Materials Literature
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The backbone dynamics of specific residues in two collagen-like triple-helical peptides with (X-Y-Gly)n sequences have been investigated using two-dimensional inverse-detected 15N NMR relaxation measurements and hydrogen-exchange experiments. One peptide, (POG)10, has the highest possible imino acid content and is con…
A flexible ϵ-Keggin (Mo12O40) core that can encapsulate either two protons or a Na+ ion is found in the title compounds. In the Na compound (shown on the right) the Na+ guest has the unusual coordination number of four.
Graft polymerization of methoxy-poly(ethylene glycol) methacrylate, an ester of methacrylic acid and monomethoxy-poly(ethylene glycol) (PEO), was performed onto a polyetherurethane (PU) film and tube under different polymerization conditions by a plasma treatment technique. The surface of grafted PU film was character…
Recombinant molecular spectra of O2 in crystalline Kr and Xe, obtained from sudden recombination induced by laser pumping of the predissociative B state, and by adiabatic recombination induced thermally, are reported. All electronic states that correlate with O(3P)+O(3P) are populated by both methods in Kr. The excite…
The dissociative chemisorption of nitrogen on clean and cesiated Ru(0001) surfaces has been studied using high-resolution electron energy loss spectroscopy (HREELS) and thermal desorption spectroscopy (TDS). N2 (at 300 K) chemisorbs dissociatively with a sticking coefficient of 2×10−6, independent of substrate tempera…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRegio- and enantioselective catalytic epoxidation of conjugated polyenes. Formal synthesis of LTA4 methyl esterSukbok Chang, Nam Ho Lee, and Eric N. JacobsenCite this: J. Org. Chem. 1993, 58, 25, 6939–6941Publication Date (Print):December 1, 1993Publication History Published…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface-selective deposition of palladium and silver films from metal-organic precursors: a novel metal-organic chemical vapor deposition redox transmetalation processWenbin Lin, Timothy H. Warren, Ralph G. Nuzzo, and Gregory S. GirolamiCite this: J. Am. Chem. Soc. 1993, 115…
The utilization of as the fuel in a solid‐oxide fuel cell was demonstrated, with the achievement of 42 mA/cm 2 , the highest current density achieved with to date. Two different ionic conductor electrolyte systems have been studied, oxide ion conductors and protonic conductors; the electrolyte membranes had the common…
The incubation of lens capsules with glucose in vitro resulted in changes in the mechanical and thermal properties of type-IV collagen consistent with increased cross-linking. Differential scanning calorimetry (d.s.c.) of fresh lens capsules showed two major peaks at melting temperatures Tm 1 and Tm 2 at approx. 54 de…
A Gaussian size distribution of independently relaxing domains is used to model the response of various glass-forming liquids. With a single temperature-dependent parameter, the model accurately characterizes the observed dielectric susceptibility of salol and glycerol [P. K. Dixon et al., Phys. Rev. Lett. 65, 1108 (1…
Abstract The aim of this study was to investigate the effect of phagocytosed poly( L ‐lactic acid) particles on the morpholgy and viability of phagocytes, mainly macrophages. Therefore, predegraded poly( L ‐lactic acid) (P‐PLLA) and nontreated PLLA (N‐PLLA) particles, both having diameters not exceeding 38 μm, were in…
Electrochemical models of failure in oxide perovskite materials are reviewed. It is noted that oxygen vacancies are a common source of electrical degradation, fatigue, and ageing. Taking the behavior of oxygen vacancies into account, a semi-quantitative model for time dependent dielectric breakdown (TDDB) is proposed…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural aspects of the ambient-pressure BEDT-TTF superconductorsHideki Yamochi, Tokutaro Komatsu, Nozomu Matsukawa, Gunzi Saito, Takehiko Mori, Masami Kusunoki, and Kenichi SakaguchiCite this: J. Am. Chem. Soc. 1993, 115, 24, 11319–11327Publication Date (Print):December 1…
PURPOSE: To test an expandable nitinol intraluminal stent for hoop strength, biocompatibility, corrosion resistance, and patency. MATERIALS AND METHODS: Forty-four stents were implanted in the iliac arteries of 22 sheep. Follow-up was performed with angiography and histologic examination for up to 6 months. RESULTS: A…
The structure of the hexadecameric ribulose-bisphosphate carboxylase/oxygenase from Synechococcus PCC6301 has been solved to 2.2-A resolution. Crystallization was in the presence of CO2, Mg2+, and 2'-carboxyarabinitol bisphosphate to form a stable enzyme quaternary complex that mimics one of the intermediate states of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDicopper(I) trefoil knots and related unknotted molecular systems: influence of ring size and structural factors on their synthesis and electrochemical and excited-state propertiesChristiane O. Dietrich-Buchecker, Jean Francois Nierengarten, Jean Pierre Sauvage, Nicola Armar…
We work out a theory of low-energy Raman scattering in glasses. The scattering and the energy transfer are due to interaction of the light with the soft potentials in glasses. We exploit relations between the scattering cross sections at a certain energy transfer, \ensuremath{\Elzxh}\ensuremath{\omega}, and the mean f…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase behavior of poly(ethylene oxide)-poly(propylene oxide) block copolymers in aqueous solutionPer LinseCite this: J. Phys. Chem. 1993, 97, 51, 13896–13902Publication Date (Print):December 1, 1993Publication History Published online1 May 2002Published inissue 1 December 19…
A computational method is applied for the analysis of optical absorption spectra of amorphous materials to obtain both the power index, r, and E opt, the optical band gap, from the theories of Tauc, and Davis and Mott which relate the energy of the incident photon (hw) to the absorption coefficient α(w) i.e. [αhw ∼ (h…
The short- and medium-range orders of ${\mathrm{GeSe}}_{2}$ chalcogenide glass were studied by using the radial distribution function. The effect of the annealing temperature on the short-range order structure of this glass was investigated. The short-range order structure of as-prepared and annealed ${\mathrm{GeSe}}_…