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Lillianites and andorites: new life for the oldest homologous series of sulfosalts

Emil Makovicky、Dan Topa2014-04-01Mineralogical Magazine

Abstract The current state of the lillianite homologous series is presented, with its two branches − the lillianite branch of the predominantly Pb-Bi-Ag sulfosalts and the andorite branch of predominantly Pb-Sb-Ag sulfosalts. Both the natural and synthetic members are discussed, especially from the structural and comp…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyElectronic and Structural Properties of Oxides

Surface potential decay dynamic characteristics of negative-corona-charged fibrous dielectric materials

Belaïd Tabti、Belkacem Yahiaoui、Boukhalfa Bendahmane 等 4 位作者2014-04-01IEEE Transactions on Dielectrics and Electrical Insulation

The dielectric behavior of an insulating material is commonly characterized by exposing its surface to a DC corona discharge for relatively short duration and then recording the decay of the electric potential Vs at its surface, Vs = f(t). The representation of the surface potential decay (SPD) by using tdVs/dt = f(lo…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaAerosol Filtration and Electrostatic Precipitation

Complex metallic alloys as new materials for additive manufacturing

Samuel Kenzari、D. Bonina、Jean-Marie Dubois 等 4 位作者2014-04-01Science and Technology of Advanced Materials

Additive manufacturing processes allow freeform fabrication of the physical representation of a three-dimensional computer-aided design (CAD) data model. This area has been expanding rapidly over the last 20 years. It includes several techniques such as selective laser sintering and stereolithography. The range of mat…

Quasicrystal Structures and PropertiesAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

IN VITRO CYTOTOXICITY OF CARALLUMA SPECIES BY MTT AND TRYPAN BLUE DYE EXCLUSION

Pavan Kumar Bellamakondi、Ashok Godavarthi、Mohammed Auwal Ibrahim 等 6 位作者2014-04-01OpenAlex

Caralluma species have been reported for various traditional claims; the scientific data for possible activities have not yet been studied thoroughly. However the toxicity of a plant has to be studied for further exploration of various biological activities. Extracts were studied for their toxicity by MTT and trypan b…

Fungal Biology and ApplicationsChemical synthesis and alkaloidsPhytochemistry and Bioactive Compounds

Synthesis of a Broad-Band Excited and Multicolor Tunable Phosphor Gd2SiO5:Ce3+,Tb3+,Eu3+for Near-Ultraviolet Light-Emitting Diodes

Xinguo Zhang、Yibo Chen、Liya Zhou 等 5 位作者2014-04-01Industrial & Engineering Chemistry Research

Broad-band near-ultraviolet (NUV)-excited and multicolor-emitting Gd 2 SiO 5:Ce 3+,Tb 3+,Eu 3+ phosphors were synthesized by solid-state reaction. The emission color of the phosphors can be tuned from blue (0.153, 0.091) to green (0.325, 0.495) and eventually to red (0595, 0.370) through efficient Ce 3+ → (Tb 3+ ) n →…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesGa2O3 and related materials

Influence of Block Copolymer Compatibilizers on the Morphologies of Semiflexible Polymer/Solvent Blends

Dylan Kipp、Venkat Ganesan2014-04-01The Journal of Physical Chemistry B

We study the influence of block copolymer (BCP) compatibilizers on the domain and interfacial characteristics of the equilibrium morphological structures of semiflexible polymer/solvent blends. Our study is motivated by the question of whether block copolymer compatibilizers can be used to influence the phase separati…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

New Chitosan Nanospheres for the Delivery of 5-Fluorouracil: Preparation, Characterization and in vitro Studies

Roberta Cavalli、Federica Leone、Rosalba Minelli 等 5 位作者2014-04-01Current Drug Delivery

The aim of this work was to develop new chitosan nanospheres for the delivery of 5-fluorouracil (5-FU). Drug loaded nanospheres were prepared using a technique derived from a combination of coacervation and emulsion droplet coalescence methods. The size and morphology of nanospheres were characterized by laser light s…

Nanoparticle-Based Drug DeliveryCancer Treatment and Pharmacology

Ammonia Generation over TWC for Passive SCR NO<sub>X</sub> Control for Lean Gasoline Engines

Vitaly Y. Prikhodko、James E. Parks、Josh A. Pihl 等 4 位作者2014-04-01SAE International Journal of Engines

&lt;div class="section abstract"&gt;&lt;div class="htmlview paragraph"&gt;A commercial three-way catalyst (TWC) was evaluated for ammonia (NH&lt;sub&gt;3&lt;/sub&gt;) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system.…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen Reduction

Surface modification and deuterium retention in reduced activation ferritic martensitic steels exposed to low-energy, high flux D plasma and D2gas

V.Kh. Alimov、Yuji Hatano、K. Sugiyama 等 10 位作者2014-04-01Physica Scripta

Samples prepared from steels F82H and EUROFER97 were irradiated with 20 MeV W ions at 300 K to 0.54 displacements per atom at the damage peak. Damaged and undamaged samples were exposed at elevated temperatures both to deuterium plasma at ion energies of 60 and 200 eV to a fluence of ≈10 26 D m −2 and to D 2 gas at a…

Fusion materials and technologiesNuclear Materials and PropertiesIon-surface interactions and analysis

Misfit dislocation loops in composite core-shell nanoparticles

M. Yu. Gutkin、A. L. Kolesnikova、S. A. Krasnitsky 等 4 位作者2014-04-01Physics of the Solid State

The critical conditions have been calculated for the generation of circular prismatic loops of misfit dislocations at the interfaces in spherically symmetric composite core-shell nanoparticles. It has been shown that the formation of these loops becomes energetically favorable if the misfit parameter exceeds a critica…

Quantum Dots Synthesis And PropertiesChemical and Physical Properties of MaterialsSurface and Thin Film Phenomena

The Effect of Bias Voltage and Gas Pressure on the Structure, Adhesion and Wear Behavior of Diamond Like Carbon (DLC) Coatings With Si Interlayers

Liam Ward、Fabian Junge、Andreas Lampka 等 6 位作者2014-04-01Coatings

In this study diamond like carbon (DLC) coatings with Si interlayers were deposited on 316L stainless steel with varying gas pressure and substrate bias voltage using plasma enhanced chemical vapor deposition (PECVD) technology. Coating and interlayer thickness values were determined using X-ray photoelectron spectros…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Nanoindentation and thermal characterization of poly (vinylidenefluoride)/MWCNT nanocomposites

Obulapathi Eggedi、Uvais Valiyaneerilakkal、M. R. Darla 等 4 位作者2014-04-01AIP Advances

We report the preparation, thermal and micro/nanomechanical behavior of poly (vinylidine diflouride) (PVDF)/multiwalled carbon nanotube (MWCNT) nanocomposites. It has been found that the addition of MWCNT considerably enhances the β-phase formation, thermal and mechanical properties of PVDF. Atomic force microscope (A…

Polymer Nanocomposites and PropertiesDielectric materials and actuatorsPolymer Nanocomposite Synthesis and Irradiation

Visible‐Light‐Driven Water Oxidation with Nanoscale Co3O4: New Optimization Strategies

Hongfei Liu、Greta R. Patzke2014-04-01Chemistry - An Asian Journal

Water oxidation is the "bottleneck" of artificial photosynthesis on the way to clean and sustainable solar fuels production. Although spinel-type Co3 O4 keeps attracting considerable research interest as a robust and low-cost water oxidation catalyst (WOC), full control over its manifold performance parameters remains…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsAdvanced Nanomaterials in Catalysis

Improved dynamic model of DC arc discharge on ice-covered post insulator surfaces

Shamsodin Taheri、M. Farzaneh、I. Fofana2014-04-01IEEE Transactions on Dielectrics and Electrical Insulation

This paper presents a self-consistent dynamic two-arc model predicting the behavior of DC arcs on ice-covered station post insulators. This model makes it possible to determine the minimum flashover voltage (VMF) as well as some characteristics of the discharge, including temporal evolution of leakage current, arc cha…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Net versus gross erosion of high-Zmaterials in the divertor of DIII-D

D.L. Rudakov、P.C. Stangeby、W.R. Wampler 等 13 位作者2014-04-01Physica Scripta

Net versus gross erosion of high-Z materials in the divertor of DIII-D, Rudakov, D L, Stangeby, P C, Wampler, W R, Brooks, J N, Brooks, N H, Elder, J D, Hassanein, A, Leonard, A W, McLean, A G, Moyer, R A, Sizyuk, T, Watkins, J G, Wong, C P C

Magnetic confinement fusion researchFusion materials and technologiesNuclear Materials and Properties

Metalloenzyme-Mimicking Supramolecular Catalyst for Highly Active and Selective Intramolecular Alkyne Carboxylation

Li-Chen Lee、Yan Zhao2014-04-01Journal of the American Chemical Society

Creation of synthetic catalysts with enzyme-like behavior is challenging despite strong interest in such systems. Extraction of tetrachloroaurate into the hydrophilic core of an interfacially cross-linked reverse micelle (ICRM) produced an artificial "metalloenzyme" with highly unusual catalytic properties. The ICRM p…

Catalytic Alkyne ReactionsAsymmetric Hydrogenation and CatalysisNanocluster Synthesis and Applications

Magnetic and piezoelectric properties of the Bi1 − x La x FeO3 system near the transition from the polar to antipolar phase

D. V. Karpinsky、I. O. Troyanchuk、O. S. Mantytskaja 等 7 位作者2014-04-01Physics of the Solid State

The crystal structure, piezoelectric and magnetic properties of the Bi1 − x La x FeO3 solid-solution system near the structural transition between the rhombohedral and orthorhombic phases (0.15 ≤ x ≤ 0.2) have been investigated. The regions of existence of the polar rhombohedral and orthorhombic phases have been deter…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Effects of epoxidized natural rubber (ENR‐50) and processing parameters on the properties of NR/EPDM blends using response surface methodology

Noraiham Mohamad、Juliana Yaakub、Jeefferie Abd Razak 等 6 位作者2014-04-01Journal of Applied Polymer Science

ABSTRACT The effects of epoxidized natural rubber (ENR‐50) and processing parameters on the properties of natural rubber/ethylene–propylene–diene rubber (NR/EPDM; 70 : 30 phr) blends were studied. The compounds were prepared by melt compounding method. Using response surface methodology of two‐level full factorial, th…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Deuterium retention in tungsten films deposited by magnetron sputtering

Peng Wang、W. Jacob、L. Gao 等 5 位作者2014-04-01Physica Scripta

Deuterium retention in tungsten films deposited on polycrystalline bulk tungsten substrates was investigated and compared with deuterium retention in W films deposited on silicon and in polycrystalline bulk W alone. The structure of the deposited films was investigated by x-ray diffraction and scanning electron micros…

Metal and Thin Film MechanicsFusion materials and technologiesNuclear Materials and Properties

Ab Initio Atomistic Thermodynamics of Water Reacting with Uranium Dioxide Surfaces

Pablo Maldonado、Lena Z. Evins、Peter M. Oppeneer2014-04-01The Journal of Physical Chemistry C

Using first-principles simulations, we study the temperature- and pressure-dependent adsorption reaction of water on the flat (111) and (211) and (221) stepped surfaces of uranium dioxide. Our calculations are based on the density functional theory (DFT) corrected for on-site Coulomb interactions (DFT+ U ) for describ…

Radioactive element chemistry and processingNuclear Materials and PropertiesQuantum, superfluid, helium dynamics