ChemInform Abstract: Some Highs and Lows (and In‐Betweens) of Solubility Measurements of Solid Electrolytes
Abstract Review: 25 refs.
Materials Literature
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Abstract Review: 25 refs.
Particle-based simulations are performed to study the post-relaxation dynamics of functionalized (patchy) colloids adsorbed on an attractive substrate. Kinetically arrested structures that depend on the number of adsorbed particles and the strength of the particle-particle and particle-substrate interactions are ident…
Abstract Large single crystals of Ba2V(VO4)2(OH) (I) and Sr2V(VO4)2(OH) (II) are hydrothermally synthesized from mixtures of BaO or SrO, V2O3, V2O5, and aqueous NaOH as a mineralizer solution (Ag ampules, autoclave, 1.2 kbar, 650 °C, 10 d).
Abstract A reduced form of Sr2FeMoO6 is synthesized through topochemical reduction with CaH2 (glass ampule, 500 °C, 3 d).
Abstract ε‐Fe3N magnetic nanospheres of an average 45 nm size are prepared by nitriding Fe nanoparticles with gaseous NH3 (alumina boat, 650 °C, 4 h).
Abstract Review: 863 refs.].
Abstract Oxidation of Pd with oleum (65% SO3) in the presence of BaCO3 (sealed glass ampoules, 180 °C) results in single crystals of Ba2 [Pd(HS2O7)2 (S3O10)2] which crystallize in the triclinic space group P$\bar 1$ (Z = 1, single crystal XRD) and show Pd2+ in a square‐planar coordination of O atoms from two [HS2O7] a…
Abstract Review: 76 refs.
Abstract The Nazarov reaction of divinylketones of type (I) affording cyclopentenone derivatives of type (II) is the key step in the synthesis of new photochromic diarylethenes.
Abstract A black metallic single crystal of the title compound is synthesized from the elements using lithium metal as a flux (Nb ampule, 1250 °C, 72 h).
선캠브리아기의 지리산 편마암 복합체는 초기의 백립암상에서 후기의 각섬암상 또는 녹색편암상까지 후퇴변성작용을 받았으며, 편마암 복합체 내 관입한 하동 회장암체는 이 중 후기 변성작용의 영향을 받았다. 회장암체 내 주요 유색광물은 각섬석으로 이를 통해 변성조건 및 변성상에 관한 추정이 가능하다. 회장암체 내 각섬석은 개방니콜 하에서 주로 청녹색 내지 녹색을 나타내고, 반자형 내지타형의 형태를 보인다. 일부 갈색의 각섬석 주변부로 청록색으로 변하는 누대조직(zonal texture)이 존재하고, 사방휘석 내에는 각섬석으로 변하는 반응부가 존재해 후퇴변성 내지 변질 양상을…
Abstract The formation of complex phosphates is investigated in melts containing Rb2CO3, H3PO4, TiO2, and NiO at different molar ratios of Rb:P = 0.5‐1.3, Ti:P = 0.15, Ti:Ni = 1.0 at 1073‐953 K (Pt crucible, 1273 K, 3 h).
One of the early triumphs of quantum physics is the explanation why some materials are metallic whereas others are insulating. While a treatment based on single electron states correctly predicts the character of most materials this approach can fail spectacularly, when the electrostatic repulsion between electrons ca…
Abstract Review: 72 refs.
Abstract SrGa12O19:Cr3+x (x = 0.0005‐0.02) are fabricated by calcination of stoichiometric amounts of SrCO3, Ga2O3, and Cr2O3 in air (1.
Abstract Yb3+/Er3+, Yb3+/Tm3+, or Yb3+/Er3+/Tm3+ (25, 1, and 0.5 mol%, resp.) co‐doped Ca9Y(PO4)7 are prepared by hydrothermal reaction of a stoichiometric solution of CaCO3, Y2O3, and lanthanide oxides in HNO3 to which (NH4)2HPO4 is added at a controlled pH of 8 (autoclave, 200 °C, 10 h) followed by annealing in air…
Abstract The heterogeneous title reaction exhibits superior activity compared to homogeneous cobalt phthalocyanine catalysts with added benefits of easy recovery and recycling.
Abstract The stability of MgH6 with a sodalite‐like framework at <150 GPa is predicted by first‐principles DFT calculations.
Abstract Review: [preparation, molecular design, structural relationship, and performance characteristics; 85 refs.
Abstract Review: 42 refs.