiative ener…
Serine/glycolic acid-based biodegradable polymers have been prepared by ring-opening homopolymerization of 3-(O-benzyl)-L -serinylmorpholine-2,5-dione, and ring-opening copolymerization of the morpholine-2,5-dione derivative and L -lactide/ϵ-caprolactone. The homopolymerization was carried out in the melt at 165°C for…
This study focuses on the kinetics of ethylene/propylene (homo/co) polymerization reactions using a high activity TiCl4/MgCl2/AlEt3 catalyst. The reactor system is a gas phase reactor equipped with an on-line composition control scheme. As such, important kinetic data such as the instantaneous reaction rate of each mo…
Extensive thermal and relaxational behavior in the blends of linear low-density polyethylene (LLDPE) (1-octene comonomer) with low-density polyethylene (LDPE) and high-density polyethylene (HDPE) have been investigated to elucidate miscibility and molecular relaxations in the crystalline and amorphous phases by using…
New A2B monomers were synthesized for preparation of hyperbranched aryl ether sulfone macromolecules with aryl fluoride and phenol terminal functionalities. The macromolecules, which possess high thermal stability, were prepared using the divergent approach. A masked phenol with two aryl fluoride groups and a bispheno…
Pressure-volume-temperature (PVT) studies were performed on a glass-forming polymer, poly(carbonate) (PC), under both isobaric and isochoric (constant volume) conditions. An isochoric glass transition was observed and the formation points were found to be consistent with those obtained isobarically. Although the isoba…
A combined experimental and modeling program approach was applied to evaluate the role of the carbon dioxide reactive component of soil gas on the long-term performance of cementitious wasteforms. Small wasteforms were cast with Portland cement and synthetic wastewater containing metals and nitrate as a tracer. A seri…