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Predictive Modelling of Internal Pitting Corrosion of Aged Non-Piggable Pipelines

Chinedu I. Ossai、Brian Boswell、Ian J. Davies2015-01-01Journal of The Electrochemical Society

© 2015 The Electrochemical Society. A multivariate regression analysis and time-dependent maximum pit depth growth model was developed using maximum pit depths and pipeline operational parameters, which includes temperature, CO<inf>2</inf> partial pressure, flow rate, pH, sulfate ion, chloride ion and wate…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability Analysis

Facile construction of graphene-like Ni 3 S 2 nanosheets through the hydrothermally assisted sulfurization of nickel foam and their application as self-supported electrodes for supercapacitors

Ming Zhuo、Ping Zhang、Yuejiao Chen 等 4 位作者2015-01-01RSC Advances

A facile and low-cost approach has been developed for the fabrication of large-area nickel sulfide nanosheets <italic>via</italic> the hydrothermally assisted sulfurization of Ni foam.

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Light induced modulation of charge transport phenomena across the bistability region in [Fe(Htrz) 2 (trz)](BF 4 ) spin crossover micro-rods

Constantin Lefter、Reasmey P. Tan、Julien Dugay 等 9 位作者2015-01-01Physical Chemistry Chemical Physics

We studied the effect of light irradiation on the electrical conductance of micro-rods of the spin crossover [Fe(Htrz)2(trz)](BF4) network, organized between interdigitated gold electrodes. By irradiating the sample with different wavelengths (between 295 and 655 nm) either in air or under a nitrogen atmosphere we obs…

Magnetism in coordination complexesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Growth Behavior of Initial Product Layer Formed on Mg Alloy Surface Induced by Polyaniline

Yizhong Luo、Xianhong Wang、Wei Guo 等 4 位作者2015-01-01Journal of The Electrochemical Society

The quality of the interfacial protective layer induced by polyaniline (PANI) has been claimed to play a crucial role for the enhanced corrosion protection of Mg alloy, but its growth behavior is not well understood. Here some composition, structure and growth kinetics of the protective layer formed at the PANI-emeral…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Validation of a dendron concept to tune colloidal stability, MRI relaxivity and bioelimination of functional nanoparticles

Adam D. Walter、Antonio Garofalo、Audrey Parat 等 14 位作者2015-01-01Journal of Materials Chemistry B

The functionalization of spherical superparamagnetic iron oxide nanoparticles (SPION) of 10 nm with a linear monophosphonate (L1) and also PEGylated mono-phosphonated dendrons of growing generation (D2-G1, -G2 and -G3) yielded dendritic nano-objects of 15 to 30 nm in size, stable in physiological media and showing bot…

Gold and Silver Nanoparticles Synthesis and ApplicationsDendrimers and Hyperbranched PolymersPhotoacoustic and Ultrasonic Imaging

Light driven growth of silver nanoplatelets on 2D MoS 2 nanosheet templates

Torben Daeneke、Benjamin J. Carey、Adam F. Chrimes 等 8 位作者2015-01-01Journal of Materials Chemistry C

This work investigates a novel synthesis strategy for the functionalisation of 2D MoS <sub>2</sub> nanosheets with silver. Direct excitation of the MoS <sub>2</sub> bandgap was found to lead to the photodeposition and eventual planar growth of metallic silver on the 2D MoS <sub>2</sub> nanosheet templates.

Advanced Photocatalysis TechniquesGraphene research and applications2D Materials and Applications

Prussian blue analogues as heterogeneous catalysts for epoxidation of styrene

Yanling Liang、Chao-Yong Yi、Simon Tricard 等 6 位作者2015-01-01RSC Advances

Prussian blue analogues are high performance catalyst for low toxicity, lower dosage reactions, simple preparation processes and cheap.

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsInorganic Chemistry and Materials

Biodegradable PLGA nanoparticles loaded with hydrophobic drugs: confocal Raman microspectroscopic characterization

Hu Yan、Yifan Hou、Pengfei Niu 等 9 位作者2015-01-01Journal of Materials Chemistry B

Poly(lactic-co-glycolic acid) (PLGA) nanoparticles with bicyclol (5%) and 3-n-butyl-6-bromophthalid (Br-NBP) (3%) were prepared by an emulsification-solvent evaporation technique. The PLGA nanoparticles were, for the first time, successfully characterized by a laser trapping/confocal Raman spectroscopic technique usin…

Nanoparticle-Based Drug DeliveryOrbital Angular Momentum in OpticsElectrohydrodynamics and Fluid Dynamics

Magneto-fluorescent nanoparticles with high-intensity NIR emission, T 1 - and T 2 -weighted MR for multimodal specific tumor imaging

Guannan Wang、Xuanjun Zhang、Yaxu Liu 等 6 位作者2015-01-01Journal of Materials Chemistry B

Fe <sub>3</sub> O <sub>4</sub> @NIR semiconducting polymer nanoparticles were used for both <italic>T</italic> <sub>1</sub> -, <italic>T</italic> <sub>2</sub> -weighted MRI and fluorescence imaging of targeted tumors.

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

Impact of linker in polypyrrole/quinone conducting redox polymers

Christoffer Karlsson、Hao Huang、Maria Strømme 等 5 位作者2015-01-01RSC Advances

Introducing a linker unit in polypyrrole/quinone conducting redox polymers dramatically reduces the interaction between the two redox systems. Moreover, increasing its length and flexibility completely eliminates the interaction.

Advanced Battery Materials and TechnologiesConducting polymers and applicationsAdvanced battery technologies research

Aerobic oxidation of α-pinene catalyzed by carbon nanotubes

Yonghai Cao、Yuhang Li、Hao Yu 等 5 位作者2015-01-01Catalysis Science & Technology

Carbon nanotubes (CNTs) and nitrogen-doped CNTs (NCNTs) as metal-free catalysts exhibited an excellent activity in the selective oxidation of α-pinene with molecular oxygen as the terminal oxidant.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisOxidative Organic Chemistry Reactions

Electronic structure and photocatalytic activity of wurtzite Cu–Ga–S nanocrystals and their Zn substitution

Tarek A. Kandiel、Dalaver H. Anjum、Philippe Sautet 等 5 位作者2015-01-01Journal of Materials Chemistry A

Stoichiometric and gallium-rich wurtzite Cu–Ga–S ternary nanocrystals with and without Zn substitution were synthesized and their electronic structure and photocatalytic activities were investigated.

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Structural phase transition in TlGaSe2 under high pressure

S. H. Jabarov、T. G. Mammadov、А. И. Маммадов 等 6 位作者2015-01-01Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques

The crystal structure of the layered semiconductor TlGaSe 2 is studied using neutron diffraction at room temperature and under high pressures up to 4.6 GPa. Under ambient conditions the crystal structure of TlGaSe 2 is described by monoclinic symmetry with the space group C 2/ c . In the pressure range P = 0.2–0.9 GPa…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

A Ag-molecularly imprinted polymer composite for efficient surface-enhanced Raman scattering activities under a low-energy laser

Shaona Chen、Xin Li、Yan Guo 等 4 位作者2015-01-01The Analyst

In this work, we have fabricated flower-shaped Ag particles coated with a molecularly imprinted polymer (Ag@MIP) based on the molecular imprinting technique and SERS technology. Although Raman signals decrease with the reducing laser power, Ag@MIP could sensitively detect the target molecules even at a laser power as…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials StudiesLaser-induced spectroscopy and plasma

Synthetic peptides caged on histidine residues with a bisbipyridyl ruthenium( ii ) complex that can be photolyzed by visible light

Jesús Mosquera、Mateo I. Sánchez、José L. Mascareñas 等 4 位作者2015-01-01Chemical Communications

We report a light-sensitive histidine building block for Fmoc/tBu solid-phase peptide synthesis in which the imidazole side chain is coordinated to a ruthenium complex. We have applied this building block for the synthesis of caged-histidine peptides that can be readily deprotected by irradiation with visible light, a…

Chemical Synthesis and AnalysisClick Chemistry and ApplicationsPhotochromic and Fluorescence Chemistry

Fractional Debye–Stokes–Einstein behaviour in an ultraviscous nanocolloid: glycerol and silver nanoparticles

Szymon Starzonek、Sylwester J. Rzoska、Aleksandra Drozd-Rzoska 等 7 位作者2015-01-01Soft Matter

One of the major features of glass forming ultraviscous liquids is the decoupling between translational and orientational dynamics. This paper presents studies of this phenomenon in glycerol, an accepted molecular glass former, concentrating on the impact of two exogenic factors: high pressures (P) up to the extreme 1…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Au@Cu 7 S 4 yolk–shell nanoparticles as a 980 nm laser-driven photothermal agent with a heat conversion efficiency of 63%

Jing Zhang、Guigao Liu、Fang He 等 5 位作者2015-01-01RSC Advances

Au@Cu <sub>7</sub> S <sub>4</sub> yolk–shell nanoparticles have been prepared <italic>via</italic> an inward replacement strategy and they exhibit powerful photothermal properties with a heat conversion efficiency up to 63% under 980 nm laser irradiation.

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films