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Detection of Nitric Oxide and Nitrogen Dioxide with Photoluminescent Porous Silicon

Jessica Harper、Michael J. Sailor1996-11-01Analytical Chemistry

The visible photoluminescence of porous Si is quenched by nitric oxide and nitrogen dioxide to detection limits of 1.4 × 10(-)(3) and 5.3 × 10(-)(5) Torr, respectively (corresponding to 2 ppm and 70 ppb). At analyte partial pressures in the low milliTorr range, the photoluminescence quenching is partially reversible;…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnalytical Chemistry and Sensors

Time-resolved fluorescence-line narrowing and energy-transfer studies in aEu3+-doped fluorophosphate glass

R. Balda、J.F. Fernández、Jean‐Luc Adam 等 4 位作者1996-11-01Physical review. B, Condensed matter

The optical properties of ${\mathrm{Eu}}^{3+}$-doped fluorophosphate glasses of composition (in mol %) 60 ${\mathrm{NaPO}}_{3}$-${15\mathrm{B}\mathrm{a}\mathrm{F}}_{2}$-(25-x)${\mathrm{YF}}_{3}$-x${\mathrm{EuF}}_{3}$ (x=0.5, 2, 5, 10, 15, 20, and 25) have been investigated in the 4.2--300 K temperature range by using…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Improved blood compatibility of segmented polyurethanes by polymeric additives having phospholipid polar groups. I. Molecular design of polymeric additives and their functions

Kazuhíko Ishihara、Shinobu Tanaka、Naoya Furukawa 等 5 位作者1996-11-01Journal of Biomedical Materials Research

To improve the blood compatibility of a segmented polyurethane (SPU), 2-methacryloyloxyethyl phosphorylcholine (MPC) polymer was blended with the SPU. The MPC was copolymerized with cyclohexyl methacrylate (CHMA) or 2-ethylhexyl methacrylate (EHMA), and the MPC polymers obtained could be dissolved in the same solvent…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesSynthetic Organic Chemistry Methods

Measuring Fiber Orientation in Nonwovens

Behnam Pourdeyhimi、R. Ramanathan、R. W. Dent1996-11-01Textile Research Journal

In nonwovens, fiber orientation is an important characteristic because it directly influences the properties of the material. In a series of papers, we plan to explore the viability of image analysis algorithms for characterizing fiber orientation. In the first part of this series, we present a simulation scheme to pr…

3D Shape Modeling and AnalysisTextile materials and evaluationsIndustrial Vision Systems and Defect Detection

High‐Pressure Sintering of Nanocrystalline γAl 2 O 3

Rajiv S. Mishra、Charles E. Lesher、Amiya K. Mukherjee1996-11-01Journal of the American Ceramic Society

High‐pressure sintering of nanocrystalline γ‐A1 2 O 3 has been studied over a temperature range of 923‐1323 K and at a pressure of 1 GPa. The γ‐Al 2 O 3 to α‐Al 2 O 3 transformation temperature changed from 1473 K without pressure to ∼1023 K at 1 GPa. Full density was obtained at 1273 and 1323 K in 10 min. The microha…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

Polymerized Complex Route to Barium Titanate Powders Using Barium‐Titanium Mixed‐Metal Citric Acid Complex

Momoko Arima、Masato Kakihana、Yoshiyuki Nakamura 等 5 位作者1996-11-01Journal of the American Ceramic Society

Barium titanate (BaTiO 3 ) powders were prepared by a polymerized complex method based on the Pechini‐type reaction route, wherein a mixed solution of citric acid (CA), ethylene glycol (EG), and barium and titanium ions, with a molar ratio of CA:EG:Ba:Ti = 10:40:1:1, was polymerized to form a transparent resin, which…

Bone Tissue Engineering MaterialsFerroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics Synthesis

BTEX Sorption by Organo‐Clays: Cosorptive Enhancement and Equivalence of Interlayer Complexes

W. F. Jaynes、G. F. Vance1996-11-01Soil Science Society of America Journal

Abstract Aqueous organic contaminants, such as gasoline‐derived aromatics, are effectively sorbed by organo‐clays. Organo‐clays were prepared from montmorillonite (SWy‐1, SAz‐1) and vermiculite (VSC) clay minerals by exchanging quaternary, alkylammonium cations for the inorganic exchange cations; thus, a variety of cl…

Clay minerals and soil interactions

Biodiversity of microorganisms that degrade bacterial and synthetic polyesters

Joris Mergaert、Jean Swings1996-11-01Journal of Industrial Microbiology & Biotechnology

The biodiversity and occurrence in nature of bioplastic-degrading microorganisms are exemplified by the identification of 695 strains, isolated from different environments, such as soils, composts, natural waters, and sludge, that are able to degrade the bacterial polyester poly(3-hydroxybutyrate)in vitro. These micro…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Abinitiomolecular-dynamics study of the structural, vibrational, and electronic properties of glassyGeSe2

Mark Cobb、D. A. Drabold、R. L. Cappelletti1996-11-01Physical review. B, Condensed matter

We present results of an ab initio molecular-dynamics study of glassy ${\mathrm{GeSe}}_{2}$ using a 216 atom model. The network topology of our model is analyzed through partial pair correlations, angle distributions, partial static structure factors, and ring structures. The total static structure factor and first sh…

Glass properties and applicationsSpectroscopy and Quantum Chemical StudiesPhase-change materials and chalcogenides

Conductive dots, wires, and supertips for field electron emitters produced by electron-beam induced deposition on samples having increased temperature

H. W. P. Koops、C. Schößler、A. Kaya 等 4 位作者1996-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

The procedure for three-dimensional additive lithography with electron-beam induced deposition is applied in a scanning electron microscope equipped with an image processor beam control system for lithography. Employing organometallic materials, which contain gold or platinum, quantum dots, resistors, and field emitte…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Sequence and properties of pentaerythritol tetranitrate reductase from Enterobacter cloacae PB2

Chris French、S. Nicklin、Neil C. Bruce1996-11-01Journal of Bacteriology

Pentaerythritol tetranitrate reductase, which reductively liberates nitrite from nitrate esters, is related to old yellow enzyme. Pentaerythritol tetranitrate reductase follows a ping-pong mechanism with competitive substrate inhibition by NADPH, is strongly inhibited by steroids, and is capable of reducing the unsatu…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Physical processes of the interaction of fusion plasmas with solids

U. Samm1996-11-01Plasma Physics and Controlled Fusion

This book covers the most important issues of plasma - wall interactions in nuclear fusion devices. Several authors, all actively working in that particular field, have written articles on surface phenomena (erosion mechanisms, particle recyling, wall coatings and ablation) and bulk material properties (thermal stabil…

Magnetic confinement fusion researchFusion materials and technologies

Modelling of additive diffusion in polyolefins

William Limm、Henry C. Hollifield1996-11-01Food Additives & Contaminants

A semi-empirical model has been developed for additive diffusion in polymers. The model estimates apparent diffusion coefficients of an additive migrating through polyolefin polymers into a fatty food simulant for a range of temperatures between the glass transition and melting temperatures of the polymer. This diffus…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Passive‐Oxidation Kinetics of High‐Purity Silicon Carbide from 800° to 1100°C

C. Eric Ramberg、Gary Cruciani、Karl E. Spear 等 5 位作者1996-11-01Journal of the American Ceramic Society

Highly textured chemically vapor‐deposited silicon carbide (CVD‐SiC) thick films were oxidized and compared to single‐crystal SiC and single‐crystal silicon. The oxidation rates of the (111) face of the cubic CVD‐SiC were the same as those of the (0001) face of the single‐crystal SiC. Similarly, the opposite faces of…

Advanced ceramic materials synthesisSemiconductor materials and devicesAdvanced materials and composites

Fourier transform IR spectroscopic study of hydration-induced structure changes in the solid state of ω-gliadins

Nikolaus Wellner、Peter Belton、Arthur S. Tatham1996-11-01Biochemical Journal

The hydration of omega-gliadins and party deamidated and esterified omega-gliadins has been studied by Fourier transform IR spectroscopy. The secondary structure of the fully hydrated proteins was a mixture of beta-turns and extended chains, with a small amount of intermolecular beta-sheets. The absorption of the glut…

Food composition and propertiesProteins in Food SystemsEnzyme Structure and Function

Characterization of Sr‐Doped LaMnO3 and LaCoO3 as Cathode Materials for a Doped LaGaO3 Ceramic Fuel Cell

Kevin Huang、Man Feng、John B. Goodenough 等 4 位作者1996-11-01Journal of The Electrochemical Society

Energy dispersive spectrometry line scan and ac impedance spectroscopy were used in this study to investigate the chemical reactions between two cathode materials, La 0.84 Sr 0.16 MnO 3 (LSM), La 0.5 Sr 0.5 CoO 3 − δ (LSC), and the electrolyte La 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 2.85 (LSGM). Significant interdiffusions of C…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsMagnetic and transport properties of perovskites and related materials

Anneal-tunable Curie temperature and transport of La0.67Ca0.33MnO3

D. C. Worledge、G. Jeffrey Snyder、M. R. Beasley 等 6 位作者1996-11-01Journal of Applied Physics

Resistivity measurements on a La0.67Ca0.33MnO3 film are reported for a series of argon anneals at successively higher temperatures. Tc, the ferromagnetic ordering temperature, increases uniformly with increasing annealing temperature and annealing time. Hence, Tc can be tuned by appropriate annealing. In order to full…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Large-area achromatic interferometric lithography for 100 nm period gratings and grids

T. A. Savas、Mark L. Schattenburg、J. M. Carter 等 4 位作者1996-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Achromatic interferometric lithography is the preferred approach for producing large-area, spatially coherent 100 nm period gratings and grids. We report on improvements to processes which have enabled exposure areas of ≊10 cm2. In addition, we report on the fabrication of 100 nm period free-standing gold gratings.

Photonic and Optical DevicesAdvanced Measurement and Metrology TechniquesOptical Coatings and Gratings

Photoswitched and Functionalized Oligothiophenes: Synthesis and Photochemical and Electrochemical Properties

Gerasimos M. Tsivgoulis、Jean‐Maríe Lehn1996-11-01Chemistry - A European Journal

Abstract The extended dithienylethene compounds 1–3 have been synthesized. They undergo photochromic and electrochemical changes by photoinduced interconversion between open and closed forms of type A and B . In addition, both forms of the N ‐methylated derivatives 1b and 2b have absorption bands in which excitation r…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Director structure around a colloid particle suspended in a nematic liquid crystal

O. V. Kuksenok、R. W. Ruhwandl、Sergij V. Shiyanovskii 等 4 位作者1996-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We analyze the director field around a spherical colloid particle with radial (homeotropic) anchoring on its surface. Depending on the relative strength of anchoring W, controlled by the parameter WR/K with K the Frank constant and R the particle radius, the director distribution may possess a singular ring of a -1/2…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation