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Change of Structural Behaviors of Organo-Silane Exposed Graphene Nanoflakes

C. W. Pao、S. C. Ray、H. M. Tsai 等 12 位作者2010-04-15The Journal of Physical Chemistry C

The electronic structures of graphene nanoflakes (GNFs) exposed to an organo-silane precursor [tetramethylsilane, TMS, Si(CH 3 ) 4 ] were studied using electron field emission (EFE), Raman spectroscopy, X-ray absorption near-edge structure (XANES), X-ray photoelectron spectroscopy (XPS), X-ray emission spectroscopy (X…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

dc magnetoelectric sensor based on direct coupling of Lorentz force effect in aluminum strip with transverse piezoelectric effect in 0.7Pb(Mg1/3Nb2/3)O3–0.3PbTiO3 single-crystal plate

Chung Ming Leung、Siu Wing Or、S. L. Ho2010-04-15Journal of Applied Physics

We report theoretically and experimentally a dc magnetoelectric sensor consisting of a thickness-polarized 0.7Pb(Mg1/3Nb2/3)O3–0.3PbTiO3 (PMN-PT) piezoelectric single-crystal plate arranged along the longitudinal direction and sandwiched between a pair of electrically connected aluminum strips. The operation of the se…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Synthesis of Rod‐Like High‐Purity β‐Sialon Powder by a Novel Carbothermal Reduction–Nitridation Method with a Nanocasting Procedure

Qiang Yan、Qian Liu、Qian Liu 等 5 位作者2010-04-15Journal of the American Ceramic Society

Rod‐like high‐purity β‐Sialon(Si 6− z Al z O z N 8− z , z =1,2,3) powders were synthesized from the mesoporous SiO 2 /C/Al 2 O 3 composites, that were prepared using a nanocasting procedure, through a carbothermal reduction–nitridation method at 1420°C. The XRD analysis provided considerable evidence regarding the hig…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisAerogels and thermal insulation

Temperature-dependent S-shaped photoluminescence in ZnCdO alloy

Antaryami Mohanta、Raj K. Thareja2010-04-15Journal of Applied Physics

Photoluminescence (PL) of ZnCdO alloy with medium Cd concentration (50 wt %) is studied at different temperatures and at varying excitation intensity. The PL peak position shows red-blue-red (S-shaped) shift with increase in temperature due to potential fluctuations on alloying. The line width of PL profile shows incr…

ZnO doping and propertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Interfacial microrheology as a tool to study viscoelastic transitions in nanoconfined soft matter

A. K. Kandar、Rupak Bhattacharya、J. K. Basu2010-04-15Physical Review E

We present a method to perform in situ microrheological measurements on monolayers of soft materials undergoing viscoelastic transitions under compression. Using the combination of a Langmuir trough mounted on the inverted microscope stage of a laser scanning confocal microscope we track the motion of individual fluor…

Material Dynamics and PropertiesForce Microscopy Techniques and ApplicationsRheology and Fluid Dynamics Studies

Vapour‐phase growth, purification and large‐area deposition of ZnO tetrapod nanostructures

L. Zanotti、Davide Calestani、Marco Villani 等 6 位作者2010-04-15Crystal Research and Technology

Abstract Large‐yield zinc oxide (ZnO) nanosized tetrapods have been obtained by a standard vapour‐phase growth technique to which a few modifications have been added, such as the separation of the Zn source evaporation region from the Zn oxidation region inside the reactor setup. This modification allows to keep the g…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Perfluoroisopropyl Zinc Phthalocyanines Conjugated with Deoxyribonucleosides: Synthesis, Photophysical Properties and In Vitro Photodynamic Activities

Banibrata Das、Etsuko Tokunaga、Motohiro Tanaka 等 5 位作者2010-04-15European Journal of Organic Chemistry

Abstract Perfluoroisopropyl‐substituted zinc phthalocyanines conjugated with deoxyribonucleosides have been synthesized and evaluated as photodynamic therapy agents from both spectral and biological points of view. They show non‐aggregation, high chemical stability and good fluorescence quantum yields in both organic…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Development of bubble microstructure in ErT2 films during aging

Gillian M. Bond、James F. Browning、Clark Sheldon Snow2010-04-15Journal of Applied Physics

Helium bubbles form in metal tritide films as tritium decays into H3e, influencing mechanical properties and long-term film stability. The bubble nucleation and growth mechanisms comprise an active research area, but there has been only one previous systematic experimental study of helium bubble growth in metal tritid…

Fusion materials and technologiesNuclear Materials and PropertiesSuperconducting Materials and Applications

Novel Features of Nanoscaled Particles Addition to Alumina–Magnesia Refractory Castables

M.A.L. Braulio、Guilherme G. Morbioli、L. R. M. Bittencourt 等 4 位作者2010-04-15Journal of the American Ceramic Society

Previous work by the authors indicated that the addition of nanomagnesia or colloidal alumina to alumina–magnesia (AM) refractory castables resulted in benefits in terms of reducing the overall linear expansion during heat‐up. Considering this aspect, this paper addresses the effects of colloidal alumina sources conta…

Advanced ceramic materials synthesisAdvanced materials and compositesMagnesium Oxide Properties and Applications

Effect of potassium fertilization on soil potassium pools and rice response in an intensive cropping system in China

Qichun Zhang、Wang Guang-huo、Yu‐ke Feng 等 5 位作者2010-04-15Journal of Plant Nutrition and Soil Science

Abstract In order to assess the changes in soil K pools as affected by K‐fertilizer application and the impact of the changes on K balance, grain yield, and K uptake, an experiment was conducted in Central Zhejiang Province, E China, in a continuous double‐cropping rice system. Two sites were selected: (1) the Agricul…

Soil Carbon and Nitrogen DynamicsPlant nutrient uptake and metabolismClay minerals and soil interactions

The effect of grain boundaries on the domain wall dynamics in Pr1−xAgxMnO3 manganites

Hossein Ahmadvand、Hadi Salamati、Parviz Kameli2010-04-15Journal of Applied Physics

We performed detailed ac susceptibility measurements on Pr1−xAgxMnO3 (x=0.15,0.20) manganites and observed unusual and interesting features, which are associated with the domain walls and the effects of grain-boundaries on their movements. It is shown that the ac field, frequency, temperature, thermal cycling, and gra…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsElectrical and Thermal Properties of Materials

Synthesis and Characterization of Novel Thermoplastic Films for Removal of Heavy Metal Ions

Ahmed A. Haroun、E. M. Abu Taleb、M.A. Abd El‐Ghaffar2010-04-15Polymer-Plastics Technology and Engineering

The main objective of this study is to establish the applicability of novel thermoplastic films based on extracted gelatins from bovine (Gb) and bird (Gc) bones in addition to hide powder (HP), which blended with modified polyethylene (MPE) for the removal of heavy metal ions such as copper (II), chromium (VI), nickel…

Bone Tissue Engineering MaterialsMicroplastics and Plastic PollutionCollagen: Extraction and Characterization

Effect of ultraviolet radiation on slow-relaxation processes in ferroelectric capacitance structures

Peter K. Petrov、Neil McN. Alford、A. B. Kozyrev 等 9 位作者2010-04-15Journal of Applied Physics

The effects of ultraviolet (UV) irradiation on the relaxation processes in Ba0.3Sr0.7TiO3 thin film capacitors were experimentally investigated in a range of wavelengths λ=(310–400) nm. It was observed that irradiation with a specific wavelength reduces the time of slow capacitance relaxation up to three orders of mag…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesSemiconductor materials and interfaces

Synthesis, identification and study of electrical conductivity of the doped poly aniline

Roza Al‐Aqar2010-04-15Arabian Journal of Chemistry

Poly aniline and poly aniline doped with 2,5-dimethyl benzene sulfonic acid (PXSA), 4-hydroxy-m-benzene disulfonic acid (PDSA), 3-chloro-4-hydroxybenzene sulfonic acid (OCPSA) were prepared. The polymers are identified by FT-IR and UV–vis spectroscopy. The ionic conductivities of poly aniline and poly aniline doped wi…

Fuel Cells and Related MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Calorimetric studies of crystallisation kinetics of Se75Te15−xCd10Inxmulti-component chalcogenide glasses using non-isothermal DSC

Sunil Kumar、Kedar Singh、N. Mehta2010-04-15Philosophical Magazine Letters

The crystallisation kinetics of bulk Se75Te15− x Cd10In x (x = 0, 5, 10 and 15) multi-component chalcogenide glasses have been studied using differential scanning calorimetry with different heating rates (5, 10, 15 and 20 K/min) under non-isothermal conditions. Various kinetic parameters of crystallisation, such as th…

Phase-change materials and chalcogenidesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Electron paramagnetic resonance study of size and nonstoichiometry effects on magnetic ordering in half-doped La0.5Ca0.5MnO3 manganite

M. Auslender、Alexander I. Shames、E. Rozenberg 等 6 位作者2010-04-15Journal of Applied Physics

The X-band electron paramagnetic resonance in La0.5Ca0.5MnO3 was studied. Fitting the measured temperature dependence of the EPR linewidth and intensity to established models were employed to probe the effects of finite-size and nonstoichiometry. Regarding these effects, the complex mixed magnetic ordering inherent in…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Hydrogen‐Bonding Induced Cooperative Effect on the Energy Transfer in Helical Polynorbornenes Appended with Porphyrin‐Containing Amidic Alanine Linkers

Zhichang Liu、Chih‐Hsien Chen、Hsian‐Wen Wang 等 7 位作者2010-04-15Chemistry - An Asian Journal

Polynorbornenes appended with porphyrins containing a range of different linkers are synthesized. The use of bisamidic chiral alanine linkers between the pending porphyrins and the polymeric backbone has been shown to bring the adjacent porphyrin chromophores to more suitable orientation for exciton coupling owing to…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Hydrothermal synthesis of ultralong single‐crystalline α‐Ni(OH)2 nanobelts and corresponding porous NiO nanobelts

Hui Liang、Ling Liu、Zhijie Yang 等 4 位作者2010-04-15Crystal Research and Technology

Abstract Ultralong α‐Ni(OH) 2 nanobelts with uniform size have been prepared on large scale via a facile template‐free hydrothermal method. The as‐prepared nanobelts were single crystals, with several tens of microns in length and about 100 nm in width. For the whole process, a novel nucleation–aggregation–dissolution…

Supercapacitor Materials and FabricationTransition Metal Oxide NanomaterialsLayered Double Hydroxides Synthesis and Applications

Effects of substrate temperature and Cu underlayer thickness on the formation of SmCo5(0001) epitaxial thin films

Mitsuru Ohtake、Yuri Nukaga、Fumiyoshi Kirino 等 4 位作者2010-04-15Journal of Applied Physics

SmCo 5 ( 0001 ) epitaxial thin films were prepared on Cu(111) underlayers heteroepitaxially grown on Al2O3(0001) single-crystal substrates by molecular beam epitaxy. The effects of substrate temperature and Cu underlayer thickness on the crystallographic properties of SmCo5(0001) epitaxial films were investigated. The…

Rare-earth and actinide compoundsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Lean neodymium Nd–Fe–B magnets containing minor addition of titanium

Marzena Spyra、D. Derewnicka、M. Leonowicz2010-04-15physica status solidi (a)

Abstract The effect of titanium addition on the structure and magnetic properties was studied for the nanocomposite Nd 7 Fe 79– x B 14 Ti x and Nd 8 Fe 78– x B 14 Ti x systems. The alloys were rapidly solidified by melt‐spinning with the roll speed 20 m/s. The overquenched, amorphous ribbons were subsequently crystall…

Metallic Glasses and Amorphous AlloysRare-earth and actinide compoundsMagnetic Properties of Alloys