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Control of Nanoparticle Assembly by Using DNA‐Modified Diatom Templates

Nathaniel L. Rosi、C. Shad Thaxton、Chad A. Mirkin2004-10-13Angewandte Chemie International Edition

Microorganisms point the way: The silica cell walls of various diatoms were covalently functionalized with DNA by using straightforward chemical procedures and then used as templates for the sequence-specific assembly and 3D hierarchical arrangement of prefabricated DNA-modified gold nanoparticles. The DNA was used to…

Protist diversity and phylogenyPaleontology and Stratigraphy of FossilsDiatoms and Algae Research

Multiband theory of multi-exciton complexes in self-assembled quantum dots

Weidong Sheng、Shun-Jen Cheng、Pawel Hawrylak2004-10-13arXiv

We report on a multiband microscopic theory of many-exciton complexes in self-assembled quantum dots. The single particle states are obtained by three methods: single-band effective-mass approximation, the multiband $k\cdot p$ method, and the tight-binding method. The electronic structure calculations are coupled with…

Mesoscale and Nanoscale PhysicsMaterials Science

Electron scattering dependence of dendritic magnetic instability in superconducting MgB2 films

Z. X. Ye、Qiang Li、Y. F. Hu 等 8 位作者2004-10-13arXiv

Magnetic instability in both ultra-pure and carbon-doped MgB2 films is investigated by magneto-optical imaging, transport and bulk magnetization measurements. In the carbon-doped MgB2 thin film, familiar dendritic flux-jump patterns were observed at low temperature as reported in previous experiments. In the ultra-pur…

Materials ScienceSuperconductivity

Far-field optical microscope with nanometer-scale resolution based on in-plane surface plasmon imaging

Igor I. Smolyaninov2004-10-13arXiv

A new far-field optical microscopy technique capable of reaching nanometer-scale resolution has been developed recently using the in-plane image magnification by surface plasmon polaritons. This microscopy is based on the optical properties of a metal-dielectric interface that may, in principle, provide extremely larg…

Materials ScienceStrongly Correlated Electrons

Magnetic properties of a helical spin chain with alternating isotropic and anisotropic spins: Magnetization plateaus and finite entropy

Vinod Chandra、S. Ramasesha、Diptiman Sen2004-10-13Physical Review B

We propose a model which could explain some of the unusual magnetic properties observed for the one-dimensional helical spin system $\mathrm{Co}{(hfac)}_{2}\mathrm{N}\mathrm{I}\mathrm{T}\mathrm{Ph}\mathrm{O}\mathrm{Me}$. One of these properties is that the magnetization shows some plateaus if a magnetic field is appli…

Quantum many-body systemsMagnetism in coordination complexesTheoretical and Computational Physics

Photoconduction and photocontrolled collective effects in the Peierls conductor TaS$_3$

S. V. Zaitsev-Zotov、V. E. Minakova2004-10-13arXiv

Light illumination of thin crystals of CDW conductor TaS$_3$ is found to result in dramatic changes of both linear ($G$) and nonlinear conduction. The increase of $G$ is accompanied by suppression of the collective conduction, growth of the threshold field $E_T$, and appearance of the switching and hysteretic behavior…

Strongly Correlated ElectronsMaterials Science

Structural and effective charge determination for planar-zigzag beta-poly(vinylidene fluoride)

Nicholas J. Ramer、Kimberly A. Stiso2004-10-13arXiv

We present the computation of structural and polarization for a ferroelectric polymer, specifically, the beta-phase of poly(vinylidene fluoride) or (-CH$_2$-CF$_2$-)$_n$. Two structures have been described in the literature: one containing an undistorted carbon backbone (planar-zigzag) and the other containing alterna…

Materials Science

The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11

Kang Min Ok、P. Shiv Halasyamani2004-10-13Angewandte Chemie International Edition

The layered iodate Cs2I4O11 has been synthesized and characterized. Its hexagonal tungsten oxide-like framework consists of six-membered rings of corner-sharing IO5 polyhedra with three lone pairs pointing inward and three lone pairs pointing outward (depicted for central ring). Capping of the layer by asymmetric IO3…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyMetal-Organic Frameworks: Synthesis and Applications

Polymer Nanocomposites through Controlled Self-Assembly of Cubic Silsesquioxane Scaffolds

Lei Zheng、Sheng Hong、Grégoire Cardoen 等 6 位作者2004-10-13Macromolecules

A novel bottom-up approach to obtain polymer nanocomposites using cubic silsesquioxanes (POSS) nanoparticles as building blocks is reported. The design is based on associative interaction between particles to form ordered nanostructure and limited crystal growth to render anisotropic shapes. Specifically, the affinity…

Synthetic Organic Chemistry MethodsSilicone and Siloxane ChemistryAdvanced ceramic materials synthesis

Genome-Wide Transcriptional Analysis of the Cold Shock Response in Wild-Type and Cold-Sensitive, Quadruple- csp -Deletion Strains of Escherichia coli

Sangita Phadtare、Masayori Inouye2004-10-13Journal of Bacteriology

A DNA microarray-based global transcript profiling of Escherichia coli in response to cold shock showed that in addition to the known cold shock-inducible genes, new genes such as the flagellar operon, those encoding proteins involved in sugar transport and metabolism, and remarkably, genes encoding certain heat shock…

RNA and protein synthesis mechanismsProtein Structure and DynamicsEnzyme Structure and Function

Viscoelasticity of Single Wall Carbon Nanotube Suspensions

Lawrence A. Hough、Mohammad F. Islam、Paul A. Janmey 等 4 位作者2004-10-13Physical Review Letters

We investigate the viscoelastic properties of an associating rigid rod network: aqueous suspensions of surfactant stabilized single wall carbon nanotubes (SWNTs). The SWNT suspensions exhibit a rigidity percolation transition with an onset of solidlike elasticity at a volume fraction of 0.0026; the percolation exponen…

Mechanical and Optical ResonatorsCarbon Nanotubes in CompositesForce Microscopy Techniques and Applications

Size and Surface Effects of Prussian Blue Nanoparticles Protected by Organic Polymers

Takashi Uemura、Masaaki Ohba、Susumu Kitagawa2004-10-13Inorganic Chemistry

Prussian blue (PB) nanoparticles protected by organic polymers such as poly(vinylpyrrolidone) (PVP) and poly(diallyldimethylammonium chloride) (PDDA) were prepared. Different experimental conditions (concentrations of Fe ions and feed ratios of Fe to the polymers) have been investigated to control the size of the PB n…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsMagnetism in coordination complexes

Integrating Single‐Wall Carbon Nanotubes into Donor–Acceptor Nanohybrids

Dirk M. Guldi、Gul Rahman、Norbert Jux 等 5 位作者2004-10-13Angewandte Chemie International Edition

A tube for electrons: Through π–π and Coulomb interactions, a complex is obtained between carbon nanotubes grafted with pyrene+ (1) and the zinc porphyrin complex 2. Photoexcitation of the resulting donor–acceptor assembly is followed by a rapid and efficient charge separation to generate a charge-separated state that…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresPorphyrin and Phthalocyanine Chemistry

Phase Analysis of Quantum Oscillations in Graphite

Igor Lukyanchuk、Y. Kopelevich2004-10-13Physical Review Letters

The quantum de Haas-van Alphen (dHvA) and Shubnikov-de Haas oscillations measured in graphite were decomposed by pass-band filtering onto contributions from three different groups of carriers. Generalizing the theory of dHvA oscillations for 2D carriers with an arbitrary spectrum and by detecting the oscillation frequ…

Molecular Junctions and NanostructuresGraphene research and applicationsCarbon Nanotubes in Composites

Use of Electrospinning to Directly Fabricate Hollow Nanofibers with Functionalized Inner and Outer Surfaces

Dan Li、Jesse T. McCann、Younan Xia2004-10-13OpenAlex

Within or without: With the use of a coaxial, dual-capillary spinneret, electrospinning has been demonstrated as a versatile tool to fabricate hollow nanofibers with either their outer or inner surfaces being functionalized by molecular species or nanoparticles (the pictures show schematic cross sections of the functi…

Electrospun Nanofibers in Biomedical ApplicationsConducting polymers and applicationsSupercapacitor Materials and Fabrication

Fabrication and Biocompatibility of Carbon Nanotube-Based 3D Networks as Scaffolds for Cell Seeding and Growth

Miguel A. Correa‐Duarte、Nicholas Wagner、José Rojas-Chapana 等 6 位作者2004-10-13OpenAlex

Thin film networks of multiwalled carbon nanotubes (MWCNTs) were prepared by exerting chemically induced capillary forces upon the nanotubes. During this process MWCNTs undergo a transformation from being a vertically aligned structure to an interlocking resistive network of interconnected nanotubes, whose main featur…

Graphene and Nanomaterials ApplicationsCarbon Nanotubes in CompositesNeuroscience and Neural Engineering

Thermal decomposition, combustion and flame‐retardancy of epoxy resins—a review of the recent literature

Sergei V. Levchik、Edward D. Weil2004-10-13OpenAlex

Abstract An overview of the recent literature on combustion and flame‐retardancy of epoxy resins is presented. A brief overview of the structures of cured epoxy resins is also presented as a background for better understanding of the thermal decomposition and combustion phenomena. The literature sources were mostly ta…

Silicone and Siloxane ChemistryEpoxy Resin Curing ProcessesFlame retardant materials and properties

Evidence for a structurally-driven insulator-to-metal transition inVO2: A view from the ultrafast timescale

A. Cavalleri、T. Dekorsy、Henry Chong 等 5 位作者2004-10-13OpenAlex

We apply ultrafast spectroscopy to establish a time-domain hierarchy between structural and electronic effects in a strongly correlated electron system. We discuss the case of the model system ${\mathrm{VO}}_{2}$, a prototypical nonmagnetic compound that exhibits cell doubling, charge localization, and a metal-insulat…

Transition Metal Oxide NanomaterialsGa2O3 and related materialsAdvanced Memory and Neural Computing

New 1:3 Type Nickel−Bis(dithiolene) Salt (FcCHCHPymCH3)[Ni(dmit)2]3 (dmit: 2-Thioxo-1,3-dithiole-4,5-dithiolate): Its Electrocrystallization, Crystal Structure, Electrical Properties, and Electronic Band Structure Analysis

Yoon-Kyoung Han、Dong‐Kyun Seo、Haeyong Kang 等 5 位作者2004-10-12Inorganic Chemistry

Black single crystals of Ni(dmit)(2) complex (dmit: 2-thioxo-1,3-dithiole-4,5-dithiolate) with trans-4-[2-(1-ferrocenyl)vinyl]-1-methylpyridinium chromophore as a countercation, (FcCHCHPymCH(3))[Ni(dmit)(2)](3), were prepared by the electrocrystallization technique. In the triclinic structure of the complex (P, a = 11…

Magnetism in coordination complexesPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

Hypervelocity particle impact studies performed on a gold-coated beryllium substrate mirror

James B. Heaney、J. C. Pearl、M. Stuebig 等 5 位作者2004-10-12Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

This paper presents the results of the hypervelocity projectile bombardment of a gold-coated beryllium substrate telescope mirror. Individual latex (&#961; = 1.1 g/cm<sup>3</sup>) and iron (7.9 g/cm<sup>3</sup>) projectiles, in the size range 0.70 to 1.44&#956;m (avg. mass = 0.24 - 7.1 x 10<sup>-15</sup> kg), represen…

High-pressure geophysics and materialsHigh-Velocity Impact and Material BehaviorTraumatic Ocular and Foreign Body Injuries