Materials Literature
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The production of hydrocarbons through the pyrolysis of polyolefins is a promising way of fuel recycling. In this work, online single-photon ionization time-of-flight mass spectrometry (SPI–TOFMS) was used to study both thermal and catalytic decompositions of polypropylene (PP) in a tubular furnace. SPI produces few o…
Abstract An efficient palladium catalyst supported on fibrous silica nanospheres (KCC‐1) has been developed for the hydrogenation of alkenes and α,β‐unsaturated carbonyl compounds, providing excellent yields of the corresponding products with remarkable chemoselectivity. Comparison (high‐resolution TEM, chemisorption)…
In this work, a novel, porous structured NiSi2/Si composite material with a core-shell morphology was successfully prepared using a facile ball-milling method. Furthermore, the chemical vapor deposition (CVD) method is deployed to coat the NiSi2/Si phase with a thin carbon layer to further enhance the surface electron…
We describe the fabrication of crystalline electrically conducting antimony-doped tin oxide (ATO) nanoparticles highly dispersible in polar solvents such as water and ethanol without any stabilizing agents. Nonagglomerated monodisperse ATO nanoparticles with different doping levels are obtained by a facile solvotherma…
Commercial markets desire integrated multifrequency band-select duplexer and diplexer filters with a wide fractional bandwidth and steep roll-off to satisfy the ever-increasing demand for spectrum. In this paper, we discuss the fabrication and design of lithium niobate (LN) thin-film S0Lamb-wave resonators on a piezoe…
The feasibility of indirect application of low frequency ultrasound for demulsification of crude oil was investigated without using chemical demulsifiers. Experiments were performed in an ultrasonic bath with frequency of 35 kHz. Synthetic emulsions with water content of 12%, 35% and 50% and median of droplet size dis…
The temperature dependence of electrical conductivity of the Cu2ZnSnS4 (CZTS) thin films has been measured in order to identify the dominant conduction mechanism. These CZTS film have been deposited by ultrasonic assisted chemical vapor deposition method at different substrate temperatures in a single step process. Al…
Abstract TiO2 hybrid nanocomposites are promising electrode materials for lithium‐ion batteries because of the large specific capacity, excellent rate capability, and high cycling stability. We have developed an effective facile incipient wetness impregnation method that can be used to fabricate novel mesoporous MoS2–…
It is highly desirable to precisely tune the molecule release rate from the surfaces of nanoparticles (NPs) that are relevant to cancer therapy and single-cell biology. An innovative mechanism is reported to actively tune the biochemical release rate by rotation of NPs. Plasmonic nanomotors were assembled from NPs and…
Abstract Nitrogen‐doped carbon‐based catalysts are promising candidates to substitute expensive and moderately durable platinum‐based catalysts for polymer electrolyte membrane fuel cells (PEMFCs). Condensation of ionic liquids (ILs) in salt melts enables the formation of hierarchically porous nitrogen‐doped carbons w…
The urgent need for nanoporous metal oxides with highly crystallized frameworks is motivating scientists to try to discover new preparation methods, because of their wide use in practical applications. Recent work has demonstrated that two-dimensional (2D) cyanide-bridged coordination polymers (CPs) are promising mate…
Abstract This paper presents a detailed spectroscopic investigation of luminescence properties of 4,4′-bis(N-carbazolyl)-1,1′-biphenyl (CBP) and N,N,N′,N′-tetraphenylbenzidine (TAD) in solutions and neat films. These compounds are compared to their derivatives CDBP and TDAD that contain methyl groups in the 2 and 2′ p…
A pH-responsive nanohybrid (LDH-ZnPcPS4 ), in which a highly hydrophilic zinc(II) phthalocyanine tetra-α-substituted with 4-sulfonatophenoxy groups (ZnPcPS4 ) is incorporated with a cationic layered double hydroxide (LDH) based on electrostatic interaction, has been specially designed and prepared through a facile co-…
Graphene oxide/polydopamine-coated Si nanocomposite (GO/PDA-Si) was synthesized by a novel facile solution-based chemical method at room temperature. The nanocomposite with a PDA coating layer of ∼1.5 nm exhibits a high reversible specific capacity and excellent cycling stability (1074 mAh g –1 after 300 cycles at 210…
We demonstrate the existence of multiple electromagnetically induced transparencies (EIT)-like spectral responses in graphene metamaterials consisting of a series of self-assembled graphene Fabry-Pérot (FP) cavities. By exploiting the graphene plasmon resonances and phase-coupling effects, the transfer matrix model is…
Thermally activated delayed-fluorescence (TADF) emitters have attracted increasing attention as third-generation electroluminescent materials for organic light-emitting diodes. This study presents a design strategy for highly efficient TADF emitters, guided by quantum-chemistry calculations of radiative and nonradiati…
Condition monitoring and diagnosis have become an essential part of power transformer asset management. A variety of online and offline measurements have been performed in utilities for evaluating different aspects of transformers' conditions. However, properly processing measurement data and explicitly correlating th…
The influence of capping agents on the oxidation of silver nanoparticles was studied by using the electrochemical techniques of anodic stripping voltammetry and anodic particle coulometry ("nano-impacts"). Five spherical silver nanoparticles each with a different capping agent (branched polyethylenimine (BPEI), citrat…
Oligomeric protein nanopores with rigid structures have been engineered for the purpose of sensing a wide range of analytes including small molecules and biological species such as proteins and DNA. We chose a monomeric β-barrel porin, OmpG, as the platform from which to derive the nanopore sensor. OmpG is decorated w…
To improve the electrochemical performance of cobalt oxide owing to its inherent poor electrical conductivity and large volume expansion/contraction, Co3O4-carbon nanosheet hybrid nanoarchitectures were synthesized by a facile and scalable chemical process. However, it is still a challenge to control the size of Co3O4…