Materials Literature
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An organic nonlinear optical single crystal of ninhydrin was grown by Sankaranarayanan–Ramasamy (SR) method by using specially designed glass ampoule. The good quality seed crystal has been prepared by conventional solution growth technique using double distilled water as the solvent. The lattice dimension of the grow…
Abstract Highly photochemically stable nanoparticles, in which upconversion luminescence can be excited – so-called upconversion nanocrystals (UC-NCs) – exhibit widely separated (up to 500 nm) narrow luminescence bands in the visible (VIS) region located far from the excitation near-infrared (NIR) laser radiation, and…
Purpose: of this paper is to review the effect of heat treatments and of strain hardening on microstructure and properties of superduplex stainless steels. Design/methodology/approach: Annealing and strain hardening treatments influences microstructures
The spin-polarized electronic structures across the interface between single-layer graphene and a Ni(111) thin film are explored by employing depth-resolved X-ray absorption and magnetic circular dichroism spectroscopy with atomic layer resolution. The depth-resolved Ni L2,3-edge analysis clarifies that the Ni atomic…
The first molecular superconductor based on BEDT-TTF radical cation salt with the paramagnetic tris(oxalato)ruthenate anion, β′′-(BEDT-TTF)4Kx(H3O)1−x[RuIII(ox)3]C6H5Br (x ∼ 0.8), is synthesized and its crystal and electronic structure as well as transport and magnetotransport properties are studied. The single crysta…
We report an extensive density-functional theory and coupled-cluster CCSD(T) study on boron dihydride dianion clusters BnH2(2-) (n = 6-22) and their dilithiated Li2BnH2(0/-) salt complexes. Double-chain (DC) planar nanoribbon structures are confirmed as the global minima for the BnH2(2-) (n = 6-22) clusters. Charging…
Infiltration has attracted increasing attention as an effective technique to modify SOFC cathodes to improve cell electrochemical performance while maintaining material compatibility and long-term stability. However, the infiltrated material's effect on oxygen transport is still not clear and detailed knowledge of the…
A straightforward, mild and green chemistry process had been developed to synthesize well-defined spherical Ag/PS (polystyrene) hybrid materials by using nontoxic L-ascorbic acid as both reducing agent and capping agent. Negatively charged –SO3− could act as a linker between Ag+ ions (Ag nanoparticles) and polystyrene…
Amphiphilic cationic cellulose derivatives with different long alkyl chains as hydrophobic segments were synthesized. They can self-assemble into cationic micelles in distilled water. The structure and properties of the micelles were characterized by elemental analysis, FT-IR, 1H NMR, ζ-potential measurements, DLS, TE…
Turbinaria turbinata brown seaweeds were tested as carbon electrode material in symmetric, electrochemical supercapacitors. The electrochemical properties of the carbon materials were characterised for their application as supercapacitors using cyclic voltammetry, galvanostatic charge/discharge method and electrochemi…
The inherently high magnetic anisotropy and nanoscale grain size in a Sm5Co19 compound result in an intrinsic coercivity far higher than those of known Sm-Co compounds prior to orientation treatment. The combination of ultrahigh intrinsic coercivity, high Curie temperature and low coercivity temperature coefficient of…
Triisobutylaluminum reacts with silica yielding three different Al sites according to high-field aluminum-27 NMR and first principle calculations: a quadruply grafted dimeric surface species and two incorporated Al(O)x species (x = 4 or 5). This result is in stark contrast to the bis-grafted species that forms during…
The genipin-cross-linked silk sericin/poly(vinyl alcohol) (PVA) films were developed aiming to be applied as two-dimensional wound dressings for the treatment of superficial wounds. The effects of genipin cross-linking concentration on the physical and biological properties of the films were investigated. The genipin-…
In the last few years there has been an increasing interest in the possibility of recycling polymeric materials, using physical recycling. However, is it well known that polymers experience a depletion of all the properties upon recycling. These effects have been widely characterized in the literature for what concern…
The present study examined the effect of chitosan (Ch) and combination of chitosan and Thymus vulgaris essential oil (Ch+T) on the quality and shelf life of butterfly-shaped rainbow trout stored under refrigerated condition (5 ± 1°C) for 15 days. The treatments in the present study were Ch (chitosan: 2% w/v) and Ch+T…
A facile method to develop electro-induced shape memory polymer composites with good location- and process-controlled shape recovery performance is proposed. The poly(butylene succinate) (PBS)–poly(ethylene glycol) (PEG) multiblock copolymer (PBSEG), which has excellent flexibility, was chosen as the matrix of the com…
A panoramic overview of the leather world market is given. The industrial tanning process is schemat- ically explained giving a general outline of how an animal skin is transformed into a durable material having many different characteristics according to its specific future use. All the tanning industrial steps are o…
From the viewpoint of developing photoresponsive supramolecular systems in microenvironments to exhibit more sophisticated photo-functions even at the macroscopic level, inorganic/organic hybrid compounds based on clay or niobate nanosheets as the microenvironments were prepared, characterized, and examined for their…
A new functional triphenylamine-based (TPA-based) aromatic polyether (OXPE) derived from 2,5-bis(4-fluorophenyl)-1,3,4-oxadiazole and 4,4′-dihydroxytriphenylamine and polyester (6FPET) derived from 4,4′-(hexafluoroisopropylidene)bis(benzoyl chloride) and 4,4′-dihydroxytriphenylamine were synthesized and used for memor…
A new straightforward method for the synthesis of gold nanoparticles from addition of cyclohexanone to aqueous solutions of auric acid at room temperature is presented. By understanding this process we have discovered a new organic chemistry transformation reaction for converting cyclic ketones to α-chloro ketones and…