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Interaction of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide with an electrospun PVdF membrane: Temperature dependence of the concentration of the anion conformers

Francesco Vitucci、Oriele Palumbo、F. Trequattrini 等 8 位作者2015-09-04The Journal of Chemical Physics

We measured the temperature dependence of the infrared absorption spectrum of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PY R14-TFSI) between 160 and 330 K, through all the phase transitions presented by this compound. The comparison of the experimental spectra with the calculated vibration mode…

Ionic liquids properties and applicationsConducting polymers and applicationsAnalytical Chemistry and Sensors

Metallic Honeycombs as Catalyst Supports for Methanation of Carbon Dioxide

David Schlereth、Philipp J. Donaubauer、Olaf Hinrichsen2015-09-04Chemical Engineering & Technology

Abstract By means of reactor modeling, externally cooled tubular reactors equipped with metallic honeycombs as catalyst supports are investigated. A 2D pseudo‐continuous reactor model is adopted to study in particular heat transfer properties and to identify the influencing parameters as well as transport processes on…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Modulation of Amyloid-β Fibrils into Mature Microrod-Shaped Structure by Histidine Functionalized Water-Soluble Perylene Diimide

Muthuraj Balakrishnan、Sayan Roy Chowdhury、Parameswar Krishnan Iyer2015-09-04ACS Applied Materials & Interfaces

Alzheimer's disease (AD) is associated with different types of amyloid peptide aggregates including senile plaques, fibrils, protofibrils, and oligomers. Due to these difficulties, a powerful strategy is needed for the disaggregation of amyloid aggregates by modulating their self-aggregation behavior. Herein, we repor…

Alzheimer's disease research and treatmentsLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Instabilities of Layers of Deposited Molecules on Chemically Stripe Patterned Substrates: Ridges versus Drops

Christoph Honisch、Te‐Sheng Lin、Andreas Heuer 等 5 位作者2015-09-04Langmuir

A mesoscopic continuum model is employed to analyze the transport mechanisms and structure formation during the redistribution stage of deposition experiments where organic molecules are deposited on a solid substrate with periodic stripe-like wettability patterns. Transversally invariant ridges located on the more we…

Block Copolymer Self-AssemblyFluid Dynamics and Thin Filmsnanoparticles nucleation surface interactions

Pharmacokinetics and Safety of Macrocyclic Gadobutrol in Children Aged Younger Than 2 Years Including Term Newborns in Comparison to Older Populations

Christian Kunze、Hans‐Joachim Mentzel、Rajesh Krishnamurthy 等 11 位作者2015-09-04Investigative Radiology

OBJECTIVES: This clinical study evaluated the pharmacokinetics (PK) and safety data of macrocyclic extracellular contrast agent gadobutrol in pediatric subjects aged younger than 2 years. MATERIALS AND METHODS: Pediatric subjects (term newborns to those aged younger than 2 years) with normal renal function undergoing…

Acute Kidney Injury ResearchPediatric Urology and Nephrology StudiesLanthanide and Transition Metal Complexes

Isoenergetic Polymorphism: The Puzzle of Tolazamide as a Case Study

E.V. Boldyreva、Sergey G. Arkhipov、T.N. Drebushchak 等 11 位作者2015-09-04Chemistry - A European Journal

In the present case study of tolazamide we illustrate how many seemingly contradictory results that have been obtained from experimental observations and theoretical calculations can finally start forming a consistent picture: a "puzzle put together". For many years, tolazamide was considered to have no polymorphs. Th…

Crystallography and molecular interactionsCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Identification of oxidoreductases from the petroleum Bacillus safensis strain

Francine Souza Alves da Fonseca、Célio Fernando Figueiredo Angolini、Marco Aurélio Zezzi Arruda 等 13 位作者2015-09-04Biotechnology Reports

A gram-positive bacterium, denominated CFA-06, was isolated from Brazilian petroleum in the Campos Basin and is responsible for the degradation of aromatic compounds and petroleum aromatic fractions. The CFA-06 strain was identified as Bacillus safensis using the 16S rRNA and gyrase B sequence. Enzymatic assays reveal…

Microbial bioremediation and biosurfactantsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Adjustable wideband reflective converter based on cut-wire metasurface

Linbo Zhang、Peiheng Zhou、Haiyan Chen 等 6 位作者2015-09-04Journal of Optics

We present the design, analysis, and measurement of a broadband reflective converter using a cut-wire (CW) metasurface. Based on the characteristics of LC resonances, the proposed reflective converter can rotate a linearly polarized (LP) wave into its cross-polarized wave at three resonance frequencies, or convert the…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

A Porphyrin Coordination Cage Assembled from Four Silver(I) Triazolyl‐Pyridine Complexes

Pablo Ballester、Mickaël Claudel、Stéphanie Durot 等 6 位作者2015-09-04Chemistry - A European Journal

The synthesis of a zinc(II) porphyrin 1 with four appended triazolyl-pyridine chelates is reported. Complexation of the porphyrin peripheral ligands with Ag(I) ions in a 1:2 binding stoichiometry afforded quantitatively the coordination cage [Ag4 (1)2 ](4+) . The assembly and disassembly processes of the cage were inv…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Growth of High Crystalline Quality HVPE-GaN Crystals with Controlled Electrical Properties

Jaime A. Freitas、James C. Culbertson、Nadeemullah A. Mahadik 等 6 位作者2015-09-04Crystal Growth & Design

Thick free-standing hydride vapor phase epitaxy (HVPE) GaN wafers were grown with close to perfect crystalline quality and with more than two orders of magnitude reduced free carrier concentration relative to ammonothermal GaN without resorting to deep level compensation. These new homoepitaxially grown crystals excee…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Vortex-induced morphology on a two-fluid interface and the transitions

Jih-Chiang Tsai、C.-Y. Tao、Yongtao Sun 等 7 位作者2015-09-04Physical Review E

We investigate experimentally the steady flows in a cylinder containing two immiscible liquids, with the primary fluid being driven by the upper boundary rotating at constant speeds. The system exhibits interesting interplays between the flow fields and the morphology of the interface, with evidence showing that the r…

Fluid Dynamics and Heat TransferPickering emulsions and particle stabilizationFluid Dynamics and Thin Films

The effects of technical and compositional variables on the size and release profile of bovine serum albumin from PLGA based particulate systems.

Behzad Taghipour、Mohammad Yakhchali、Ismaeil Haririan 等 5 位作者2015-09-04PubMed

Double emulsion solvent evaporation technique is one of the most attractive methods used to prepare micro and nanoparticles in pharmaceutical areas of interest, but because of the effects of many formulation factors on the size and release behavior of the fabricated particles, optimization of the formulation factors i…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

Full Three-Dimensonal Reconstruction of the Dyadic Green Tensor from Electron Energy Loss Spectroscopy of Plasmonic Nanoparticles

Anton Hörl、Andreas Trügler、Ulrich Hohenester2015-09-04ACS Photonics

Electron energy loss spectroscopy (EELS) has emerged as a powerful tool for the investigation of plasmonic nanoparticles, but the interpretation of EELS results in terms of optical quantities, such as the photonic local density of states, remains challenging. Recent work has demonstrated that, under restrictive assump…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Biomass‐Derived Hierarchical Nanoporous Carbon with Rich Functional Groups for Direct‐Electron‐Transfer‐Based Glucose Sensing

Xiaoling Zhong、Weiyong Yuan、Yuejun Kang 等 6 位作者2015-09-04ChemElectroChem

Abstract Glucose oxidase (GOD) is immobilized, for the first time, on a hierarchical nanoporous carbon (HNC) with rich functional groups by carbonizing a biomass derivation extracted from green tree leaves on a nanostructured CaCO 3 template at high temperature, which exhibits fast electrooxidation for glucose and dir…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Enhancement of superconductivity at the onset of charge-density-wave order in a metal

Yuxuan Wang、Andrey V. Chubukov2015-09-04Physical Review B

We analyze superconductivity in the cuprates near the onset of an incommensurate charge-density-wave (CDW) order with momentum $\mathbf{Q}=(Q,0)/(0,Q)$, as observed in experiments. We first consider a semiphenomenological charge-fermion model in which hot fermions, separated by $\mathbf{Q}$, attract each other by exch…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchIron-based superconductors research

Deciphering Photoluminescence Dynamics and Reactivity of the Luminescent Metal–Metal‐Bonded Excited State of a Binuclear Gold(I) Phosphine Complex Containing Open Coordination Sites

Chensheng Ma、Chris Tsz‐Leung Chan、Wai‐Pong To 等 5 位作者2015-09-04Chemistry - A European Journal

Luminescent metal complexes having open coordination sites hold promise in the design of sensory materials and photocatalysts. As a prototype example, [Au2 (dcpm)2)](2+) (dcpm = bis(dicyclohexylphosphanyl) is known for its intriguing environmental sensitive photoluminescence. By integrating a range of complementary ul…

Organometallic Complex Synthesis and CatalysisCatalytic C–H Functionalization MethodsNanocluster Synthesis and Applications

Efficient Counter Electrode Manufactured from Ag2S Nanocrystal Ink for Dye‐Sensitized Solar Cells

Qingquan He、Shoushuang Huang、Jiantao Zai 等 7 位作者2015-09-04Chemistry - A European Journal

It is generally believed that silver or silver-based compounds are not suitable counter electrode (CE) materials for dye-sensitized solar cells (DSSCs) due to the corrosion of the I(-) /I3 (-) redox couple in electrolytes. However, Ag2 S has potential applications in DSSCs for catalyzing I3 (-) reduction reactions bec…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Synthesis, cytotoxicity assessment, and interaction and docking of novel palladium(II) complexes of imidazole derivatives with human serum albumin

Mahboube Eslami Moghadam、Adeleh Divsalar、Abdolghafar Abolhosseini Shahrnoy 等 4 位作者2015-09-04Journal of Biomolecular Structure and Dynamics

Imidazole analogs are the agents that attract both bioinorganic chemist and drug designer. Numerous methods have been proposed for synthesis of imidazole derivatives. In this study, a series of heterocyclic system with p-conjugated system such as 2-aryl-imidazo[4,5-f][1,10]phenanthroline analogs were synthesized. Then…

Metal complexes synthesis and propertiesLanthanide and Transition Metal ComplexesSynthesis and Reactivity of Heterocycles

Understanding Structure–Function Relationship in Hybrid Co3O4–Fe2O3/C Lithium-Ion Battery Electrodes

Irin Sultana、Md Mokhlesur Rahman、Thrinathreddy Ramireddy 等 9 位作者2015-09-04ACS Applied Materials & Interfaces

A range of high-capacity Li-ion anode materials (conversion reactions with lithium) suffer from poor cycling stability and limited high-rate performance. These issues can be addressed through hybridization of multiple nanostructured components in an electrode. Using a Co3O4-Fe2O3/C system as an example, we demonstrate…

Advancements in Battery MaterialsMagnetic Properties and Synthesis of FerritesExtraction and Separation Processes

Toward Automated Benchmarking of Atomistic Force Fields: Neat Liquid Densities and Static Dielectric Constants from the ThermoML Data Archive

Kyle A. Beauchamp、Julie M. Behr、Ariën S. Rustenburg 等 6 位作者2015-09-04The Journal of Physical Chemistry B

Atomistic molecular simulations are a powerful way to make quantitative predictions, but the accuracy of these predictions depends entirely on the quality of the force field employed. Although experimental measurements of fundamental physical properties offer a straightforward approach for evaluating force field quali…

Protein Structure and DynamicsSpectroscopy and Quantum Chemical StudiesMachine Learning in Materials Science