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Diesel Fuel Desulfurization via Adsorption with the Aid of Activated Carbon: Laboratory- and Pilot-Scale Studies

Penelope Baltzopoulou、Kyriakos X. Kallis、George Karagiannakis 等 4 位作者2015-08-24Energy & Fuels

The present work is an experimental investigation of commercial diesel fuel liquid desulfurization via adsorption under mild conditions. The sorbent employed was a commercial high surface area activated carbon (AC), and studies involved both laboratory- and pilot-scale experiments performed in dedicated fixed-bed setu…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions

Ultrathin Mesoporous NiCo2O4 Nanosheet Networks as High‐Performance Anodes for Lithium Storage

Xuning Leng、Yuan Shao、Sufeng Wei 等 7 位作者2015-08-24ChemPlusChem

Abstract Ultrathin mesoporous NiCo2O4 nanosheets were directly grown on Ni foams to form an efficient and reversible anode for lithium‐ion half‐cell batteries. Nanosheets with wrinkles, which were monolayers of 10 nm NiCo2O4 nanoparticles, were interconnected to build up a honeycomb‐like architecture that offered a la…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

DNA Single-Base Mismatch Study Using Graphene Oxide Nanosheets-Based Fluorometric Biosensors

Yinxi Huang、Hui Ying Yang、Ye Ai2015-08-24Analytical Chemistry

Single nucleotide polymorphisms (SNPs) are frequently associated with various gene-related human diseases, whose determination has attracted great interest. Herein, we report a graphene oxide (GO) nanosheets-based fluorometric DNA biosensor to study the type and location of the single-base mismatch, as well as the inf…

Graphene research and applicationsAdvanced biosensing and bioanalysis techniquesMolecular Junctions and Nanostructures

Adsorption Characteristics of Norfloxacin by Biochar Prepared by Cassava Dreg: Kinetics, Isotherms, and Thermodynamic Analysis

Dan Feng、Huamei Yu、Hui Deng 等 5 位作者2015-08-24BioResources

Biochars (BC) generated from biomass residues have been recognized as effective sorbents for organic compounds. In this study, biochars as adsorbents for the removal of norfloxacin (NOR) from aqueous solutions were evaluated. Biochars were prepared from cassava dregs at 350 °C, 450 °C, 550 °C, 650 °C, and 750 °C, resp…

Adsorption and biosorption for pollutant removalExtraction and Separation ProcessesClay minerals and soil interactions

Second harmonic generation spectroscopy in the Reststrahl band of SiC using an infrared free-electron laser

Alexander Paarmann、Ilya Razdolski、Alexey Melnikov 等 6 位作者2015-08-24Applied Physics Letters

The Reststrahl spectral region of silicon carbide has recently attracted much attention owing to its potential for mid-infrared nanophotonic applications based on surface phonon polaritons (SPhPs). Studies of optical phonon resonances responsible for surface polariton formation, however, have so far been limited to li…

Plasmonic and Surface Plasmon ResearchSilicon Nanostructures and PhotoluminescenceThermal Radiation and Cooling Technologies

Directed Assembly of Cuprous Oxide Nanocatalyst for CO2 Reduction Coupled to Heterobinuclear ZrOCoII Light Absorber in Mesoporous Silica

Wooyul Kim、Heinz Frei2015-08-24ACS Catalysis

Hierarchical assembly of an oxo-bridged binuclear ZrOCo II light absorber unit coupled to a cuprous oxide nanocluster catalyst for CO 2 reduction on mesoporous silica support is demonstrated. The proper positioning of the Cu oxide cluster was achieved by photodeposition of a [Cu(NCCH 3 ) 4 ] 2+ precursor by visible li…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCO2 Reduction Techniques and Catalysts

Magnetic excitations and phonons simultaneously studied by resonant inelastic x-ray scattering in optimally doped Bi1.5Pb0.55Sr1.6La0.4CuO6+δ

Y. Y. Peng、Makoto Hashimoto、M. Moretti Sala 等 16 位作者2015-08-24Physical Review B

Magnetic excitations in the optimally doped high-${T}_{\mathrm{c}}$ superconductor ${\mathrm{Bi}}_{1.5}{\mathrm{Pb}}_{0.55}{\mathrm{Sr}}_{1.6}{\mathrm{La}}_{0.4}{\mathrm{CuO}}_{6+\ensuremath{\delta}}$ (OP-Bi2201, ${T}_{\mathrm{c}}\ensuremath{\simeq}34$ K) are investigated by Cu ${L}_{3}$ edge resonant inelastic x-ray…

Physics of Superconductivity and MagnetismHigh-pressure geophysics and materialsMagnetic Properties and Applications

UV-Induced Micropatterning of Complex Functional Surfaces by Photopolymerization Controlled by Alkoxyamines

Siham Telitel、Sofia Telitel、Julien Bosson 等 11 位作者2015-08-24Langmuir

We report on the use of an alkoxyamine (AA) for fabrication of functional micropatterns with complex structures by UV mask lithography. The living character of the polymer surface and the vertical spatial control of the repolymerization reaction from few tens of nanometers to few micrometers were demonstrated. The imp…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Phosphate removal from water by a novel zeolite/lanthanum hydroxide hybrid material prepared from coal fly ash

Jie Xie、Li Lai、Li‐Dan Lin 等 6 位作者2015-08-24Journal of Environmental Science and Health Part A

This study was undertaken to investigate the effectiveness of the hybrid adsorbent, which was synthesized from coal fly ash and was composed of lanthanum hydroxide and zeolite (La-ZFA), for phosphate removal from water. Long-term repeated adsorption tests for 30 days showed that the maximum removal capacity of the mat…

Constructed Wetlands for Wastewater TreatmentLayered Double Hydroxides Synthesis and ApplicationsPhosphorus and nutrient management

A Global Model for Starve-Fed Nonconventional Single-Screw Extrusion of Thermoplastics

Krzysztof J. Wilczyński、A. Lewandowski、Andrzej Nastaj 等 4 位作者2015-08-24Advances in Polymer Technology

A global computer model has been developed for starve-fed nonconventional single-screw extrusion. The model has been built by combining a new melt conveying model with recently developed melting models. Mixing screw equipped with dispersive mixing element of Maddock has been considered as an example for modeling. Exte…

Rheology and Fluid Dynamics StudiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Dynamic equilibrium between closed and partially closed states of the bacterial Enzyme I unveiled by solution NMR and X-ray scattering

Vincenzo Venditti、Charles D. Schwieters、Alexander Grishaev 等 4 位作者2015-08-24Proceedings of the National Academy of Sciences

Enzyme I (EI) is the first component in the bacterial phosphotransferase system, a signal transduction pathway in which phosphoryl transfer through a series of bimolecular protein-protein interactions is coupled to sugar transport across the membrane. EI is a multidomain, 128-kDa homodimer that has been shown to exist…

Protein Structure and DynamicsBacterial Genetics and BiotechnologyEnzyme Structure and Function

A New Low Melting-Point Polymorph of Fenofibrate Prepared via Talc Induced Heterogeneous Nucleation

Pratchaya Tipduangta、Khaled Takieddin、L. Fábián 等 5 位作者2015-08-24Crystal Growth & Design

Fenofibrate is one of the most commonly prescribed hyperlipidemia agents. Despite its high lipophilicity and ultralow aqueous solubility, most commercially available formulations use micronized crystalline fenofibrate form I, which has a low dissolution rate and poor oral bioavailability. Little is known about the cry…

Drug Solubulity and Delivery SystemsCrystallization and Solubility StudiesPharmacological Effects of Natural Compounds

Sialylation potentials of the silkworm,Bombyx mori;B. moripossesses an active α2,6-sialyltransferase

Hiroyuki Kajiura、Yuichi Hamaguchi、Hiroki Mizushima 等 5 位作者2015-08-24Glycobiology

N-Glycosylation is an important post-translational modification in most secreted and membrane-bound proteins in eukaryotic cells. However, the insect N-glycosylation pathway and the potentials contributing to the N-glycan synthesis are still unclear because most of the studies on these subjects have focused on mammals…

Glycosylation and Glycoproteins ResearchInvertebrate Immune Response MechanismsSilk-based biomaterials and applications

Preparation and Characterization of Amphoteric Cellulose Hydrogels as Adsorbents for the Anionic Dyes in Aqueous Solutions

Hiroyuki Kono2015-08-24Gels

A series of cellulose ampholytes (CAms), with substitution degrees of cationic groups (DSC) of 0.41, 0.79, and 1.08, and with a substitution degree of anionic groups of 0.68, was prepared from sodium carboxymethylcellulose by a cationization reaction with 2,3-epoxypropyltrimethylammonium chloride. The obtained CAms we…

Adsorption and biosorption for pollutant removalHydrogels: synthesis, properties, applicationsAdvanced Cellulose Research Studies

Selective absorbers and thermal emitters for far-infrared wavelengths

W. Streyer、Kaijun Feng、Yi Chen Zhong 等 5 位作者2015-08-24Applied Physics Letters

We demonstrate engineered selective absorption and subsequent selective thermal emission from sub-wavelength thickness optical structures at far-infrared (30–40 μm) wavelengths. Control over absorption/emission wavelength is demonstrated, with both polarization-dependent and -independent structures fabricated. Samples…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsThermal Radiation and Cooling Technologies

Effects of Surface Nonuniformities on the Mean Transverse Energy from Photocathodes

Siddharth Karkare、Ivan Bazarov2015-08-24Physical Review Applied

The performance of both large linear electron accelerators and smaller-scale ultrafast electron-diffraction setups is limited by the source of electrons, the photocathode. This study shows how a nonuniform surface of the source affects the energies of emitted electrons, using fundamental physics principles to guide th…

Radiation Therapy and DosimetryElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Open-Circuit Voltage Losses in Selenium-Substituted Organic Photovoltaic Devices from Increased Density of Charge-Transfer States

Dana B. Sulas、Kai Yao、Jeremy J. Intemann 等 12 位作者2015-08-24Chemistry of Materials

Abstract Using an analysis based on Marcus theory, we characterize losses in open-circuit voltage (VOC) due to changes in charge-transfer state energy, electronic coupling, and spatial density of charge-transfer states in a series of polymer/fullerene solar cells. We use a series of indacenodithiophene polymers and th…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

A Self-Assembled, Low-Cost, Microstructured Layer for Extremely Stretchable Gold Films

Heather L. Filiatrault、R. Stephen Carmichael、Rachel A. Boutette 等 4 位作者2015-08-24ACS Applied Materials & Interfaces

We demonstrate a simple, low-cost, and green approach to deposit a microstructured coating on the silicone elastomer polydimethylsiloxane (PDMS) that can be coated with gold to produce highly stretchable and conductive films. The microstructured coating is fabricated using an aqueous emulsion of poly(vinyl acetate) (P…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTactile and Sensory Interactions

The geometry of generalized force matching and related information metrics in coarse-graining of molecular systems

Evangelia Kalligiannaki、Vagelis Harmandaris、Markos A. Katsoulakis 等 4 位作者2015-08-24The Journal of Chemical Physics

Using the probabilistic language of conditional expectations, we reformulate the force matching method for coarse-graining of molecular systems as a projection onto spaces of coarse observables. A practical outcome of this probabilistic description is the link of the force matching method with thermodynamic integratio…

Protein Structure and DynamicsForce Microscopy Techniques and ApplicationsBlock Copolymer Self-Assembly

Requirements to achieve high in-field critical current density at 30 K in heavily-doped (Gd,Y)Ba 2 Cu 3 O x superconductor tapes

V. Selvamanickam、Meysam Heydari Gharahcheshmeh、Aixia Xu 等 5 位作者2015-08-24Superconductor Science and Technology

Critical current densities ( J c ) above 15 MA cm −2 have been achieved at 30 K, 2.5 T ( B || c ) in (Gd,Y)–Ba–Cu–O tapes with 20–25 mol.% Zr addition. The optimal compositions of Gd + Y, Ba + Zr and Cu to achieve lift factor in critical current above 6 at 30 K, 2.5 T ( B || c ) have been determined by development of…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics