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Expansion and crystallization of a sediment of charged colloidal spheres

Jeroen S. van Duijneveldt、Jan K. G. Dhont、H. N. W. Lekkerkerker1993-11-01The Journal of Chemical Physics

An amorphous sediment of charged colloidal particles in a nonaqueous solvent was prepared by centrifugation. The evolution of sediment height and volume fraction profile to equilibrium were studied with light scattering. A simple sedimentation–diffusion equation allows the experimental data to be modeled quantitativel…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Shrinkage Formation During the Solidification Process in an Open Rectangular Cavity

C.-J. Kim、S. T. Ro1993-11-01ASME Journal of Heat and Mass Transfer

Technical Briefs Shrinkage Formation During the Solidification Process in an Open Rectangular Cavity C.-J. Kim, C.-J. Kim Department of Mechanical Engineering, Seoul National University, Seoul 151-742, Korea Search for other works by this author on: This Site PubMed Google Scholar S. T. Ro S. T. Ro Department of Mecha…

Aluminum Alloy Microstructure PropertiesHigh Temperature Alloys and CreepSolidification and crystal growth phenomena

Isolation, characterization and nucleotide sequence of the Streptococcus mutans lactose-specific Enzyme II (lacE) gene of the PTS and the phospho- -galactosidase (lacG) gene

Allen L. Honeyman、Roy Curtiss1993-11-01Journal of General Microbiology

The lacE and lacG genes from Streptococcus mutans have been isolated and characterized, and their nucleotide sequence has been determined. The lacE gene encodes the lactose-specific Enzyme II component of the phosphoenolpyruvate-dependent phosphotransferase system (PTS). The lacG gene encodes the phospho-beta-galactos…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

The oxidative dechlorination reaction of 2,4,6-trichlorophenol in dilute aqueous suspensions of manganese oxides

Ljerka Ukrainczyk、Murray B. McBride1993-11-01Environmental Toxicology and Chemistry

Abstract Oxidation of 2,4,6-trichlorophenol (TCP) by layered manganese oxides (Na and Co-buserite) in dilute acidified aqueous suspension gives 2,6-dichloro-p-benzoquinone as a major product. This compound is likely to further polymerize and become incorporated into humuslike materials. The oxidation rate was higher a…

Extraction and Separation ProcessesElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

Empirical many-body potential energy functions for iron

Fei Gao、Roy L. Johnston、J.N. Murrell1993-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEmpirical many-body potential energy functions for ironFei Gao, Roy L. Johnston, and John N. MurrellCite this: J. Phys. Chem. 1993, 97, 46, 12073–12082Publication Date (Print):November 1, 1993Publication History Published online1 May 2002Published inissue 1 November 1993http…

Advanced Chemical Physics StudiesAdvanced Physical and Chemical Molecular InteractionsThermal and Kinetic Analysis

Why hydrogen-bonded liquids tend to have high static dielectric constants

Saul Goldman、Chris Joslin1993-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWhy hydrogen-bonded liquids tend to have high static dielectric constantsSaul Goldman and Chris JoslinCite this: J. Phys. Chem. 1993, 97, 47, 12349–12355Publication Date (Print):November 1, 1993Publication History Published online1 May 2002Published inissue 1 November 1993ht…

Advanced Chemical Sensor TechnologiesSolid-state spectroscopy and crystallography

Thermodynamic Activities in B 2 O 3 ‐SiO 2 Melts at 1475 K

Martin Boike、K. Hilpert、Franz Müller1993-11-01Journal of the American Ceramic Society

Eight glass samples in the B 2 O 3 ‐SiO 2 system with compositions from 20 to 90 mol% B 2 O 3 were prepared. The equilibrium vaporization was studied by Knudsen effusion mass spectrometry at temperatures between 1450 and 1500 K. B 2 O 3 ( g ) was the most abundant boron‐containing species in the vapor; no silicon‐cont…

Luminescence Properties of Advanced MaterialsHigh-pressure geophysics and materialsGlass properties and applications

Thin films of a binary polymer system: poly(vinyl acetate)/poly(dimethylsiloxane) layers at the air/water interface

Frank Runge、Hyuk Yu1993-11-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThin films of a binary polymer system: poly(vinyl acetate)/poly(dimethylsiloxane) layers at the air/water interfaceFrank E. Runge and Hyuk YuCite this: Langmuir 1993, 9, 11, 3191–3199Publication Date (Print):November 1, 1993Publication History Published online1 May 2002Publi…

Surface Modification and Superhydrophobicity

Free‐Radical stabilizers for the thiol/ene‐systems

Elisabeth Klemm、Steffi Sensfuß、Uta Holfter 等 4 位作者1993-11-01Die Angewandte Makromolekulare Chemie

Abstract By means of calorimetric investigations it is shown that dithiol/diene‐mixtures show a more or less distinct spontaneous dark reaction, without light and in the absence of initiators. Pyrogallol, hydroquinone and catechol were tested as stabilizers. The efficacy of the stabilizer to transform the radicals res…

Organic and Molecular Conductors ResearchVarious Chemistry Research TopicsOrganic Chemistry Cycloaddition Reactions

Activity of the keggin polyoxotungstate pm‐19 against herpes simplex virus type 2 infection in immunosuppressed mice: Role of peritoneal macrophage activation

Satoru Ikeda、Shigeki Nishiya、Akihiro Yamamoto 等 6 位作者1993-11-01Journal of Medical Virology

The in vivo antiviral activity of the Keggin polyoxotungstate PM-19 [K7(PTi2W10O40).6H2O] against herpes simplex virus type 2 (HSV-2) was investigated in mice immunosuppressed by cyclophosphamide (CY). When PM-19 was administered intraperitoneally to immunosuppressed mice for 3 days (once daily) starting at the time o…

Polyoxometalates: Synthesis and ApplicationsSulfur-Based Synthesis TechniquesSynthesis and Characterization of Heterocyclic Compounds

The Properties and Applications of Shape Memory Polyurethanes

Richard F. Gordon1993-11-01Materials Technology

In this article, the important properties and applications of shape memory polyurethanes are introduced. A number of dramatic property changes occurring at the glass transition temperature are reviewed, including elastic modulus, hardness, damping, variable vapor permeability, shape memory, and fixity. Stress-strain-t…

Polymer composites and self-healing

Dielectric Properties and Ferroelectric Domain of BaTiO3 Powders

Hsing‐I Hsiang、Fu-Su Yen Fu-Su Yen1993-11-01Japanese Journal of Applied Physics

A systematic study of the particle size dependence of the ferroelectric domain, internal stress and dielectric constant ( K ) of BaTiO 3 powders was performed using scanning electron microscopy, X-ray diffractometer and differential scanning calorimetry. The dielectric constant of BaTiO 3 powder was lower than that of…

Ferroelectric and Piezoelectric MaterialsPolymer Nanocomposites and PropertiesDielectric materials and actuators

Paraelastic—ferroelastic interfaces

J. Dec1993-11-01Phase Transitions

Paraelastic–ferroelastic phase boundaries (interfaces) are two-dimensional formations in the three-dimensional crystal lattice, which accommodate the crystal lattices of two neighbouring modifications of the same compound. Their characteristic features include both orientation and kinetic properties. Three theories ar…

High-pressure geophysics and materialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

A Review of Commercial Polyblends Based on PVC, ABS, and PC

A. K. Kulshreshtha1993-11-01Polymer-Plastics Technology and Engineering

Information available from recent literature (1—6) is presented in this report on PVC-based, ABS-based, and PC-based polyblends. Property profiles of polyblends are superior to those of component homopolymers. Enhanced properties, combined with the low cost of polyblends, make them economically attractive for special…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Science and PVC

Evidence of a quantitative relationship between the degree of hydrogen intercalation and the coercivity of the two permanent magnet alloys Nd/sub 2/Fe/sub 14/B and Nd/sub 2/Fe/sub 11/Co/sub 3/B

E. Claude、S. Ram、Iara F. Gimenez 等 6 位作者1993-11-01IEEE Transactions on Magnetics

Nd/sub 2/Fe/sub 14/BH/sub x/ micron-size loose particles are synthesized by the oxide reduction-diffusion technique. When excess Ca is used as a reducing agent, an exothermic reaction is observed by washing under water, with production of native hydrogen that diffuses in the interstitial sites of the alloy. Depending…

Hydrogen Storage and MaterialsMagnetic Properties of AlloysSuperconducting Materials and Applications

Carbon(IV) Nitride C3N4— A New Material Harder Than Diamond?

Wolfgang Schnick1993-11-01Angewandte Chemie International Edition in English

Numerous complex interacting factors complicate the prediction of the existence, structure, and properties of solid‐state compounds. No success crowned the efforts to synthesize a compound of composition C 3 N 4 having a β‐Si 3 N 4 structure, which should have the hardness and stability of diamond. Recently Lieber et…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

A magnetostrictive electric generator

Anna Sofia Lundgren、H. Tiberg、L. Kvarnsjö 等 5 位作者1993-11-01IEEE Transactions on Magnetics

An electric generator based on the magnetostrictive effect is presented. Longitudinal oscillations of a Terfenol-D rod give rise to a varying flux which induces a current in a coil wound around the rod. A small prototype of such a device is discussed, and both calculations and experiments are performed. The problem of…

Magnetic properties of thin filmsNonlinear Dynamics and Pattern FormationMagnetic Properties and Applications

Ruthenium(II) complexes of a fused phenanthroline-pteridinedione ligand

Kirk J. Black、Huakai Huang、Stacie High 等 6 位作者1993-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRuthenium(II) complexes of a fused phenanthroline-pteridinedione ligandKirk J. Black, Huakai Huang, Stacie High, Lee Starks, Mark Olson, and Mark E. McGuireCite this: Inorg. Chem. 1993, 32, 24, 5591–5596Publication Date (Print):November 1, 1993Publication History Published o…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Solid-State Transition Mechanisms of Ammonium Nitrate Phases IV, III, and II Investigated by Simultaneous Raman Spectrometry and Differential Scanning Calorimetry

Mauno E. E. Harju1993-11-01Applied Spectroscopy

The solid-state transition mechanisms of ammonium nitrate IV, III, and II were studied by measuring samples simultaneously by Raman spectrometry and differential scanning calorimetry (DSC). The Raman instruments were a Fourier transform Raman spectrophotometer and triple monochromator Raman spectrophotometer with char…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Poly(styrene-co-N-maleimide) copolymers: preparation by reactive extrusion, molecular characterization by FTIR, and use in blends

I. Vermeesch、G. Groeninckx、M . M . Coleman1993-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPoly(styrene-co-N-maleimide) copolymers: preparation by reactive extrusion, molecular characterization by FTIR, and use in blendsI. M. Vermeesch, G. Groeninckx, and M. M. ColemanCite this: Macromolecules 1993, 26, 24, 6643–6649Publication Date (Print):November 1, 1993Publica…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties