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Protein Stabilization by Naturally Occurring Osmolytes

D. Wayne Bolen2003-11-14Humana Press eBooks

Natural selection is believed to be an unforgiving and relentless force in the evolution of life on earth. An organism that cannot adapt to a changing environment or an environment hostile to cell functions is at risk as a species. So it is important to understand the mechanisms used by plants, animals, and microorgan…

Enzyme Structure and FunctionHemoglobin structure and functionAldose Reductase and Taurine

Quaternary Self-Organization of Porphyrin and Fullerene Units by Clusterization with Gold Nanoparticles on SnO2 Electrodes for Organic Solar Cells

Taku Hasobe、Hiroshi Imahori、Prashant V. Kamat 等 4 位作者2003-11-14Journal of the American Chemical Society

Novel organic solar cells prepared using quaternary self-organization of porphyrin (donor) and fullerene (acceptor) dye units by clusterization with gold nanoparticles on SnO2 electrodes exhibit the remarkable enhancement of the photoelectrochemical properties relative to the reference systems.

Porphyrin and Phthalocyanine ChemistryQuantum Dots Synthesis And PropertiesFullerene Chemistry and Applications

Paramagnetic anisotropic magnetoresistance in thin films of SrRuO3

Isaschar Genish、Yevgeny Kats、Lior Klein 等 5 位作者2003-11-14arXiv

SrRuO3 is an itinerant ferromagnet and in its thin film form when grown on miscut SrTiO3 it has Tc of ~ 150 K and strong uniaxial anisotropy. We measured both the Hall effect and the magnetoresistance (MR) of the films as a function of the angle between the applied field and the normal to the films at temperatures abo…

Strongly Correlated ElectronsMaterials Science

Large anisotropy in the paramagnetic susceptibility of SrRuO3 films

Yevgeny Kats、Isaschar Genish、Lior Klein 等 5 位作者2003-11-14arXiv

By using the extraordinary Hall effect in SrRuO3 films we performed sensitive measurements of the paramagnetic susceptibility in this itinerant ferromagnet, from Tc (~ 150 K) to 300 K. These measurements, combined with measurements of magnetoresistance, reveal that the susceptibility, which is almost isotropic at 300…

Strongly Correlated ElectronsMaterials Science

Spin dynamics in exchange-biased F/AF bilayers

D. Spenato、J. Ben Youssef、H. Le Gall2003-11-14arXiv

The spin dynamics of the ferromagnetic pinned layer of ferro-antiferromagnetic coupled NiFe/MnNi bilayers is investigated in a broad frequency range (30 MHz-6 GHz). A phenomenological model based on the Landau-Lifshitz equation for the complex permeability of the F/AF bilayer is proposed. The experimental results are…

Materials Science

Dynamic roughening and fluctuations of dipolar chains

Renaud Toussaint、Geir Helgesen、Eirik G. Flekkøy2003-11-14arXiv

Nonmagnetic particles in a carrier ferrofluid acquire an effective dipolar moment when placed in an external magnetic field. This fact leads them to form chains that will roughen due to Brownian motion when the magnetic field is decreased. We study this process through experiments, theory and simulations, three method…

cond-mat.stat-mechSoft Condensed MatterMaterials Science

Asymmetric magnetization reversal in exchange biased polycrystalline F/AF bilayers

D. Spenato、S. P. Pogossian、H. Le Gall2003-11-14arXiv

This paper describes a model for magnetization reversal in polycrystalline Ferromagnetic/Antiferromagnetic exchange biased bilayers. We assume that the exchange energy can be expanded into cosine power series. We show that it is possible to fit experimental asymmetric shape of hysteresis loops in exchange biased bilay…

Materials Science

Interaction model for magnetic holes in a ferrofluid layer

Renaud Toussaint、Jørgen Akselvoll、Eirik G. Flekkøy 等 5 位作者2003-11-14arXiv

Nonmagnetic spheres confined in a ferrofluid layer (magnetic holes) present dipolar interactions when an external magnetic field is exerted. The interaction potential of a microsphere pair is derived analytically, with a precise care for the boundary conditions along the glass plates confining the system. Considering…

Soft Condensed MatterMaterials Science

Principal Components of the Protein Dynamical Transition

Alexander Tournier、Jeremy C. Smith2003-11-14Physical Review Letters

Proteins exhibit a solvent-driven dynamical transition at 180-220 K, manifested by nonlinearity in the temperature dependence of the average mean-square displacement. Here, molecular dynamics simulations of hydrated myoglobin show that the onset of the transition at approximately 180 K is characterized by the appearan…

Protein Structure and DynamicsSpectroscopy and Quantum Chemical StudiesMaterial Dynamics and Properties

Automatic Coarse Graining of Polymers

Roland Faller2003-11-14arXiv

Several recently proposed semi--automatic and fully--automatic coarse--graining schemes for polymer simulations are discussed. All these techniques derive effective potentials for multi--atom units or super--atoms from atomistic simulations. These include techniques relying on single chain simulations in vacuum and se…

Soft Condensed MatterMaterials Science

Interaction of UV photons with solid and nanocrystalline silicon

Lionel Patrone、Igor Ozerov、Marc Sentis 等 4 位作者2003-11-14arXiv

The studies of interaction of the UV photons with bulk and nanocristalline silicon by time-of-flight (TOF) mass-spectrometry allowed to reveal two populations of Si ion monomers. The first rapid population ejected even at low laser fluences is attributed to Colombian repulsion between the surface charges which are ind…

Materials Science

Low-temperature nucleation in a kinetic Ising model with soft stochastic dynamics

Kyungwha Park、Per Arne Rikvold、Gloria M. Buendia 等 4 位作者2003-11-14arXiv

We study low-temperature nucleation in kinetic Ising models by analytical and simulational methods, confirming the general result for the average metastable lifetime, = A*exp(beta*Gamma) (beta = 1/kT) [E. Jordao Neves and R.H. Schonmann, Commun. Math. Phys. 137, 209 (1991)]. Contrary to common belief, we find that bot…

Materials Sciencecond-mat.stat-mech

Preparation and structural characterization of nanocrystalline poly(vinyl chloride)

Chuanxi Xiong、Tao Wang、Qihong Liu 等 6 位作者2003-11-13Journal of Applied Polymer Science

Abstract This article describes the development of novel nanocrystalline poly(vinyl chloride) (PVC) for potential applications in PVC processes and reports improvements in the mechanical properties and thermal resistance. Before the preparation of nanocrystalline PVC via jet milling, PVC was spray‐treated and heat‐tre…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesPolymer Science and PVC

Thermal property of epoxy/SiO2 hybrid material synthesized by the sol–gel process

Wei‐Hsiang Weng、Hui Chen、Song‐Po Tsai 等 4 位作者2003-11-13Journal of Applied Polymer Science

Abstract Organic–inorganic hybrid materials synthesized by the sol–gel process have been developed for several years. This synthesis method can effectively overcome the defects of conventional composite materials. In this investigation, epoxy/SiO 2 hybrid material was synthesized by a sol–gel process with a precursor…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Trinuclear to Dinuclear: A Radii Dependence Lanthanide(III) Self-Assembly Coordination Behavior of an Amide-Type Tripodal Ligand

Xiaofeng Li、Weisheng Liu、Zhijun Guo 等 4 位作者2003-11-13Inorganic Chemistry

Lanthanide nitrate complexes with the heptadentate ligand L (6-[2-(2-(diethylamino)-2-oxoethoxy)ethyl]-N,N,12-triethyl-11-oxo-3,9-dioxa-6,12-diazatetradecanamide), [Ln(2)L(NO(3))(6)] (Ln = La, Nd, Sm, Eu, Ho), have been prepared and characterized. The X-ray crystallographic studies show that, in [La(2)L(NO(3))(6)(H(2)…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesMagnetism in coordination complexes

Facile synthesis of novel optically active poly(amide‐imide)s containing N,N′‐(pyromellitoyl)‐bis‐l‐phenylalanine diacid chloride and 5,5‐disubstituted hydantoin derivatives under microwave irradiation

Khalil Faghihi、Khosrow Zamani、Azzizullah Mirsamie 等 4 位作者2003-11-13Journal of Applied Polymer Science

Abstract Pyromellitic dianhydride (1,2,4,5‐benzenetetracarboxylic acid 1,2,4,5‐dianhydide) (1) was reacted with L‐phenylalanine (2) in a mixture of acetic acid and pyridine (3 : 2) at room temperature, then was refluxed at 90–100°C and N,N ′‐(Pyromellitoyl)‐bis‐ L ‐phenylalanine diacid (3) was obtained in quantitative…

Microwave-Assisted Synthesis and ApplicationsSynthesis and properties of polymersChemical Synthesis and Reactions

Fluorescence properties of labeled proteins near silver colloid surfaces

Badri P. Maliwal、Joanna Malicka、Ignacy Gryczyński 等 5 位作者2003-11-13Biopolymers

The fluorescence properties of a monolayer of labeled avidin molecules were studied near silver island films. We first adsorbed a monolayer of biotinylated-BSA as a base that was used to capture labeled avidin molecules. For labeled avidin on silver island films, we observed an increase of the fluorescence intensity o…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Glass Network Evolution with Bi3+/Ti4+ Substitution in Phosphate Glasses Formulated with a Constant Oxygen/Phosphorus Ratio. EXAFS, XANES, and 31P Double Quantum MAS NMR

Lionel Montagne、Sylvie Daviero‐Minaud、G. Palavit 等 5 位作者2003-11-13Chemistry of Materials

This paper reports a structural study of the effect of TiO 2 substitution for Bi 2 O 3 in x Na 2 O− x P 2 O 5 − y Bi 2 O 3 − z TiO 2 glasses, which were formulated in order to keep a constant average polymerization of the phosphate network. XANES and EXAFS analyses have indicated that the bismuth coordination sphere i…

Advanced Condensed Matter PhysicsGlass properties and applicationsAdvanced NMR Techniques and Applications

Low-temperature structural phase transition in aCd6Y1/1 approximant

Ryuji Tamura、Keiichi Edagawa、C. Aoki 等 5 位作者2003-11-13Physical review. B, Condensed matter

Electron and x-ray-diffraction studies have revealed that a ${\mathrm{Cd}}_{6}\mathrm{Y}$ 1/1 crystalline approximant $(Im3\ifmmode\bar\else\textasciimacron\fi{},$ $a=1.5482\mathrm{nm})$ undergoes a phase transition at some temperature around 160 K. The transition accompanies a change of the lattice period as well as…

Quasicrystal Structures and PropertiesCrystallography and molecular interactionsX-ray Diffraction in Crystallography