Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
We investigated the importance of the specific effective surface area through a detailed study on the relationship between electrical conductivity of single-walled carbon nanohorns (SWCNHs) and accessibility of the electrolyte ions in the SWCNH-based supercapacitor. After heat treatment of the SWCNHs, the ratio of sp…
Surface acetylated nanocrystalline cellulose (NCC) was prepared from cotton fiber by a single-step method under mild conditions using anhydrous phosphoric acid as the solvent. The absorbance peak of O-H was reduced, and the absorbance peaks of C=O and CH3 appeared in the Fourier transform infrared (FTIR) spectrum of t…
We demonstrate the preparation of peptide gel microparticles that are emulsified and stabilized by SiO2 nanoparticles. The gels are composed of aromatic peptide amphiphiles 9-fluorenylmethoxycarbonyldiphenylalanine (Fmoc-FF) coassembled with Fmoc-amino acids with different functional groups (S: serine; D: aspartic aci…
A powerful variation of traditional radical thiol-yne reaction with diphenylacetylene (DPA)-based starting materials leading to the quantitative and selective formation of the corresponding vinyl sulfides is reported. A variety of different thiols are shown to undergo reaction with DPA and the influence of their struc…
The concentration profile of deuterated myoglobin (Mb) adsorbed onto polystyrene substrates displaying poly(ethylene glycol) (PEG) brushes is characterized by neutron reflectometry (NR). The method allows to directly distinguish among primary adsorption at the grafting surface, ternary adsorption within the brush, and…
The spontaneous nucleation of d -mannitol polymorphs at different initial concentrations in an aqueous solution was investigated. Two in situ process analytical technology (PAT) tools, Raman spectroscopy and focused beam reflectance measurement (FBRM), were combined to monitor the process, allowing instantaneous detec…
Amino-cellulose-based nanofibers are prepared by electrospinning of blended solutions of 6-deoxy-6-trisaminoethyl-amino (TEAE) cellulose and polyvinyl alcohol (PVA). The TEAE cellulose with a degree of substitution of 0.67 is synthesized via a nucleophilic displacement reaction starting from cellulose-p-toluenesulfoni…
The core–shell structured electrode fabricated from solution infiltration and high-temperature reactive sintering delivers promising and stable power outputs.
This paper focuses enhancement of the electrical insulation properties of commercial polycarbonate using nanostructured alumina as an additive material.Various polycarbonate composites have been prepared by varying the level of additive material and DC conductivity in presence of oxygen of the derived composite materi…
Intrinsically disordered proteins (IDPs) are often characterized in terms of the hydrodynamic radius, Rh . The Rh of IDPs are known to depend on fractional proline content and net charge, where increased numbers of proline residues and increased net charge cause larger Rh . Though sequence and charge effects on the Rh…
The selective oxidation of the α-position of two heme-Fe(III) tetraarylporphryinate complexes occurs when water(hydroxide) attacks their oxidized Cmpd I-type equivalents, high-valent Fe(IV)═O π-cation radical species ((P(+•))Fe(IV)═O). Stepwise intermediate formation occurs, as detected by UV-vis spectroscopic monitor…
The fabrication of a mesoporous silica nanoparticle (MSN)−protamine hybrid system (MSN−PRM) is reported that selectively releases drugs in the presence of specific enzyme triggers present in the proximity of cancer cells. The enzyme trigger involved is a protease called trypsin, which is overexpressed in certain speci…
While there is a persistent interest in oxides, e.g., for semiconductor technology or optoelectronics, it seems to be difficult to achieve n‐type and p‐type doping for one and the same material. At the same time, it is important to understand the electronic structure for both types of doping individually. In this work…
Site-specific electrochemical deposition is used to prepare polystyrene (PS)–Ag Janus particle arrays with superhydrophobic properties. Analyte molecules can be significantly enriched using the superhydrophobic properties of the PS–Ag Janus particle array before SERS detection, enabling the extremely sensitive detecti…
Abstract Two kinds of phosphole‐ and benzodithiophene‐based copolymers bearing P V =O or P V =NSO 2 C 8 H 17 functions were prepared by Pd–CuI‐promoted Stille coupling reactions, and their optical and electrochemical properties were investigated. Bulk heterojunction organic photovoltaic devices comprised of the new P,…
Extended linear arm chair defects are intentionally fabricated in suspended monolayer graphene using controlled focused electron beam irradiation. The atomic structure is accurately determined using aberration-corrected transmission electron microscopy with monochromation of the electron source to achieve ∼80 pm spati…
Charge distribution and ion and electron migration have been theoretically studied in the reduced CeO 2 (111) surface by means of density functional calculations including on-site localization corrections (DFT+ U ). The analysis of the charge distribution shows that nearest-neighbor and next-nearest-neighbor configura…
Electrochemical capacitors with fast charging-discharging rates are very promising for hybrid electric vehicle industries including portable electronics. Complicated pore structures have been implemented in active materials to increase energy storage capacity, which often leads to degrade dynamic response of ions. In…
Mesoporous titanium zirconium (TiZr) oxide nanospheres with variable Ti to Zr ratios were synthesized using sol-gel chemistry followed by solvothermal treatment. These oxide nanospheres exhibited similar diameters (~360 nm), high surface areas (from 237 ± 2 to 419 ± 4 m(2) g(-1)), and uniform pore diameters (~3.7 nm).…
Ligation of 2,6-diphenylbenzenethiol (DppSH) onto Au clusters stabilized by poly(N-vinyl-2-pyrrolidone) and subsequent core etching yielded a single cluster Au25(SDpp)11. High-energy X-ray diffraction measurement showed that Au25 constitutes a core in Au25(SDpp)11. We propose a bi-icosahedral Au25 core whose 22 Au sur…