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Atomic structure of a complex defect configuration in synthetic diamond: A fivefold twin centre connected to two high-order grain boundaries

D. Dorignac、S. Delclos、F. Phillipp2001-11-01Philosophical Magazine B

Elucidation of a complex defect configuration arising from the interaction between eight first-order twin boundaries in a diamond thin film prepared by chemical vapour deposition on a silicon substrate is reported. The defect has been identified by ultrahigh-resolution electron microscopy at 0.12nm resolution. It is s…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

A New Oleanane Triterpenoid fromGordonia ceylanica

H. M. T. Bandara Herath、P.S. Athukoralage、Joanne F. Jamie2001-11-01Natural product letters

The chemical investigation of the hexane extract of the stem bark of Gordonia ceylanica afforded 3beta-acetoxy-11alpha(2',3'-epoxyferulyloxy)-olean-13(18)-ene as a new natural product and alpha-spinasterol for the first time from Gordonia.

Marine Sponges and Natural ProductsPhytochemical Studies and BioactivitiesPhytochemistry and Bioactive Compounds

Einkristalle des Cer(IV)–Oxotellurats(IV) CeTe2O6

Steffen F. Meier、Frank A. Weber、Roger Gläser 等 4 位作者2001-11-01Zeitschrift für anorganische und allgemeine Chemie

Single Crystals of the Cerium(IV) Oxotellurate(IV) CeTe2O6 Orange-red, coffin-shaped single crystals of CeTe2O6 (monoclinic, P21/n; a = 703.71(5), b = 1106.32(8), c = 735.24(5) pm, β = 108.066(6)°; Z = 4) were obtained by the reaction of admixtures of cerium dioxide and tellurium dioxide (CeO2, TeO2; molar ratio 1 : 2…

Crystal structures of chemical compoundsCrystal Structures and PropertiesOrganometallic Compounds Synthesis and Characterization

Wet oxidation of domestic sludge and process integration: the Mineralis® process

Thomas Lendormi、C. Prévot、F. Doppenberg 等 5 位作者2001-11-01Water Science & Technology

Wet oxidation (WO) in subcritical conditions is a new alternative to usual routes for sewage sludge treatment that complies with environmental standards. This paper presents tests carried out using a batch reactor and continuous pilot and industrial units, treating municipal sewage sludge. The main products after oxid…

Catalytic Processes in Materials ScienceAdvanced oxidation water treatmentEnvironmental remediation with nanomaterials

In‐situ investigation on the oxidation behaviour of low alloyed steels annealed under N2‐5%H2 protective atmospheres

Carlos J. Martinez、R. Cremer、D. Loison 等 4 位作者2001-11-01Steel Research

The oxidation behaviour of low alloyed steels, Fe‐0.6%Mn and Fe‐1.5%Mn, under different annealing conditions was studied. Due to the crucial importance of the surface state of the sample, the experiments were performed in an in‐situ device to avoid any contact with air after the annealings. The annealing experiments w…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsElectron and X-Ray Spectroscopy Techniques

Processing, Characterization, and Dielectric Studies on K(Ta 1− x Nb x )O 3 for Use at Cryogenic Temperatures

Cristopher B. DiAntonio、Stephen M. Pilgrim2001-11-01Journal of the American Ceramic Society

Development of the next generation space telescope, to supplement the Hubble Space Telescope, has heightened the need for cryogenic actuators. High performance electromechanical materials are needed for use from 10 to 77 K. The use of piezoelectric materials to satisfy this need involves major property trade‐offs; con…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Modeling and Numerical Simulation on Thermomechanical Behavior of SMA Plates with Two-Way Shape Memory Effect

Toshiyuki Takagi、Yun Luo、Shunji Suzuki 等 5 位作者2001-11-01Journal of Intelligent Material Systems and Structures

Phenomenological modeling on the thermomechanical behavior of shape memory alloy (SMA) plates with two-way shape memory effect (TWSME) is presented in this paper. Two important characteristics of SMA materials as sensors or actuators; the thermal responses and the transformation accompanied deformation; are described…

Shape Memory Alloy TransformationsAeroelasticity and Vibration ControlTopology Optimization in Engineering

Isotope Exchange Capacity on Li4SiO4and Comparison of Tritium Inventory in Various Solid Breeder Blankets

Masabumi Nishikawa、N. Nakashima、K. Hashimoto 等 4 位作者2001-11-01Journal of Nuclear Science and Technology

It has been pointed out by the present authors that it is essential to understand such mass transfer steps as diffusion of tritium in the grain of a breeder material, absorption of water vapor into bulk of the grain, adsorption of water on surface of the grain, and exchange capacity of tritium to be trapped to surface…

Fusion materials and technologiesNuclear Materials and PropertiesGraphite, nuclear technology, radiation studies

Structural Versatility of Oxalamide-Based Compounds: A Computational Study on the Isomerization of the Oxalamide Group and the Structural Preferences of the Polyoxalamides

Elaine Armelín、Carlos Alemán、Jordi Puiggalı́2001-11-01The Journal of Organic Chemistry

The conformational properties of the oxalamide group and crystal structure of several polyoxalamides have been investigated by computational methods. First, a detailed quantum mechanical study of the conformational preferences of N,N'-dimethyloxalamide is reported. Results, which were obtained at the MP2/6-31G(d) leve…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

X-ray study of Nd0.5Sr0.5MnO3 manganite structure above and below the ferromagnetic metal–antiferromagnetic insulator spontaneous phase transition

V. V. Eremenko、S. L. Gnatchenko、N. Makedonska 等 10 位作者2001-11-01Low Temperature Physics

The crystal structure of the manganite Nd0.5Sr0.5MnO3 is studied at temperature T=300 and 77.3 K by means of an x-ray diffractometer. It is shown that the transition from the ferromagnetic metallic state to the antiferromagnetic insulating charge-ordered state is accompanied by a lowering of the symmetry of the struct…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsShape Memory Alloy Transformations

Preparation of Optically Active β-Amino Acids from Microbial Polyester Polyhydroxyalkanoates

Sang Hyun Park、Seung Hwan Lee、Sang Yup Lee 等 5 位作者2001-11-01Journal of Chemical Research

An efficient method for the preparation of optically active ethyl β-aminobutyrate from the biopolymer, poly-( R)-(-)-3-hydroxybutyrate (PHB) obtained from bacterial cells has been established using chemical transformations: simple recovery of PHB from bacterial cells followed by acidic alcoholysis, tosylation, nucleop…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesChemical Synthesis and Analysis

High temperature Cu-Al-Nb - based shape memory alloys

J. Lelątko、H. Morawiec2001-11-01Journal de Physique IV (Proceedings)

New type of Cu-AI-Nb -base alloys containing nickel, cobalt and chromium with high martensitic transformation temperatures have been developed. In this paper the mechanical properties, shape memory characteristics, the temperatures of reversible martensitic transformation and thermal stability of these alloys are pres…

Shape Memory Alloy TransformationsSolidification and crystal growth phenomenaIntermetallics and Advanced Alloy Properties

Lattice deformations at martensite-martensite interfaces in Ni-Al

D. Schryvers、Philippe Boullay、Robert V. Kohn 等 4 位作者2001-11-01Journal de Physique IV (Proceedings)

The atomic configurations at macrotwin interfaces between microtwinned martensite plates in Ni 65 AI, 5 material are investigated using high resolution transmission electron microscopy (HRTEM). The observed structures are interpreted in view of possible formation mechanisms of these interfaces. A distinction is made b…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsShape Memory Alloy Transformations

Effect of biomineralized manganese on pitting corrosion of type 304L stainless steel

B. H. Olesen、Nurdan Yurt、Zbigniew Lewandowski2001-11-01Materials and Corrosion

During the past few years, biomineralized manganese has been shown to cause ennoblement of various stainless steels to open circuit potentials of 300–400 mV/SCE. We have demonstrated that ennoblement, caused by biologically deposited manganese minerals, along with a relatively low stainless steel pitting potential, ca…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Preparation, Properties, and Crystal Structure of Quaternary Silicide Carbides RCr2Si2C (R = Y, La - Nd, Sm, Gd - Ho)

Marc W. Pohlkamp、Wolfgang Jeitschko2001-11-01Zeitschrift für Naturforschung B

The title compounds were prepared by arc-melting cold-pressed pellets of the elemental components. They crystallize with a tetragonal structure already reported for CeCr 2 Si 2 C. It was refined from single-crystal X-ray data of PrCr 2 S 2 C: P4/mmm, a - 402.2( 1) pm, c = 535.2(1) pm, Z = 1, R = 0.012 for 252 structur…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Crystallographic texture in ceramics and metals

Mark D. Vaudin2001-11-01Journal of Research of the National Institute of Standards and Technology

Preferred crystallographic orientation, or texture, occurs almost universally, both in natural and man-made systems. Many components and devices in electronic and magnetic systems are fabricated from materials that have crystallographic texture. With the rapidly increasing use of thin film technology, where sharp axis…

Microstructure and mechanical propertiesNuclear Physics and ApplicationsX-ray Diffraction in Crystallography

Field electron emission in graphite-like films

A. N. Obraztsov、I. Yu. Pavlovskii、А. П. Волков2001-11-01Technical Physics

Results of investigation of carbon films deposited with the use of gas-phase chemical reactions in the plasma of a dc discharge are presented. Films obtained at different parameters of the deposition process varied widely in their structure and phase composition, from polycrystalline diamond to graphite-like material.…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

The equation of bubble dynamics in a compressible linear viscoelastic liquid

Emil‐Alexandru Brujan2001-11-01Fluid Dynamics Research

Several forms of the equation describing the radial motion of a spherical bubble in a compressible linear viscoelastic liquid are derived. The relative merits of these equations are discussed by using a three-parameter linear Oldroyd model to describe the non-Newtonian properties of the liquid.

Enhanced Oil Recovery TechniquesFluid Dynamics and MixingUltrasound and Cavitation Phenomena

Characterization of a maltose transport system in Clostridium acetobutylicum ATCC 824

Martin Tangney、GT Winters、WJ Mitchell2001-11-01Journal of Industrial Microbiology & Biotechnology

The utilization of maltose by Clostridium acetobutylicum ATCC 824 was investigated. Glucose was used preferentially to maltose, when both substrates were present in the medium. Maltose phosphoenolpyruvate (PEP)-dependent phosphotransferase system (PTS) activity was detected in extracts prepared from cultures grown on…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionEnzyme Production and Characterization

Polylactones, 56. ABA Triblock Copolymers Derived fromɛ-Caprolactone orL-Lactide and a Central Polysiloxane Block

Hans R. Kricheldorf、Dennis Langanke2001-11-01Macromolecular Bioscience

A commercial oligosiloxane having two γ-hydroxypropyl endgroups and a number-average molecular weight (M̄n) around 1 000 Da was condensed with Bu2Sn(OMe)2 yielding tin-containing macrocycles but no polymers. These macrocycles reacted with γ-thiobutyrolactone by insertion of one thiolactone per Sn—O bond. When ε-caprol…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisSilicone and Siloxane Chemistry