Materials Literature
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The spreading of polymer droplets is studied using molecular dynamics simulations. To study the dynamics of both the precursor foot and the bulk droplet, large hemispherical drops of 200 000 monomers are simulated using a bead-spring model for polymers of chain length 10, 20, and 40 monomers per chain. We compare spre…
By using the in situ thermal analysis-mass spectroscopic technique, combined with transmission electron microscopic characterization of the carbon nanotube (CNT) product, we have studied the chemical vapor deposition (CVD) growth of CNTs with Fe-Co/gamma-Al2O3 catalyst and benzene precursor in the range of room temper…
We report high q-resolution neutron scattering data on $\mathrm{PMN}\ensuremath{-}x\mathrm{PT}$ single crystals with $x=20%$ and $27%.$ No rhombohedral distortion occurs in the 20PT sample for temperatures as low as 50 K. On the other hand, the 27PT sample transforms into a rhombohedral phase below ${T}_{C}\ensuremath…
PEGylated gold nanoparticles with biotin moieties installed at the distal end of the PEG tethered chains were prepared by the autoreduction of HAuCl4 catalyzed by alpha-biotinyl-PEG-block-poly[2-(N,N-dimethylamino)ethyl methacrylate] (biotinyl-PEG/PAMA) in aqueous medium at room temperature. The size of the gold nanop…
Nanoscale uniform films containing gold nanoparticle and polyelectrolyte multilayer structures were fabricated by the using spin-assembly or spin-assisted layer-by-layer (SA-LbL) deposition technique. These SA-LbL films with a general formula [Au/(PAH-PSS)nPAH]m possessed a well-organized microstructure with uniform s…
We predict the stability and electronic structure of aluminum nitride nanotubes based on calculations using density functional theory. The lower strain energy required in order to wrap up an AlN graphitic sheet into a tube and good thermal stability indicate the possibility for the formation of AlN nanotubes. All the…
We use density-functional theoretical methods to examine the recent prediction, based on a mean-field solution of the Zener model, that diamond doped by Mn (with spin $S=5/2)$ would be a dilute magnetic semiconductor that remains ferromagnetic well above room temperature. Our findings suggest this to be unlikely, for…
We show that carbon nanotube Schottky-barrier transistors exhibit scaling that is qualitatively different than conventional transistors. The performance depends in an unexpected way on both the thickness and the dielectric constant of the gate oxide. Experimental measurements and theoretical calculations for ambipolar…
Variations in the structure of gamma-alumina (γ-Al 2 O 3 ), derived from well-crystalline boehmite, calcined at various temperatures in air were investigated. Consistent distribution of cation coordination, ∼69% octahedral and ∼31% tetrahedral, was observed for material calcined between 500 and 900 °C. Gamma alumina w…
A continual model of non-singular screw dislocation lying along a straight infinitely long circular cylinder is investigated in the framework of translational gauge approach with the Hilbert--Einstein gauge Lagrangian. The stress--strain constitutive law implies the elastic energy of isotropic continuum which includes…
We comment on a recent theory of dynamic wetting, that is based directly upon a model for interface formation, introduced by Shikhmurzaev. We argue that the treatment of surface tension and its relaxation, inherent in the original model, is physically flawed.
Inorganic-organic hybrid mesoporous materials were prepared by cocrystallization of a "sandwich" type polyoxometalate, [ZnWZn2(H2O)2(ZnW9O34)2]12-, and branched tripodal organic polyammonium salts, tris[2-(trimethylammonium)ethyl]-1,3,5-benzenetricarboxylate or 1,3,5-tris[4-(N,N,N-trimethylammoniumethylcarboxyl)phenyl…
In this paper, we bring forward an effective strategy, solvothermal postsynthesis, to prepare ordered mesoporous silica materials with highly branched channels. Structural characterizations indicate that the titled mesoporous materials basically have the cubic double gyroidal (space group Ia-3d) structure with small f…
Abstract Creep resistant magnesium alloys are candidate materials for automotive powertrain applications. Since the 90's, a number of new creep‐resistant magnesium alloy systems have been investigated and developed. These are for the most part based on rare‐earth, alkaline earth, and silicon additions. This paper give…
Quantum dots having four different surface coatings were tested for use in in vivo imaging. Localization was successfully monitored by fluorescence imaging of living animals, by necropsy, by frozen tissue sections for optical microscopy, and by electron microscopy, on scales ranging from centimeters to nanometers, usi…
Uniform polyaniline nanofibers readily form using interfacial polymerization without the need for templates or functional dopants. The average diameter of the nanofibers can be tuned from 30 nm using hydrochloric acid to 120 nm using perchloric acid as observed via both scanning and transmission electron microscopy. W…
Abstract The purpose of this paper is to provide a succinct but nevertheless complete mechanistic overview of the various types of magnesium corrosion. The understanding of the corrosion processes of magnesium alloys builds upon our understanding of the corrosion of pure magnesium. This provides an understanding of th…
: In this paper, the optical performance degradation of a liquid crystal (LC) cell due to the instability of pre-tilt angle and polar anchoring strength of the alignment surface of liquid crystal devices is explored. Under accelerated thermal treatment, changes in both the pre-tilt angle and polar anchoring strength a…
This paper presents the results of investigations of the dielectric and spectral properties of NH2(CH3)2Al(SO4)2 × 6 H2O crystals doped with chromium. In particular, it is shown that the dopant noticeably changes the temperature of ferroelectric phase transition and corresponding thermal dipole relaxation with a criti…
The optical convergent-beam technique is used to measure, in 0.3 ms steps, the response of the director in a 4.6-μm-thick ZLI-2293 filled hybrid aligned nematic cell when a 10 kHz, 7 Vrms ac voltage is applied to the cell. The total time taken for the reorientation process is 2.4 ms, with backflow observed during the…