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Herstellung mikrostrukturierter Polymerbürsten auf wiederbeschreibbaren Oberflächen durch Triazolindion‐Click‐Chemie

Oliver Roling、Kevin De Bruycker、Benjamin Vonhören 等 8 位作者2015-09-08Angewandte Chemie

Abstract Triazolindion‐Click‐Chemie und Mikrokontaktchemie wurden kombiniert, um Polymerbürsten auf Oberflächen zu drucken, zu löschen und anschließend erneut anzubinden. Die mikrostrukturierten Polymerbürsten wurden auf Alken‐ und Indol‐Monoschichten gebildet, indem zuerst ein mit Triazolindion (TAD) substituierter A…

Click Chemistry and ApplicationsSynthesis and properties of polymersNanofabrication and Lithography Techniques

Characterization of melt spinnability of ethylene vinyl alcohol copolymers

Syang‐Peng Rwei、Zhi‐Feng Jue、Whe‐Yi Chiang 等 5 位作者2015-09-08Textile Research Journal

This study investigates melt spinnability of ethylene vinyl alcohol (EVOH) copolymers with various ethylene contents, which exhibits excellent biocompatibility but cannot easily undergo single-component fiber spinning. The chemical, thermal and rheological properties of EVOH were examined herein. Three EVOH copolymers…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Achnanthidium petuniabuktianum sp. nov. (Achnanthidiaceae, Bacillariophyta), a new representative of the A. pyrenaicum group from Spitsbergen (Svalbard Archipelago, High Arctic)

Eveline Pinseel、Bart Van de Vijver、Kateřina Kopalová2015-09-08Phytotaxa

During a survey of the freshwater littoral diatom flora from lakes and ponds in the region of Petuniabukta on Spitsbergen (Svalbard Archipelago, High Arctic region), a new Achnanthidium species, A. petuniabuktianum sp. nov., has been recorded. Achnanthidium petuniabuktianum is a new representative of the A. pyrenaicum…

Microbial Community Ecology and PhysiologyDiatoms and Algae Research

Uniform and electrically conductive biopolymer‐doped polypyrrole coating for fibrous PLA

Maiju Hiltunen、Jani Pelto、Ville Ellä 等 4 位作者2015-09-08Journal of Biomedical Materials Research Part B Applied Biomaterials

Three-dimensional, fibrous scaffolds can be easily fabricated from polylactide (PLA) using melt spinning and textile techniques. However, the surface properties of PLA scaffolds are not ideal for tissue engineering purposes. Furthermore, electrically conducting scaffolds are required to deliver electrical stimulation…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Synthesis, characterization and molecular structure of a dinuclear uranyl complex supported by N,N′,N″,N′″-tetra-(3,5-di-tert-butylsalicylidene)-1,2,4,5-phenylenetetraamine

René Schnorr、Marcel Handke、Berthold Kersting2015-09-08Zeitschrift für Naturforschung B

Abstract The preparation, characterization and the molecular structure of a dinuclear uranyl complex [(UO2)2L(OCMe2)2] supported by the bis-salophen ligand N,N′,N″,N′″-tetra-(3,5-di-tert-butylsalicylidene)-1,2,4,5-phenylenetetraamine (L4–) is described. [(UO2)2L(OCMe2)2] was prepared by reaction of uranyl nitrate with…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Integrated information storage and transfer with a coherent magnetic device

Ning Jia、Leonardo Banchi、Abolfazl Bayat 等 5 位作者2015-09-08Scientific Reports

Quantum systems are inherently dissipation-less, making them excellent candidates even for classical information processing. We propose to use an array of large-spin quantum magnets for realizing a device which has two modes of operation: memory and data-bus. While the weakly interacting low-energy levels are used as…

Quantum and electron transport phenomenaChemical and Physical Properties of MaterialsQuantum-Dot Cellular Automata

Field-induced detrapping in doped organic semiconductors with Gaussian disorder and different carrier localizations on host and guest sites

M. Scheb、C. Zimmermann、Christoph Jungemann2015-09-08Physical Review B

For organic host-guest systems with a low fraction of guest sites, i.e., the trap-limited case, field-induced detrapping of charge carriers is studied via master equation calculations under the assumption of Miller-Abrahams rates and two Gaussian distributions of uncorrelated energy levels. Among existing descriptions…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Surface passivation of GaAs using atomic layer deposition grown MgO

Xian Gao、Dan Fang、Xuan Fang 等 10 位作者2015-09-08Materials Research Express

In this paper, different MgO films were deposited on a GaAs substrate by atom layer deposition (ALD), which can passivate the surface state of GaAs. From XPS results, the band structure of MgO/GaAs can be indexed to type I. Based on band alignment, the excitons could not diffuse and created nonradiative centers, which…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesSemiconductor materials and devices

Schematic Studies on the Structural Properties and Device Physics of All Small Molecule Ternary Photovoltaic Cells

Yu Jin Kim、Jisu Hong、Chan Eon Park2015-09-08ACS Applied Materials & Interfaces

Although the field of ternary organic solar cells has seen much progress in terms of device performance in the past few years, limited understanding has restricted further development. For example, studies of the crystalline packing structure of ternary blends have rarely been reported in the solar cell field. Consequ…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

A new low-cost hydrogen sensor build with a thermopile IR detector adapted to measure thermal conductivity

Martin Liess2015-09-08Journal of sensors and sensor systems

Abstract. It is demonstrated how a commercially available MEMS thermopile infrared radiation sensor can be used as thermal conductivity gas detector (TCD). Since a TCD requires a heater while IR-thermopile sensors have no integrated heater, the thermopile itself is used as heater and temperature sensor at the same tim…

Fuel Cells and Related MaterialsAdvanced Thermoelectric Materials and DevicesGas Sensing Nanomaterials and Sensors

Rapid, On‐Command Debonding of Stimuli‐Responsive Cross‐Linked Adhesives by Continuous, Sequential Quinone Methide Elimination Reactions

Hyungwoo Kim、Hemakesh Mohapatra、Scott T. Phillips2015-09-08Angewandte Chemie

Abstract Adhesives that selectively debond from a surface by stimuli‐induced head‐to‐tail continuous depolymerization of poly(benzyl ether) macro‐cross‐linkers within a poly(norbornene) matrix are described. Continuous head‐to‐tail depolymerization provides faster rates of response than can be achieved using a small‐m…

Polymer composites and self-healingSynthesis and properties of polymersPolydiacetylene-based materials and applications

Critical phenomena of a single defect

Xintian Wu、Yangyang Zhang2015-09-08Physical Review E

We consider the critical system with a point defect and study the variation of thermodynamic quantities, which are the differences between those with and without the defect. Within renormalization group theory, we show generally that the critical exponent of the internal energy variation is the specific heat exponent…

Material Dynamics and PropertiesTheoretical and Computational PhysicsStochastic processes and statistical mechanics

CMOS Compatible Growth of High Quality Ge, SiGe and SiGeSn for Photonic Device Applications

Murtadha Alher、Aboozar Mosleh、Larry Cousar 等 13 位作者2015-09-08ECS Transactions

Germanium films were deposited on silicon substrate by an ultra-high vacuum chemical vapor deposition system using GeH4 as Ge precursor and different carrier gases (Ar, N2 and H2). Silicon-germanium and SiGeSn films were deposited using optimized growth conditions of Ge growth. Silane and SnD4 were used as precursors…

Photonic and Optical DevicesSemiconductor Lasers and Optical DevicesOptical Coatings and Gratings

Asymmetric transmission in prisms using structures and materials with isotropic-type dispersion

Funda Tamara Gundogdu、Andriy E. Serebryannikov、Atilla Özgür Çakmak 等 4 位作者2015-09-08Optics Express

It is demonstrated that strong asymmetry in transmission can be obtained at the Gaussian beam illumination for a single prism based on a photonic crystal (PhC) with isotropic-type dispersion, as well as for its analog made of a homogeneous material. Asymmetric transmission can be realized with the aid of refraction at…

Metamaterials and Metasurfaces ApplicationsPhotonic and Optical DevicesPhotonic Crystals and Applications

Effect of trifluoroethanol on α‐crystallin: folding, aggregation, amyloid, and cytotoxicity analysis

Mohd Shahnawaz Khan、Shams Tabrez、Sheraz Ahmed Bhat 等 6 位作者2015-09-08Journal of Molecular Recognition

α-Crystallin, a member of small heat shock proteins, is the major structural protein within the eye lens and is believed to play an exceptional role in the stability of lens proteins and its transparency. In the current manuscript, we have investigated the effect of an organic solvent, trifluoroethanol (TFE), on the s…

Enzyme Structure and FunctionConnexins and lens biologyProtein Interaction Studies and Fluorescence Analysis

Peptide-Induced Amyloid-Like Conformational Transitions in Proteins

Egorov Vv、Н. А. Грудинина、Andrey V. Vasin 等 4 位作者2015-09-08International Journal of Peptides

Changes in protein conformation can occur both as part of normal protein functioning and during disease pathogenesis. The most common conformational diseases are amyloidoses. Sometimes the development of a number of diseases which are not traditionally related to amyloidoses is associated with amyloid-like conformatio…

Protein Structure and DynamicsAlzheimer's disease research and treatmentsEnzyme Structure and Function

On the applicability of Ampère’s law

Bálint Morvay、László Pálfalvi2015-09-08European Journal of Physics

We point out that in the course of application of Ampère's law it is important to fulfil the condition of continuity. We emphasize the role of the displacement current in the case of non-closed circuits. As a didactical example the magnetostatic field generated by the current of a finite-length straight wire is analys…

Magnetic Properties and ApplicationsExperimental and Theoretical Physics StudiesElectric Power Systems and Control

An improved statistical analysis for predicting the critical temperature and critical density with Gibbs ensemble Monte Carlo simulation

Richard A. Messerly、Richard L. Rowley、Thomas A. Knotts 等 4 位作者2015-09-08The Journal of Chemical Physics

A rigorous statistical analysis is presented for Gibbs ensemble Monte Carlo simulations. This analysis reduces the uncertainty in the critical point estimate when compared with traditional methods found in the literature. Two different improvements are recommended due to the following results. First, the traditional p…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Investigation of In vitro PDT Activities and In vivo Biopotential of Zinc Phthalocyanines Using 131I Radioisotope

Mine Ince、Özge Er、Kasım Ocakoğlu 等 8 位作者2015-09-08Chemical Biology & Drug Design

Novel octylthio-containing asymmetrically substituted Zn(II) phthalocyanine (Zn(II)Pc1) and a symmetric derivative (Zn(II)Pc2) have been prepared to investigate the biological potential and ability to photosensitize singlet oxygen for photodynamic therapy applications. In this study, the singlet oxygen generation pote…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies