Materials Literature
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Deciding if a given set of Wang tiles admits a tiling of the plane is decidable if the number of Wang tiles (or the number of colors) is bounded, for a trivial reason, as there are only finitely many such tilesets. We prove however that the tiling problem remains undecidable if the difference between the number of til…
Polycrystalline samples of Al3Ti with the D022-type structure have been plastically deformed at 400°C. Observations using weak-beam transmission electron microscopy show activation of dislocations with <100] or <110] Burgers vectors. The fine structure of [100] and [010] dislocations reveals strong stabilization effec…
In recent decades, materials have been a key to increase the performance of automotive parts which leads to development of new materials. The main objective is to achieve increase in quantity and quality of automotive parts produced with optimum performance during their life cycle. Cast iron has remained a competitive…
Semiconductor organic–inorganic nanocom-posites crafted by placing conjugated polymers in intimate contact with nanocrystals markedly promote the dispersion of nanocrystals within the conjugated polymer matrix and facilitate the photoinduced charge transfer between them. On page 4353, Z. Lin and L. Zhao review recent…
Abstract This research project is focused on molecules that comprise a series of asymmetrically A 3 B‐type meso‐substituted free‐base porphyrins and their related Zn‐metalloporphyrins. A and B were taken as electron‐donor and electron–acceptor groups. Full geometry optimizations without symmetry constrains were perfor…
Silk has been considered biocompatible and used for medical applications for centuries. However, most of the silk currently used is produced by the domesticated silkworm, Bombyx mori. Recently, it has been demonstrated that silk produced by saturniidae insects such as Antheraea mylitta, Phylisomia ricini, and Antherae…
BaFe12O19/Ba0.6Sr0.4TiO3 (BaM/BST) composites were synthesized via the conventional solid-state reaction method. The phase composition and surface morphology of the composites were investigated by using X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The electrical and magnetic properties…
Molecules that exhibit emission in the solid state, especially those known as aggregation-induced emission (AIE) chromophores, have found applications in areas as varied as light-emitting diodes and biological sensors. Despite numerous studies, the mechanism of fluorescence quenching in AIE chromophores is still not c…
A calibrated soil test for phosphorus (P) fertilizer application to sugarcane (Saccharum spp.) grown on organic soils in southern Florida is an important best-management practice for minimizing P loads in water draining to the Everglades. The current calibration uses water as the soil extractant, which has the limitat…
Mechanical behavior of free-standing polymer films with submicron thicknesses exposed to a radiation environment is poorly understood. Here, we study 110-nm-thin free-standing polyvinyl formal (Formvar) films irradiated at room temperature with 1–5 keV electrons or 3 MeV alpha particles. We measure mechanical properti…
We report a method of producing superhydrophilic surfaces on titanium substrates via sandblasting and dip-coating with colloidal silica nanoparticles. The surface exhibits a high level of hydrophilic stability, as it stays superhydrophilic for an excess of 40 days and through multiple wetting–dewetting cycles. The com…
A three-dimensional (3D) poly(D,L-lactic-co-glycolic acid) porous scaffold with microgrooves and microholes on the pore walls was fabricated by using salt particulates as main porogens and sugar fibers as modifiers. Besides macropores templated from salt particulates, microgrooves and microholes were generated after l…
High density chitosan membranes were produced via a novel manufacturing process and used as implantable resorbable surgical membranes. The innovative method utilizes the following three sequential steps: (1) casting an acidic chitosan solution within a silicon mold, followed by freezing; (2) neutralizing the frozen ac…
Abstract Poly(propylene carbonate) (PPC) is inferior in thermal stability and liable to incur thermal degradation, especially in the existence of residual bimetal catalyst. In this article, PPC containing residual catalyst was end‐capped with 4, 4′‐diphenylmethane diisocyanate (MDI) through melt compounding. The blend…
Systems of complex particles such as proteins or colloidal particles have a widely observed tendency to form nonconnected nanometer-size clusters at steady state, but the underlying mechanisms remain poorly understood. We report here a numerical study on the self-aggregation of low-valence particles with flexible bond…
Fresh milk and sodium montmorillonite clay can be used to prepare foam-like materials via an environmentally sustainable freeze-drying process. The enzyme transglutaminase (Tgase) was demonstrated to be an effective cross-linker; treatment of milk with Tgase contributed to the formation of a gel network. The mechanica…
Abstract Electrically conducting composite hydrogels of poly(acrylic acid‐ co ‐acrylamide) and polyaniline were prepared by a simple two‐step synthesis process using an aqueous polymerization technique at room temperature and interfacial polymerization of aniline at a water/organic‐solvent interface. The structures of…
This article presents the results of investigations to determine how process settings and crimp geometry affect the seal strength and integrity of traditional polyolefin and biopolymer flexible packaging materials. The results show agreement with previous studies where temperature and dwell time are found to be the do…
Waterborne anti-icing coatings were prepared by embedding silicone oil microcapsules in latex paints. The long-term hydrophobicity and ice adhesion strength of the coatings were examined with a QUV accelerated weathering tester and a pull-off adhesion tester. The effects of silicone oil content and pigment/binder (PB)…
This report presents biotin-functionalized semiconducting polymers that are based on fluorene and bithiophene co-polymers (F8T2). Also presented is the application of these polymers to an organic thin film transistor used as a biosensor. The side chains of fluorene were partially biotinylated after the esterification…