Materials Literature
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Large quantities of engineered nanoparticles (NP), such as nanosilver (AgNP), have been widely applied, leading to an increased exposure and potential health concerns. Herein, we have examined the ability of AgNP to induce reactive oxygen species (ROS), their role in genotoxic effects and the involvement of mitogen-ac…
An attempt has been made to evaluate the performance characteristics of three different fusible interlinings used in apparel industries with sheep nappa leathers in terms of bending, softness, bond strength, shrinkage, tensile strength and double hole stitch tear strength. Of all aspects of performance investigated, i…
Local fracture toughness gives us useful and important information to understand and improve mechanical properties of bulk ceramics. In this study, the local fracture toughness of silicon nitride (Si 3 N 4 ) ceramics was directly measured using single‐edge notched microcantilever beam specimens prepared by the focused…
Hexagonal boron nitride hBN ceramic was successfully fabricated by pressureless sintering at 2100C using submicrometre hBN powders without any sintering additive. The as-prepared hBN ceramic showed a room temperature flexural strength of 30.7MPa. Its flexural strength increased with the increment of temperature in N2…
A key challenge in nanocluster research in particular and nanoscience in general is structure prediction for known compositions. Usually a simple ligand such as a methyl group is used to replace complex ligands in structure prediction of ligand-protected nanoclusters. However, how ligands dictate the energy landscape…
The local presence and concentration of metal ions in biological systems has been extensively studied ex vivo using fluorescent dyes. However, the detection of multiple metal ions in vivo remains a major challenge. We present a magnetic resonance imaging (MRI)-based method for noninvasive detection of specific ions th…
Newly developed crystallization routes have been designed to tailor graphene materials with specific functionalities, which can be a new direction in graphene R&D.
A series of structurally simple yet highly tunable organoboron luminophores was designed and synthesized. The solid-state fluorescence quantum yields exhibit nearly exponential growth by decorating the luminophore with additional sterically demanding substituents. Uniquely, the luminescence of these organoboron dyes c…
A host-guest inclusion compound [(DPA)(18-crown-6)]ClO4 (DPA = dipropylamine) undergoes a reversible phase transition at 214 K, which enables it to switch the NLO response between SHG-ON and SHG-OFF states associated with the order-disorder transition of the guest DPA cations and a slight tilting of the host 18-crown-…
Plasmonic hybrid nanomaterials are highly desirable in advanced sensing applications. Different components in these materials undertake distinct roles and work collectively. One material component may act as an efficient light concentrator and optical probe, whereas another provides specific chemical or biological fun…
Highly dispersed TiO <sub>2</sub> nanoparticles on graphene nanosheets were achieved by hydrothermal treatment of graphene nanosheets obtained by modified Hummer's method followed by thermal exfoliation.
The emergence of aggregation-induced emission (AIE) has opened up a new avenue for scientists. There is a great demand for the development of a new generation chemiluminescence resonance energy transfer (CRET) acceptors with AIE characteristics due to the aggregation-caused chemiluminescence (CL) quenching effect comm…
We report deep-red long-lasting persistent luminescence in Cr 3+ -doped LaAlO 3 perovskite phosphor synthesized by solid-state reaction. The LaAlO 3 :Cr 3+ sample showed persistent luminescence peaking at a very long wavelength of 734 nm due to Cr 3+ : 2 E → 4 A 2 transition after ultraviolet excitation. The Sm 3+ ion…
Silk has been used for centuries in the textile industry and as surgical sutures. In addition to its unique mechanical properties, silk possesses other properties, such as biocompatibility, biodegradability and ability to self-assemble, which make it an interesting material for biomedical applications. Although silk f…
An alkynylplatinum(II) terpyridine complex functionalized with polyhedral oligomeric silsesquioxanes (POSS) moieties has been demonstrated to exhibit self-association behavior to give various distinguishable nanostructures with interesting morphological transformation from rings to rods in response to solvent conditio…
The coexistence pressure of two phases is a well-defined point at fixed temperature. In experiment, however, due to non-hydrostatic stresses and a stress-dependent potential energy barrier, different measurements yield different ranges of pressure with a hysteresis. Accounting for these effects, we propose an inequali…
We investigate the fragmentation process of solid materials with crystalline and amorphous phases using the discrete element method. Damage initiates inside spherical samples above the contact zone in a region where the circumferential stress field is tensile. Cracks initiated in this region grow to form meridional pl…
We report the effect of varying cobalt thickness on the temperature-dependent time decay of the electrical resistance of Co/Sb multilayer samples. We find that for a given temperature, a five fold change in the Co thickness produces a 100 fold change in the characteristic decay time of the resistance. We find that the…
We perform detailed first principles calculations of the structural parameters at zero pressure and high pressure, the elastic properties, phonon dispersion relation, and ideal strengths of U2Mo with the C11b structure. In contrast to previous theoretical studies, we show that the I4/mmm structure is indeed a mechanic…
Aiming to develop a multi-functional flame retardant for epoxy resins, a novel bio-based eugenol derivative (SIEPDP) was synthesized, and was used to modify Mg–Al layered double hydroxide (SIEPDP-LDH). This modified SIEPDP-LDH was used as a novel nanoflame-retardant for bisphenol epoxy resins and compared with unmodif…