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Novel crown ether substituted phthalocyanine with good gas sensing properties to NO2

Xiyou Li、Yanli Chen、Huijun Xu1999-01-01Journal of Materials Chemistry

A novel 18-crown-6 substituted phthalocyanine was synthesized. LB films of this material were prepared by a vertical dipping method and the structures of the films were characterized by absorption spectra, polarized absorption spectra and X-ray diffraction experiments. The results indicate that the films possess highl…

Gas Sensing Nanomaterials and SensorsPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Electronic structure of Nb impurities in and on TiO2

Maurizio Casarin、Chiara Maccato、Andrea Vittadini1999-01-01Physical Chemistry Chemical Physics

The electronic properties of Nb substitutional impurities in the bulk phase and at the (110) surface of TiO2 are studied by means of density functional cluster calculations. Both the neutral (Nb4+) and the singly ionized (Nb5+) impurity charge states are taken into consideration. Nb is found to introduce a shallow don…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Synthesis and Surface Functionalization under Cold-plasma Conditions.

F. Dénès、Sorin Manolache、R. A. Young1999-01-01Journal of Photopolymer Science and Technology

Controlled, plasma-mediated, surface modification of various substrates including inorganic and organic polymers is essential for the creation of miniaturized advanced materials. Many of these approaches have focused on the surface-implantation of specific chemical groups which can be employed for subsequent chemical…

Surface Modification and Superhydrophobicity

Hydrogen diffusion in Metals : A 30-Year retrospective

David J. Fisher1999-01-01Scitec Publications eBooks

By collating data published over a 30 year period, this text summarizes the progress made in the fields of diffusion and defect research. The large number of studies of iron alloys reflects the commercial importance of hydrogen embrittlement, an phenomenon which has long plagued steel fabricators. Another metal which…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Vibration analysis for periodic diagnostic testing of circuit-breakers

M. Runde1999-01-01OpenAlex

The present paper focuses on vibration analysis for periodic diagnostic testing of circuit breakers. Initially, the basic ideas and the applied procedures are briefly outlined. Then the features of this method are evaluated with basis in the prevailing failure modes according to the CIGRE surveys. Commercial test equi…

High voltage insulation and dielectric phenomenaPower System Reliability and MaintenanceThermal Analysis in Power Transmission

Effect of Particle Size on the Thermal Decomposition of .EPSILON.-Hexanitrohexaazaisowurtzitane.

Jun‐Hyung Kim、Yoo-Jin Yim1999-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

The influence of the particle size on the thermal decomposition of ε-hexanitrohexaazaisowurtzitane (HNIW) was studied by means of differential scanning calorimetry (DSC). The kinetics and mechanism for the decomposition were evaluated using integral methods. It was found that the thermal kinetic parameters such as act…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Enhancement of the anisotropy of Nd-Fe-B powders by varying the HDDR conditions

Hajime Nakamura、Kenichi Kato、David Book 等 6 位作者1999-01-01Journal of the Magnetics Society of Japan

In order to enhance the anisotropy of Nd-Fe-B HDDR treated powder, we have investigated the hydrogen pressure dependence of the recombination reaction temperature, for disproportionated Nd2Fe14B powder. The recombination pressure of hydrogen was higher than the dissociation pressure of NdH2. The addition of Co and/or…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Siliceous deposits formed from geothermal water in Kyushu, Japan: II. Distribution and state of aluminum along the growth direction of the deposits.

Takushi Yokoyama、Yumi Sato、Mitsuru Nakai 等 5 位作者1999-01-01GEOCHEMICAL JOURNAL

The distribution of elements and chemical state of aluminum along the growth direction of a siliceous deposit formed from geothermal water at the Hachobaru geothermal power station were examined by chemical analysis and 27Al MAS NMR. The content of 4-coordinated Al, Al(4), was essentially constant along the growth dir…

Arsenic contamination and mitigationClay minerals and soil interactionsIron oxide chemistry and applications

Magnetic structure and covalence in tetrachlorobis(N-phenylacetamidinato)rhenium(IV) by neutron diffraction

Philip A. Reynolds、Brian N. Figgis、David Martín yMarero1999-01-01Journal of the Chemical Society Dalton Transactions

Powder neutron diffraction measurements have been made at 2 and 20 K for the complex cis-[ReCl4(NHCMeNHPh)2]. The changes in diffracted intensities on magnetic ordering at 9.7(1) K were fitted in the Shubnikov group Pc′c′n to an antiferromagnetically ordered magnetic structure in which the spins are aligned along c in…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Relating materials properties to structure : handbook and software for polymer calculations and materials properties

D. J. David、Ashok Misra1999-01-01OpenAlex

Relating Materials Properties to Structure: Handbook and Software for Polymer Calculations and Materials Properties lays the foundation for an understanding of the basic structure of materials and the significant distinguishing features between major classes. It provides a method of comparison between the structure of…

Polymer crystallization and properties

XPS investigations on the feasibility of isomorphous substitution of octahedral Al3+ for Fe3+ in Keggin ion salts

A. Oszkó、János Kiss、Imre Kiricsi1999-01-01Physical Chemistry Chemical Physics

Investigation of Keggin ion salts prepared by partial hydrolysis of Al3+ and Fe3+ ions followed by addition of sodium sulfate solution to generate the sulfate salt of the Keggin ion was carried out. Characterization of the salts was performed by classical analytical methods and FTIR and XP spectroscopy. Incorporation…

Polyoxometalates: Synthesis and ApplicationsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Long term performance verification of high voltage DC GIS

Michael Mendik、S.M. Lowder、F.E. Elliott1999-01-01OpenAlex

In order to determine feasibility of SF/sub 6/ gas insulated equipment for HVDC substation technology, a testpole was built and subjected to a long term test of 2 years. The test pole consisted of slightly modified commercially available 550 kV AC and 800 kV AC gas insulated components. The components were SF/sub 6/-a…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaThermal Analysis in Power Transmission

A structural investigation of Mg(PO3)2, Zn(PO3)2 and Pb(PO3)2 glasses using molecular dynamics simulation

Elizabeth Sourial、T. Peres、J. A. Capobianco 等 5 位作者1999-01-01Physical Chemistry Chemical Physics

An investigation into the structure of three metaphosphate glasses, Mg(PO3)2, Zn(PO3)2 and Pb(PO3)2, using molecular dynamics simulations is presented. The phosphate network was found to consist of long linear chains of PO4 tetrahedral units. This type of structure exists in the three metaphosphate glasses, indicating…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

On-site PD diagnostics of power cables using oscillating wave test system

Ε. Gulski1999-01-01OpenAlex

This paper discusses the results of partial discharge measurements in medium voltage power cables losing oscillating test voltages. In particular, the sensitivity and the reproducibility of this new method for on-site testing are discussed. Based on laboratory and on-site tests the usefulness of this PD measuring tech…

Advanced Fiber Optic SensorsHigh voltage insulation and dielectric phenomenaPower Line Communications and Noise

Detergency of used motor oil from cotton and polyester fabrics

Yong‐Seung Chi、S. Kay Obendorf1999-01-01Journal of Surfactants and Detergents

Abstract A study was conducted to identity factors contributing to the difficult removal of used motor oil from textile materials by detergency. Infrared spectroscopy and gel permeation chromatography of used motor oil showed that the oil was a saturated aliphatic hydrocarbon with molecular weight around 950. X‐ray an…

Textile materials and evaluations

Seasonal Development and Morphological Variability of Cyclotella ocellata (Bacillariophyceae) in the Eutrophic Lake Dagow (Germany)

Ines Schlegel、Wolfram Scheffler1999-01-01International Review of Hydrobiology

Abstract The development of Cyclotella ocellata P antocsek was studied systematically in the eutrophic, dimictic hardwater Lake Dagow from March to October, 1994. Cyclotella ocellata was the most important centric diatom in the lake with a maximum cell density of 6 × 10 6 cells 1 −1 . The seasonal development, charact…

Marine and coastal ecosystemsAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Behavior of an Oxide Dispersion Strengthened Ferritic Steel Irradiated in Phenix

Philippe Dubuisson、R. Schill、M. P. Hugon 等 5 位作者1999-01-01OpenAlex

This paper deals with the irradiation behavior of the oxide dispersion strengthened (ODS) ferritic alloy DT2203Y05, a 13% Cr ferritic alloy strengthened by a fine dispersion of yttrium and titanium oxides. This alloy was irradiated up to 81 dpa in Phénix as fuel pin cladding. The profilometry measurements confirm its…

Fusion materials and technologiesHigh-Temperature Coating BehaviorsNuclear Materials and Properties

Shocking rocks by cavitation and bubble implosion

J. G. Spray1999-01-01Geology

Research Article| August 01, 1999 Shocking rocks by cavitation and bubble implosion John G. Spray John G. Spray 1Impact Geology Group, Department of Geology, University of New Brunswick, Fredericton, New Brunswick E3B 5A3, Canada Search for other works by this author on: GSW Google Scholar Geology (1999) 27 (8): 695–6…

Calcium Carbonate Crystallization and InhibitionUltrasound and Cavitation PhenomenaNuclear Physics and Applications

Synthesis, polymerization and characterization of substituted dithieno[3,4-b:3′,4′-d]thiophenes

Seiji Inaoka、David M. Collard1999-01-01Journal of Materials Chemistry

Chemical or electrochemical oxidation of substituted dithieno[3,4-b:3′,4′-d]thiophenes provides polymers with defined regiochemical structures. These materials have lower bandgaps (0.7-0.9 eV) than the unsubstituted fused heteroarene. Potential cycling of the 1,3-dimethyl substituted polymer film shows repetitive p- a…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Synthesis and optical properties of water-soluble poly(p-phenylenevinylene)s

Zhonghua Peng、Bubin Xu、Jianheng Zhang 等 4 位作者1999-01-01Chemical Communications

A novel conjugated polymer containing carboxylic acid and 2-[2-(2-methoxyethoxy)ethoxy]ethoxy substituents which is soluble in both organic solvents and aqueous bases is synthesized.

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials