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TOPAZ-II Thermionic Fuel Element Testing

Scott Wold、Oleg Izhvanov、Valeri I. Vibivanets 等 6 位作者1994-01-01AIP conference proceedings

The single‐cell thermionic fuel element (TFE) is the main element of the TOPAZ‐II power system. The single‐cell TFE has a number of design advantages over the multi‐cell construction which enables and simplifies the performance of verification, acceptance, and qualification tests. This paper will discuss the design fe…

Nuclear reactor physics and engineeringHydrogen Storage and MaterialsNuclear Materials and Properties

Irradiation assisted stress corrosion cracking of HTH Alloy X-750 and Alloy 625

W. J. Mills、M.R. Lebo、R. Bajaj 等 6 位作者1994-01-01University of North Texas Digital Library (University of North Texas)

In-reactor testing of bolt-loaded precracked compact tension specimens was performed in 360{degree}C water to determine effect of irradiation on the SCC behavior of HTH Alloy X-750 and direct aged Alloy 625. Out-of-flux and autoclave control specimens provided baseline data. Primary test variables were stress intensit…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Organic Ferromagnets

Dante Gatteschi1994-01-01Europhysics news

The impact of molecular chemistry on understanding the new physics found in magnetic materials based on organic molecules is starting to be appreciated.

Magnetism in coordination complexes

Therapeutic Effect of Reticuloendothelial System(RES)-Avoiding Liposomes Containing a Phospholipid Analogue of 5-Fluorouracil, Dipalmitoylphosphatidylfluorouridine, in Meth A Sarcoma-Bearing Mice.

Kanako Doi、Naoto Oku、T. Toyota 等 7 位作者1994-01-01Biological and Pharmaceutical Bulletin

Reticuloendothelial system (RES)-avoiding liposomes are known to accumulate in tumor tissues due to passive targeting. Dipalmitoylphosphatidylfluorouridine (DPPF), a potent antitumor agent readily incorporated into the lipid bilayer, was embedded in RES-avoiding liposomes modified with a uronic acid derivative, palmit…

Nanoparticle-Based Drug DeliveryCancer, Lipids, and MetabolismCancer Research and Treatments

Evolution of Microstructure in Zirconium Alloy Core Components of Nuclear Reactors during Service

M. Griffiths、PCK Chow、CE Coleman 等 6 位作者1994-01-01OpenAlex

X-ray diffraction (XRD) and analytical electron microscopy (AEM) have been used to characterise microstructural and microchemical changes produced by neutron irradiation of Zr-2.5Nb, Zircaloy-2 and Zircaloy-4 nuclear reactor core components. In many cases there is a clear relationship between the radiation damage micr…

Fusion materials and technologiesNuclear Materials and PropertiesNuclear and radioactivity studies

Ab initio study of the molecular structure, polarizability and first hyperpolarizability of 6-hydroxy-1-formylfulvene

Salvatore Millefiori、Andrea Alparone1994-01-01Journal of the Chemical Society Faraday Transactions

Ab initio calculations have been carried out on 6-hydroxy-1-formylfulvene(HFF) to study (a) the ground-state molecular structure and relative stability of conformers, (b) the strength and main features of the intramolecular hydrogen bond, including harmonic vibrational frequencies and proton tunnelling, (c) hydrogen-b…

Advanced Chemical Physics StudiesNonlinear Optical Materials ResearchMolecular Spectroscopy and Structure

Critical epitaxial layers of different kinds of polyethylene on highly oriented isotactic poly(propylene) substrates

Shouke Yan、Jian Lin、Decai Yang 等 4 位作者1994-01-01Macromolecular Chemistry and Physics

Abstract Epitaxial crystallization of high‐density polyethylene (HDPE), linear low‐density polyethylene (LLDPE) and low‐density polyethylene (LDPE) in the epitaxial system with highly oriented isotactic poly(propylene) (iPP) has been investigated by electron microscopy. The results obtained by bright field electron mi…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

Miniature thermoelectric coolers for semiconductor lasers

V. Semenyuk、Tatyana V. Pilipenko、Grant C. Albright 等 5 位作者1994-01-01AIP conference proceedings

The problem of matching thermoelectric coolers and semiconductor lasers with respect to heat flow densities and electrical currents is discussed. It is shown that the solution of this problem is accomplished by the reduction of thermoelement dimensions to the submillimeter level. Assembled with extruded thermoelectric…

Semiconductor Quantum Structures and DevicesAdvanced Thermoelectric Materials and DevicesOptical properties and cooling technologies in crystalline materials

Structural Studies on Alkaline Earth Vanadate Glasses (Part 1)

Satoshi Hayakawa、Toshinobu Yoko、Sumio Sakka1994-01-01Journal of the Ceramic Society of Japan

The structure of alkaline earth vanadate glasses of the compositions, xMO⋅(100-x)V2O5 (M=Mg, Ca, Sr, Ba, x=30, 40, 45, 50, 55), has been investigated by means of IR spectroscopy with reference to various crystalline alkaline earth vanadates structurally known. It is found that the structure of alkaline earth vanadate…

Glass properties and applicationsCatalysis and Oxidation ReactionsMaterial Science and Thermodynamics

Failure waves in uniaxial compression of an aluminosilicate glass

G. F. Raiser、R. J. Clifton1994-01-01AIP conference proceedings

Recent plate impact experiments on glass specimens have apparently resulted in the generation of failure waves under uniaxial compression. Herein similar experiments are reported and interpreted for an aluminosilicate glass as a means for examining possible explanations of the observed behavior. This investigation bea…

Glass properties and applicationsBuilding materials and conservationHigh-Velocity Impact and Material Behavior

5, 10, 15, 20‐Tetra‐tert‐butylporphyrin und seine bemerkenswerte Reaktivität in 5, 15‐Stellung

Tadashi Ema、Mathias O. Senge、Nora Y. Nelson 等 5 位作者1994-01-01Angewandte Chemie

Wegen des Raumbedarfs der tert ‐Butylgruppen weicht die Reaktivität des neuartigen Porphyrins 1 mit nichtplanarem makrocyclischem Grundgerüst von der aller bekannten Porphyrine ab. So führt längere Behandlung von 1 mit HClO 4 /MeOH zur Bildung des 5,15‐Dihydroporphyrins (“Porphodimethens”) 2 . magnified image

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Dithiolenes revisited: an electron spin resonance study of some five-co-ordinate cobalt complexes and the crystal structures of [Co{S2C2(CF3)2}2{P(OPh)3] and [Co{S2C2(CF3)}2(PPh3)]

Gene B. Carpenter、Gregory S. Clark、Anne L. Rieger 等 5 位作者1994-01-01Journal of the Chemical Society Dalton Transactions

Isotropic and frozen-solution ESR spectra in CH2Cl2–ClCH2CH2Cl have been recorded for the five-co-ordinate, formally cobalt(IV) complexes [Co(S2C2R2)2L][R = CN, L = PEt3; R = CF3or Ph, L = PPh3or P(OPh)3; R = C6H4Me-4, L = PPh3or PEt3; R = C6H4OMe-4, L = PPh3]. The spectra can be described by approximately axial g and…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchOrganometallic Compounds Synthesis and Characterization

[(C6H5)4P][Cu3I4] – die erste Verbindung mit einer Tetraederhelix als Bauelement

H. Hartl、Farbod Mahdjour‐Hassan‐Abadi1994-01-01Angewandte Chemie

Flächenverknüpfte Tetraeder , die in Form einer Helix angeordnet sind (Idealform unten dargestellt), kennzeichnen die Struktur des Iodocuprats 1 , das aus Ph 4 Pi, I 2 und Cu erhalten wurde. Von den bei Raumtemperatur identifizierten fünf Cu‐Lagen sind bei tiefer Temperatur nur noch drei (langsames Abkühlen) oder vier…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesInorganic Fluorides and Related Compounds

Exchange interaction in hybrid spin systems: chloro-meso-tetraphenylporphyrinatochromium(III) derivatives ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines

Makoto Kitano、Noboru Koga、Hiizu Iwamura1994-01-01Journal of the Chemical Society Chemical Communications

The 3d electrons of chromium(III) and the unpaired electron of the nitroxide radical interact ferro- and antiferro-magnetically in chloro-meso-tetraphenylporphyrinatochromium(III) ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines to produce quintet and triplet ground states, respectively.

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryElectron Spin Resonance Studies

Ru–Cu/SiO 2 catalysts: characterization by FTIR spectroscopy

C. Crisafulli、R. Maggiore、Salvatore Sciré 等 4 位作者1994-01-01Journal of the Chemical Society Faraday Transactions

Silica supported Ru–Cu bimetallic catalysts have been studied by FTIR Spectroscopy. Experiments have been carried out on two series of samples prepared from RuCl3 and Ru(NO)(NO3)3. The systems studied contained a total amount of metal of ca. 2 wt.%. On the monometallic Ru/SiO2 samples, adsorption of CO led to an asyme…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Powder Metallurgical Duplex Austenitic-Ferritic Stainless Steels from Prealloyed and Mixed Powders

J. M. Ruiz‐Prieto、W. Moriera、J. M. Torralba 等 4 位作者1994-01-01Powder Metallurgy

To date little work has been done on powder metallurgical duplex austenitic-ferritic stainless steels. In the present work the manufacture of this type of steel from prealloyed and mixed powders is studied together with the possibility of obtaining duplex compositions of other than 50% ferrite-50% austenite. Mechanica…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Dielectric properties of polymer-liquid composite systems

Christian Brosseau1994-01-01Journal of Applied Physics

The dielectric properties of inhomogeneous media constituted by a glassy semicrystalline polymer (polypropylene) impregnated by an aromatic fluid (monodibenzyltoluene) are studied. The measured permittivity is compared to various forms of mixture equations. The closest agreement is obtained with the Lichteneker’s loga…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Mathematical Theories and Applications

Block/graft copolymer synthesis via ceric salt

Oya Gali̇oǧlu、Ahmet Soydan、Ahmet Akar 等 4 位作者1994-01-01Die Angewandte Makromolekulare Chemie

Abstract Acrylamide and acrylonitrile were polymerized with water‐soluble organic reducing compounds containing hydroxy groups such as methyl cellulose (MC), methyl hydroxy‐propyl cellulose (MHPC) and poly(ethylene glycol)s (PEG) in the presence of Ce(IV) in order to produce graft/block copolymers. The effect of ceriu…

biodegradable polymer synthesis and properties

Moving vector Preisach hysteresis model and δM curves

Florence Ossart、R. Davidson、S. H. Charap1994-01-01IEEE Transactions on Magnetics

The /spl delta/M curves predicted by the vector Preisach model are analyzed and proved to always be negative. A mean interaction field parallel to the magnetization is added to the model so as to reproduce the positive /spl delta/M curve of barium ferrite particulate media. By using this model in self consistent field…

Magnetic properties of thin filmsShape Memory Alloy TransformationsMagnetic Properties and Applications