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Microrheometry for Studying the Rheology and Dynamics of Polymers Near Interfaces

Braithwaite Gavin J.C.、McKinley Gareth H.1999-02-01Applied Rheology

The design of an instrument capable of opto-mechanical studies of the rheology of viscoelastic polymeric fluids near solid interfaces is described. The instrument probes the ‘meso’-scale (length scales of 0 (μm)) and bridges the gap between molecular-scale devices such as the Surface Force Apparatus (SFA) and conventi…

Nonequilibrium Thermodynamics – A Tool for Applied Rheologists

Öttinger Hans Christian1999-02-01Applied Rheology

GENERIC is reviewed not only as a new general framework for modeling nonequilibrium systems, but also as a new way of thinking about nonequilibrium dynamics. This unified framework of nonequilibrium thermodynamics is shown to be deeply rooted in the ample accumulated experience with nonequilibrium systems and, provide…

Evaluation of Slip Effects in the Capillary Flow of Foams

Bekkour Karim1999-02-01Applied Rheology

Foams have been prepared from water added with a surfactant (Sodium-Dodecyl-Sulfate, SDS) and a polymer (Poly-Ethylene-Oxide, PEO) at different concentrations. This work was devoted to a study of the flow properties of the foams. The pressure drops were measured during flow in capillary tubes (2.5, 3.5 and 4 mm) in la…

TABLE OF CONTENTS

作者信息未提供1999-02-01Science and Engineering of Composite Materials

Characterization of Octahedral Substitutions in Kaolinites Using Near Infrared Spectroscopy

Sabine Petit、Jana Madejová、A. Decarreau 等 4 位作者1999-02-01Clays and Clay Minerals

Abstract Fourier transform infrared (FTIR) spectroscopy investigations in the near infrared (N1R) region of synthetic and natural kaolinites with various octahedral substitutions have been carried out in order to elucidate the relationships between the substituted cations and specific features of the NIR spectra. The…

Clay minerals and soil interactionsIron oxide chemistry and applicationsGeochemistry and Geologic Mapping

An In Situ X‐Ray Absorption Spectroscopy Investigation of the Effect of Sn Additions to Carbon‐Supported Pt Electrocatalysts: Part I

Sanjeev Mukerjee、J. McBreen1999-02-01Journal of The Electrochemical Society

Carbon‐supported platinum (Pt/C) with an adsorbed layer of underpotential deposited (upd) Sn is a much better catalyst for the methanol oxidation reaction (MOR) than a carbon‐supported platinum‐tin (PtSn/C) alloy. In situ X‐ray absorption (XAS) was used to determine the differences in the effects that the two methods…

Advanced Materials Characterization TechniquesAdvanced materials and compositesMetallurgical and Alloy Processes

Degradation of Starch–Poly(β-Hydroxybutyrate-Co-β-Hydroxyvalerate) Bioplastic in Tropical Coastal Waters

S. H. Imam、Sherald H. Gordon、Randal L. Shogren 等 6 位作者1999-02-01Applied and Environmental Microbiology

Extruded bioplastic was prepared from cornstarch or poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (PHBV) or blends of cornstarch and PHBV. The blended formulations contained 30 or 50% starch in the presence or absence of polyethylene oxide (PEO), which enhances adherence of starch granules to PHBV. Degradation of…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

The Material Basis for Reduced Mechanical Properties in oim Mice Bones

Nancy P. Camacho、Lindy Hou、Talya R. Toledano 等 8 位作者1999-02-01Journal of Bone and Mineral Research

Osteogenesis imperfecta (OI), a heritable disease caused by molecular defects in type I collagen, is characterized by skeletal deformities and brittle bones. The heterozygous and homozygous oim mice (oim/+ and oim/oim) exhibit mild and severe OI phenotypes, respectively, serving as controlled animal models of this dis…

Connective tissue disorders researchSilk-based biomaterials and applicationsMuscle Physiology and Disorders

Mineralogical Interference on Kaolinite Crystallinity Index Measurements

Patricia Aparicio、Emilio Galán Huertos1999-02-01Clays and Clay Minerals

Abstract This study examines the influence of minerals and amorphous phases associated with kaolin and kaolinitic rocks on kaolinite crystallinity indices (KCI) derived from X-ray diffraction (XRD) data in order to select the best index for systematic studies of commercial kaolins or geological sequences. For this pur…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Origin of the Lone Pair of α-PbO from Density Functional Theory Calculations

Graeme W. Watson、Stephen C. Parker1999-02-01The Journal of Physical Chemistry B

We present ab initio calculations using density functional theory (DFT) within the local density approximation (LDA) on PbO in the α-phase and the idealized CsCl structure. The electron densities clearly show that CsCl-structured PbO has a symmetric lead site while α-PbO shows asymmetry, forming what could be describe…

Advanced Chemical Physics StudiesElectronic and Structural Properties of OxidesX-ray Diffraction in Crystallography

Statistical reconstruction of three-dimensional porous media from two-dimensional images

Anthony Roberts1999-02-01arXiv

A method of modelling the three-dimensional microstructure of random isotropic two-phase materials is proposed. The information required to implement the technique can be obtained from two-dimensional images of the microstructure. The reconstructed models share two-point correlation and chord-distribution functions wi…

cond-mat.dis-nnMaterials Science

Elasticity, stability, and ideal strength ofβ-SiC in plane-wave-basedab initiocalculations

Wei‐Xue Li、Tzuchiang Wang1999-02-01Physical review. B, Condensed matter

On the basis of the pseudopotential plane-wave method and the local-density-functional theory, this paper studies energetics, stress-strain relation, stability, and ideal strength of $\ensuremath{\beta}$-SiC under various loading modes, where uniform uniaxial extension and tension and biaxial proportional extension ar…

Silicon Carbide Semiconductor TechnologiesBoron and Carbon Nanomaterials ResearchAdvanced ceramic materials synthesis

Theory of the hysteresis loop in ferromagnets

Igor Lyuksyutov、Thomas Nattermann、V. L. Pokrovsky1999-02-01Physical review. B, Condensed matter

We consider three mechanisms of hysteresis phenomena in alternating magnetic field: the domain-wall motion in a random medium, the nucleation, and the retardation of magnetization due to slow (critical) fluctuations. We construct a quantitative theory for all these processes. The hysteresis is characterized by two dyn…

Magnetic properties of thin filmsTheoretical and Computational PhysicsMagnetic Properties and Applications

High‐Temperature Oxidation of Boron Nitride: I, Monolithic Boron Nitride

Nathan Jacobson、Serene C. Farmer、Arthur Moore 等 4 位作者1999-02-01Journal of the American Ceramic Society

High‐temperature oxidation of monolithic boron nitride (BN) is examined at 900–1200°C. Hot‐pressed BN and both low‐ and high‐density chemically vapor‐deposited BN are studied. The oxidation product is B 2 O 3 ( l ) and the oxidation kinetics are sensitive to crystallographic orientation, porosity, and impurity levels.…

Semiconductor materials and devicesThermal properties of materialsBoron and Carbon Nanomaterials Research