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Model identification and control strategies for batch cooling crystallizers

Stephen M. Miller、James B. Rawlings1994-08-01AIChE Journal

Abstract The open‐loop optimal control strategy to regulate the crystal‐size distribution of batch cooling crystallizers handles input, output, and final‐time constraints, and is applicable to crystallization with size‐dependent growth rate, growth dispersion, and fines dissolution. The objective function can be formu…

Chemical and Physical Properties in Aqueous SolutionsCrystallization and Solubility StudiesProcess Optimization and Integration

Fused Polycyclic Aromatics via Electrophile-Induced Cyclization Reactions: Application to the Synthesis of Graphite Ribbons

Marc B. Goldfinger、Timothy M. Swager1994-08-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFused Polycyclic Aromatics via Electrophile-Induced Cyclization Reactions: Application to the Synthesis of Graphite RibbonsMarc B. Goldfinger and Timothy M. SwagerCite this: J. Am. Chem. Soc. 1994, 116, 17, 7895–7896Publication Date (Print):August 1, 1994Publication History…

Fiber-reinforced polymer compositesCarbon Nanotubes in CompositesCatalysis for Biomass Conversion

Solid-State 13C NMR of Nephila clavipes Dragline Silk Establishes Structure and Identity of Crystalline Regions

Alexandra Simmons、Ed Ray、Lynn W. Jelinski1994-08-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolid-State 13C NMR of Nephila clavipes Dragline Silk Establishes Structure and Identity of Crystalline RegionsAlexandra Simmons, Ed Ray, and Lynn W. JelinskiCite this: Macromolecules 1994, 27, 18, 5235–5237Publication Date (Print):August 1, 1994Publication History Published…

Silk-based biomaterials and applicationsSilkworms and Sericulture Research

Spin Transitions and Thermal Hysteresis in the Molecular-Based Materials [Fe(Htrz)2(trz)](BF4) and [Fe(Htrz)3](BF4)2.cntdot.H2O (Htrz = 1,2,4-4H-triazole; trz = 1,2,4-triazolato)

Jonas Kroeber、Jean-Paul Audière、Renée Claude 等 9 位作者1994-08-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpin Transitions and Thermal Hysteresis in the Molecular-Based Materials [Fe(Htrz)2(trz)](BF4) and [Fe(Htrz)3](BF4)2.cntdot.H2O (Htrz = 1,2,4-4H-triazole; trz = 1,2,4-triazolato)Jonas Kroeber, Jean-Paul Audiere, Renee Claude, Epiphane Codjovi, Olivier Kahn, Jaap G. Haasnoot,…

Magnetism in coordination complexesMetal complexes synthesis and propertiesMetal-Organic Frameworks: Synthesis and Applications

NAD+-dependent formate dehydrogenase

Vladimir O. Popov、Victor S. Lamzin1994-08-01OpenAlex

Research Article| August 01 1994 NAD+-dependent formate dehydrogenase V O Popov; V O Popov 1A. N. Bakh Institute of Biochemistry, Russian Academy of Sciences, Leninskiy pr. 33, 117071, Moscow, Russia Search for other works by this author on: This Site PubMed Google Scholar V S Lamzin V S Lamzin 1A. N. Bakh Institute o…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Mechanical and thermal properties of dragline silk from the spider Nephila clavipes

Philip M. Cunniff、Stephen A. Fossey、Margaret Auerbach 等 9 位作者1994-08-01OpenAlex

Abstract Dragline silk from the spider, Nephila clavipes , was characterized by thermal analysis (TGA, DSC, DMA), computational modeling, scanning electron microscopy and by quasi‐static as well as high rates of strain. Thermal stability to about 230°C was observed by TGA, two transitions by DMA, −75°C, representative…

Silk-based biomaterials and applicationsSilkworms and Sericulture ResearchPhytochemical compounds biological activities

Physical Properties of Mixed Conductor Solid Oxide Fuel Cell Anodes of Doped CeO2

Mogens Bjerg Mogensen、Thomas Lindegaard、Uffe Rud Hansen 等 4 位作者1994-08-01OpenAlex

Samples of doped with oxides such as and were prepared. Their conductivities and expansions on reduction were measured at 1000°C, and the thermal expansion coefficients in the range 50 to 1000°C were determined. The ionic and electronic conductivity were derived from curves of total conductivity vs. oxygen partial pre…

Fuel Cells and Related MaterialsAdvancements in Solid Oxide Fuel CellsElectrocatalysts for Energy Conversion

Surface Activity of Poly(ethylene oxide)-block-Poly(propylene oxide)-block-Poly(ethylene oxide) Copolymers

Paschalis Alexandridis、Vassiliki Athanassiou、Shinya Fukuda 等 4 位作者1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface Activity of Poly(ethylene oxide)-block-Poly(propylene oxide)-block-Poly(ethylene oxide) CopolymersPaschalis Alexandridis, Vassiliki Athanassiou, Shinya Fukuda, and T. Alan HattonCite this: Langmuir 1994, 10, 8, 2604–2612Publication Date (Print):August 1, 1994Publicat…

Inorganic and Organometallic ChemistryAdvanced Polymer Synthesis and CharacterizationConducting polymers and applications

Protein-protein recognition: Crystal structural analysis of a barnase-barstar complex at 2.0-.ANG. resolution

Ashley M. Buckle、Gideon Schreiber、A.R. Fersht1994-08-01OpenAlex

We have solved, refined, and analyzed the 2.0-å resolution crystal structure of a 1:1 complex between the bacterial ribonuclease, barnase, and a Cys-->Ala(40,82) double mutant of its intracellular polypeptide inhibitor, barstar. Barstar inhibits barnase by sterically blocking the active site with a helix and adjacent…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Organic Salts with Large Second-Order Optical Nonlinearities

Seth R. Marder、Joseph W. Perry、Christopher P. Yakymyshyn1994-08-01OpenAlex

This paper presents a review of recent work on the development of organic salts for second-order nonlinear optical applications. In particular, salts in which the cation has been designed to have a large molecular hyperpolarizability and in which variation of the counterion facilitates preparation of crystals with the…

Nonlinear Optical Materials ResearchPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Structural Properties of a Carbon-Nanotube Crystal

J. Tersoff、Rodney S. Ruoff1994-08-01OpenAlex

Carbon nanotubes of uniform size may soon be available in macroscopic quantities. Here we examine the ordered condensed phase of these tubes. As the tube diameter varies, the structural properties show a clear transition between two regimes with qualitatively different behavior. Tubes 10 \AA{} and less in diameter beh…

Fullerene Chemistry and ApplicationsCarbon Nanotubes in CompositesGraphene research and applications

Living Radical Polymerization of Acrylates by Organocobalt Porphyrin Complexes

Bradford B. Wayland、George Poszmik、Shakti L. Mukerjee 等 4 位作者1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLiving Radical Polymerization of Acrylates by Organocobalt Porphyrin ComplexesBradford B. Wayland, George Poszmik, Shakti L. Mukerjee, and Michael FrydCite this: J. Am. Chem. Soc. 1994, 116, 17, 7943–7944Publication Date (Print):August 1, 1994Publication History Published on…

Metal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry Reactions

Why Rhodium in Automotive Three-Way Catalysts?

M. Shelef、George W. Graham1994-08-01OpenAlex

The catalytic treatment of motor vehicle exhaust gas has been a feature of all passenger cars in the USA since the 1975 model year. It has since been adopted in all the developed countries as the principal means of con-trolling the emissions from vehicles powered by Otto-cycle internal com-bustion engines. These inclu…

Chemical Synthesis and CharacterizationCatalytic Processes in Materials ScienceRadioactive element chemistry and processing

Measurement of piezoelectric coefficients of ferroelectric thin films

K. Lefki、G. J. M. Dormans1994-08-01OpenAlex

This article presents measurements of piezoelectric coefficients of lead zirconate titanate (PZT) thin films. The normal load method is used to measure the coefficients for PZT films with various compositions prepared by the sol-gel technique or by organometallic chemical vapor deposition (OMCVD). The as-deposited OMC…

Silicone and Siloxane ChemistryAdvanced MEMS and NEMS TechnologiesAdhesion, Friction, and Surface Interactions

Fluorescence and Absorption Spectroscopic Properties of Dipyrrometheneboron Difluoride (BODIPY) Derivatives in Liquids, Lipid Membranes, and Proteins

Jan Karolin、Lennart B.‐Å. Johansson、Leif Strandberg 等 4 位作者1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluorescence and Absorption Spectroscopic Properties of Dipyrrometheneboron Difluoride (BODIPY) Derivatives in Liquids, Lipid Membranes, and ProteinsJan Karolin, Lennart B.-A. Johansson, Leif Strandberg, and Tor NyCite this: J. Am. Chem. Soc. 1994, 116, 17, 7801–7806Publicat…

Analytical Chemistry and SensorsConducting polymers and applicationsLuminescence and Fluorescent Materials

Size-Selective Synthesis of Nanostructured Transition Metal Clusters

Manfred T. Reetz、Wolfgang Helbig1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSize-Selective Synthesis of Nanostructured Transition Metal ClustersManfred T. Reetz and Wolfgang HelbigCite this: J. Am. Chem. Soc. 1994, 116, 16, 7401–7402Publication Date (Print):August 1, 1994Publication History Published online1 May 2002Published inissue 1 August 1994ht…

Catalytic Processes in Materials ScienceNanocluster Synthesis and ApplicationsMolecular Junctions and Nanostructures

The concept of secondary doping as applied to polyaniline

Alan G. MacDiarmid、Arthur J. Epstein1994-08-01OpenAlex

Phenomenologically, a primary dopant for a conducting polymer is a substance, a relatively small quantity of which drastically changes the electronic, optical, magnetic and/or structural properties of the polymer and is accompanied by a large increase in conductivity. De-doping results in a reversal of the newly induc…

Conducting polymers and applicationsElectrochemical sensors and biosensorsAdvanced Sensor and Energy Harvesting Materials

Application of Carbon Nanotubes as Supports in Heterogeneous Catalysis

J.-M. Planeix、N. Coustel、Bernard Coq 等 9 位作者1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTApplication of Carbon Nanotubes as Supports in Heterogeneous CatalysisJ. M. Planeix, N. Coustel, B. Coq, V. Brotons, P. S. Kumbhar, R. Dutartre, P. Geneste, P. Bernier, and P. M. AjayanCite this: J. Am. Chem. Soc. 1994, 116, 17, 7935–7936Publication Date (Print):August 1, 19…

Nanomaterials for catalytic reactionsElectrocatalysts for Energy ConversionCatalytic Processes in Materials Science

CdS Nanoclusters: Synthesis, Characterization, Size Dependent Oscillator Strength, Temperature Shift of the Excitonic Transition Energy, and Reversible Absorbance Shift

Tobias Voßmeyer、Lynne Katsikas、Michael Giersig 等 8 位作者1994-08-01OpenAlex

Improved synthetic routes and size-selective precipitation have enabled the preparation of almost monodisperse CdS clusters. Six samples of 1-thioglycerol stabilized clusters with diameters of approximately 13, 14, 16, 19, 23, and 39 Å have been prepared as fully redispersible powders and were characterized by element…

Chalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties

Lewis J. Fetters、David J. Lohse、Dieter Richter 等 5 位作者1994-08-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConnection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic PropertiesL. J. Fetters, D. J. Lohse, D. Richter, T. A. Witten, and A. ZirkelCite this: Macromolecules 1994, 27, 17, 4639–4647Publication Date (Print):August 1, 1994Publication Hist…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesAdvanced Physical and Chemical Molecular Interactions