Materials Literature
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When a liquid touches a solid surface, it spreads to minimize the system's energy. The classic thin-film model describes the spreading as an interplay between gravity, capillarity, and viscous forces, but it cannot see an end to this process as it does not account for the nonhydrodynamic liquid-solid interactions. Whi…
ATP is the limiting precursor and driving force for S-adenosylmethionine (SAM) biosynthesis in Escherichia coli. In contrast to traditional optimization of fermentation processes, the synthetic sRNA-based repression strategy, which was developed as a highly efficient gene knockdown approach, has been applied for the r…
Novel diblock copolypeptides are synthesized and evaluated as a pH-sensitive drug delivery vector for anticancer drugs and siRNA co-delivery. The synthetic process involve the ring opening polymerization of α-amino acid N-carboxyanhydrides as well as aminolysis and deprotection reactions, and the structures are charac…
An active terahertz (THz) wave hybrid grating structure of Au/Ti metallic grating on VO2/Al2O3 (0001) was fabricated and evaluated. In our structure, it is shown that the metallic gratings on the VO2 layer strengthen the metallic characteristics to enhance the contrast of the metallic and dielectric phases of a VO2-ba…
Capping agent-controlled stability of nanoparticles tailors them for different applications, but the associated particle–solvent dynamics are poorly understood. Herein, previously unseen capping agent-gated nanoparticle redox activity is observed for poly(ethylene glycol)-coated silver nanoparticles. This is revealed…
Biogas contains trace compounds detrimental for solid oxide fuel cell (SOFC) application, especially sulphur-containing compounds and volatile organic silicon compounds (VOSiCs). It is therefore necessary to remove these impurities from the biogas for fuelling an SOFC. In this paper, dynamic lab-scale adsorption tests…
A new method improving the design of panoramic lens with a long focal length based on ogive and aspheric surface is proposed. In this design, we use a special conjugation between "annular entrance pupil" and aperture stop to correct the chromatic transverse aberrations. Moreover, we use a new imaging relationship to i…
Abstract Palladium nanoparticles supported on carbon nanotubes were used in the Tsuji–Wacker oxidation. The palladium‐based nanohybrid was found to be very active in combination with cuprous chloride for the selective oxidation of terminal olefins into methyl ketones. The co‐catalytic system operates under very mild a…
We present a rapid and gentle drying method for the production of high-grade tomato powders from double concentrated tomato paste, comparing results with powders obtained by foam mat air drying and freeze dried powders. The principle of this method consists of drying tomato paste in foamed state at low temperatures in…
In the present work we grow anodic self-organized Ta2O5 nanotube layers, which are converted by ammonolysis to Ta3 N5 nanotubes, and then are used as photoanodes for photoanalytic water splitting. We introduce a two-step anodization process that not only improves order (reduced growth defects) and overall light absorp…
Abstract g‐C3N4 sensitized TiO2 nanotube arrays (g‐C3N4/TNTs) were fabricated by using a simple solid sublimation and transition (SST) method using urea as precursor. The photoelectrochemical (PEC) performances were evaluated in this work. It is proposed that the g‐C3N4 layer can play dual roles: surface sensitization…
Nanostructuring hematite films is a critical step for enhancing photoelectrochemical performance by circumventing the intrinsic limitations on minority carrier transport. Herein, we present a novel sol-gel approach that affords nanostructured hematite films by including CuO as sacrificial templating agent. First, by a…
The magnetic critical scattering in ${\mathrm{Sr}}_{2}{\mathrm{IrO}}_{4}$ has been characterized using x-ray resonant magnetic scattering (XRMS) both below and above the three-dimensional antiferromagnetic ordering temperature ${T}_{\text{N}}$. The order parameter critical exponent below ${T}_{\text{N}}$ is found to b…
The spectroscopic, photochemical, and biological studies of 5,10,15,20-tetrakis[2,6-difluoro-5(N-methylsulfamylo)phenyl]porphyrinate Zn(II) (ZnF2PMet) were carried out including absorption and fluorescence spectra, fluorescence quantum yields, triplet absorption spectra, triplet lifetimes, singlet oxygen quantum yield…
Carbon-based sorbents have been proven to be cost-effective in removing pollutants from wastewater. Biochar from plant residue and agricultural waste is an emerging treatment technology. However, there is a limited number of studies on the effects of various biochar sources on metal adsorption. The aim of this study w…
A heterostructured Al(x)Ga(1-x)As/GaAs photocathode consisting of a composition-graded buffer layer and an exponential-doped emission layer is developed to improve the photoemission performance over the wavelength region of interest. The theoretical quantum efficiency models for reflection-mode and transmission-mode A…
A microporous Schiff base network (SNW) polymer containing melamine groups is synthesized as a specific metal template material and employed as a solid support to stabilize copper(I) ions. The Cu(I) ions are incorporated into the SNW structure through coordination with the nitrogen atoms present in the melamine groups…
Crystal engineering strategies have been delineated during the past decade for the design of multi-component molecular crystals (molecular cocrystals, MCCs). However, the same depth of understanding has not yet been established for cocrystals that are comprised of at least one ionic compound (ionic cocrystals, ICCs).…
Abstract The reaction of the Schiff base (3,5‐di‐tert‐butyl‐2‐hydroxybenzylidene)‐2‐hydroxybenzohydrazide (H3L) with copper(II) nitrate, acetate or metaborate has led to the isomeric complexes [Cu3(L)2(MeOH)4] (1), [Cu3(L)2(MeOH)2]·2MeOH (2) and [Cu3(L)2(MeOH)4] (3), respectively, in which the ligand L exhibits dianio…
Titanium dioxide (TiO2 ) is a well-known photocatalyst for its excellent bactericidal property under UVA light. The purpose of this study was to develop physically stable TiO2 coatings on food contact surfaces using different binding agents and develop methods to evaluate their durability and microbicidal property. Se…