Materials Literature
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Polyisobutylene films (PIB) were submitted to a thermal oxidation at 100°C and to a photooxidation by exposure to long-wavelength radiations (λ ≥ 300 nm) at 60°C. The modifications of the chemical structure resulting from the oxidation were determined by FT-IR analysis of the polymer films, coupled to chemical treatme…
Cu 3 Ge films have been found to have a low resistivity, good adhesion on SiO2, good thermal stability on Si, and good oxidation resistance. It has the potential as an ideal adhesion/barrier/passivation layer for Cu ultralarge scale integration metallization. The kinetics of Cu3Ge formation and the thermal stability o…
The synthesis and crystal structure of the low-tempterature polymorph of barium zirconium sulfide is reported. The title compound contains double BaZrS3 perovskite layers separated by BaS layers. The compound is the n = 2 member of the Ban+1ZrnS3n+1 Ruddlesden-Popper sulfides. This polymorph of Ba3Zr2S7 was crystalliz…
The basic aspects related to the scattering processes, useful for both the analytical and Monte Carlo calculation of backscattering and the depth distribution of low-energy ${(E}_{0}<~$10 keV) electrons impinging on solid targets, are described. After a careful analysis of the scattering mechanisms, selected new re…
We report on an angle-resolved resonant photoemission study of Co and Fe metal at the ${M}_{\mathrm{III}}$ absorption threshold. The intensity of the various spectral components was measured as a function of the electron emission angle relative to the E vector of the incident light. On ${M}_{\mathrm{III}}$ resonance,…
Polymer dispersed liquid crystal (PDLC) films (5CB/PMMA, 60/40) of different droplet size were prepared by a solvent-induced phase separation method under different N2 flow speeds. The effects of droplet size on the thermal transitions of the LC and various dielectric properties such as dielectric constant, conductanc…
The synthesis of polyamide-imide (PAI) can be performed by the reaction of p-chlorophenol-(PCP) blocked 4,4′-diphenyl methane diisocyanates (BMDI) with trimellitic anhydride (TMA) using a two-stage heating. At 80°C the polyimide oligomers were first formed and the high molecular weight PAI can not be available until t…
The piezoresistivity of polycrystalline p-type diamond films has been studied. The films were grown by microwave plasma assisted chemical vapor deposition and in situ doped with different concentrations of boron. A four-point electrical measurement was performed to evaluate the film resistivity change upon straining i…
Wide-angle x-ray diffraction studies were performed for as-spun wet poly(p-phenylene terephthalamide) fiber. The effects of sorbed water on the equatorial diffractions from the (110) and (200) crystal planes and on the meridional diffractions from the (002), (004), and (006) crystal planes were analyzed during desorpt…
Although polymeric crystallization processes heterogeneously induced by foreign surfaces have been the subject of an overwhelming amount of experimental investigations over the last 30 years, this topic suffers from the absence of theoretical or predictive tools describing the polymer–substrate interactions at work in…
Dielectric spectrometry experiments are performed on a series of polystyrene–glass bead composites with volume filler content from 0 to 50% and with three particle diameters (5 μm, 20 μm, and 90 μm) in order to study the Maxwell–Wagner–Sillars (MWS) relaxations and the percolation phenomena. In the high-temperature re…
FT–IR spectroscopy was used to study the specific interactions in polyacrylonitrile-silk fibroin (PAN–SF) and poly(acrylonitrile-co-methyl acrylate)-silk fibroin (PANMA–SF) blends. No specific interaction was found in PAN–SF blends. In PANMA–SF blends, however, a new 1703 cm−1 band, assigned to be hydrogen-bonded carb…
The crystal structure, thermal vibrations, and electron density of the charge-transfer complex bis(thiodimethylene)-tetrathiafulvalene tetracyanoquinodimethane (BTDMTTF-TCNQ, formally ${\mathrm{C}}_{10}{\mathrm{H}}_{8}{\mathrm{S}}_{6}^{+}{\mathrm{\ensuremath{\cdot}}\mathrm{C}}_{12}{\mathrm{H}}_{4}{\mathrm{N}}_{4}^{\ma…
Numerous polycarbonates were prepared by means of “diphosgene” in pyridine using hydroquinone 4-hydroxybenzoate (HQHB) as mesogenic diphenol. In addition to the homopolycarbonate, binary copolycarbonates of HQHB and 4,4′-dihydroxychalcone (DHC) with varying molar composition were prepared. A series of ternary copolyca…
We report that antiferromagnetic and antiferromagnetic (AF-AF) alternating Heisenberg chains with S =1/2 are formed in (CH 3 ) 2 CHNH 3 CuBr 3 , which is in contrast to the almost isomorphous compound (CH 3 ) 2 CHNH 3 CuCl 3 , because the Cl compound forms ferromagnetic-dominant ferromagnetic and antiferromagnetic (F-…
We report temperature-dependent infrared spectra of ${\mathrm{NdNiO}}_{3}$ prepared by synthesis under high oxygen pressure. Its room-temperature reflectivity is characteristic of a metal oxide with a Drude tail asymptotically extending to higher frequencies. The sharp metal-insulator transition is detected at about 2…
Faraday effect measurements have been carried out at room temperature for some sodium borate glasses containing Eu2+ ions prepared under a reducing atmosphere. The wavelength dependence of the Verdet constant is analyzed in terms of a theory derived by Van Vleck and Hebb to obtain effective transition wavelength of th…
The chemical state of sulfur on (NH${}_{4}{)}_{2}{\mathrm{S}}_{x}$-treated InAs(001) and thermal stability of the surface have been studied by high-resolution x-ray photoelectron spectroscopy and low-energy electron diffraction. We find sulfur bonded to In and As atoms but no elemental sulfur for the as-treated surfac…
The effect of monomer structure and catalyst on the synthesis of hyperbranched polyesters based on 4,4-(4′-hydroxyphenyl)pentanoic acid has been examined. The nature of the ester group and the catalyst have a significant effect on the molecular weight of the hyperbranched polyester but do not effect the degree of bran…
In the present work, the influence of the substitution of Al for Mn on the structure and magnetic properties of TbMn6−xAlxSn6 compounds was investigated. With increasing Al concentration the lattice constants a, c, and the unit-cell volume V decrease monotonically. The TbMn6−xAlxSn6 compounds exhibit ferrimagnetic ord…