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Band gap and refractive index tunability in thallium based layered mixed crystals

N.M. Gasanly2015-07-15Journal of Applied Physics

Compositional variation of the band gap energy and refractive index of TlMeX2-type (Me = Ga or In and X = S or Se) layered mixed crystals have been studied by the transmission and reflection measurements in the wavelength range of 400–1100 nm. The analysis of absorption data of TlGa1-xInxSe2, TlGa(S1−xSex)2, TlGa1−xIn…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Risk and Reliability Analysis of Multibarrier System for Near-Surface Disposal Facilities

S.B. Sujitha、K. Geetha Manjari、Sampurna Datta 等 4 位作者2015-07-15Journal of Hazardous Toxic and Radioactive Waste

The performance of near-surface disposal facilities (NSDFs) for low-level radioactive waste depends on the type of materials used in the construction of barrier system, the properties of geological formations around the facility, and the type of waste containment system. By taking into account the effect of the factor…

Probabilistic and Robust Engineering DesignGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Head‐to‐Tail Zig‐Zag Packing of Dipolar Merocyanine Dyes Affords High‐Performance Organic Thin‐Film Transistors

Aifeng Lv、Matthias Stolte、Frank Würthner2015-07-15Angewandte Chemie

Abstract Attachment of bulky substituents at both thiophene donor (D) and thiazole acceptor (A) heterocycles of a dipolar (μg=10.4 D) D‐π‐A merocyanine dye affords a more than 1 Å expansion of the common antiparallel supramolecular dimer motif in the solid state, enabling very close π‐contacts (3.36 Å) to two other ne…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Barrierless Single‐Electron‐Induced cis–trans Isomerization

Shachar Klaiman、Lorenz S. Cederbaum2015-07-15Angewandte Chemie

Abstract Lowering the activation energy of a chemical reaction is an essential part in controlling chemical reactions. By attaching a single electron, a barrierless path for the cis–trans isomerization of maleonitrile on the anionic surface is formed. The anionic activation can be applied in both reaction directions,…

Molecular Junctions and NanostructuresPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Growth, optical, thermal and electrical properties of nonlinear optical -glycine single crystal

N. Nithya、R. Mahalakshmi、Suresh Sagadevan2015-07-15Scientific Research and Essays

Single crystal growth of γ-glycine has been grown by solution growth technique. The lattice parameters and crystal system of the grown crystals were confirmed by single crystal X-ray diffraction analysis. The functional groups present in the grown crystal were identified by FT-IR spectral analysis. The optical propert…

Nonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical StudiesCrystallization and Solubility Studies

Fabrication of New Cellulose-Based Sorbents for Fast and Efficient Removal of Hazardous Al(III) Ions from Their Aqueous Solutions

Ahmed M. Yousif、Sherif A. Labib2015-07-15Journal of Dispersion Science and Technology

Cellulose was used as a base polymer in two prepared resins when it was grafted by glycidyl methacrylate (GMA) then immobilized with 8-hydroxyquinoline by two different procedures. The resulting resins were characterized by infrared (IR) spectroscopy, thermogravimetric analysis (TGA), and nitrogen surface area measure…

Adsorption and biosorption for pollutant removalAdvanced Cellulose Research StudiesExtraction and Separation Processes

Potential theory for gate adsorption on soft porous crystals

Ryohei Numaguchi、Hideki Tanaka、Shotaro Hiraide 等 4 位作者2015-07-15Molecular Simulation

We demonstrate that an adsorption potential at the gate adsorption pressure of soft porous crystals (SPCs) based on the Polanyi's potential theory of adsorption shows a constancy to temperature. This was done using grand canonical Monte Carlo simulations and free energy analysis, which were carried out with a simplifi…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesCarbon Dioxide Capture Technologies

In Vitro Assessment of Chronic Nanoparticle Effects on Respiratory Cells

Eleonore Fröhlich、Claudia Meindl2015-07-15InTech eBooks

Nanoparticles (NPs) are included in a variety of consumer products including cosmetics, food, and food packaging. They are also used in medical products for dermal and oral application and for inhalation. The thinness of the air–blood barrier, the large absorption area of the lung, and the relatively low inactivation…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsInhalation and Respiratory Drug Delivery

Evaluation of the Shearing Strength of a WC-12Co Thermal Spray Coating by the Scraping Test Method

Kenji KANEKO2015-07-15Coatings

This paper reports on an experimental and analytical investigation conducted into efficacy of the scraping shear-test method in estimating the shearing adhesive strength of a thermally sprayed coating. It was found that the critical average shear stress, the apparent failure strength of WC-Co thermal spray coating, de…

High-Temperature Coating BehaviorsAdvanced materials and compositesMetal Alloys Wear and Properties

Effect of Mesh Number of Wood Powder and Ratio of Raw Materials on Properties of Composite Material of Starch/Wood Powder

Yanhua Zhang、Runan Kou、Shanshan Lv 等 7 位作者2015-07-15BioResources

Utilizing wood powder and corn starch as the main materials with polyurethane adhesive as a cross-linking agent, the starch/wood powder composite material was prepared via molding forming techniques. The effects of wood powder mesh and addition of wood powder on the properties of composite material were investigated.…

Natural Fiber Reinforced CompositesLignin and Wood ChemistryPolymer Foaming and Composites

Bifunctional Indenyl‐Derived Receptors for Fluoride Chelation and Detection

Rémi Tirfoin、Joseph A. B. Abdalla、Simon Aldridge2015-07-15Chemistry - A European Journal

Anion receptors based on a [CpFe(indenyl)] scaffold offer the possibility for the incorporation of adjacent Lewis acidic functions onto a six-membered carbocyclic framework, while at the same time retaining the colorimetric/electrochemical reporter mechanisms available to synthetically simpler ferrocene systems. Thus,…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

The Effect of pH Values on the Synthesis, Microstructure and Photocatalytic Activity of Ce‐Bi2O3 by a Two‐Step Hydrothermal Method

Fengjun Zhang、Wei Lü、Guosheng Xiao 等 6 位作者2015-07-15Photochemistry and Photobiology

In this study, the effect of pH values on the microstructure and photocatalytic activity of Ce-Bi2 O3 under visible light irradiation was investigated in detail. In alkaline condition (e.g. pH = 9), the as-prepared Ce-Bi2 O3 exhibited an agglomerated status and mesoporous structures without a long-range order. While i…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Wear Behaviour and Cutting Performance of Surfaced Inserts for Wood Machining

Regita Bendikienė、Gintaras Keturakis、Tilmutė Pilkaitė 等 4 位作者2015-07-15Strojniški vestnik – Journal of Mechanical Engineering

Machining, in general, and wood machining, in particular, is a complex to explain and describe many influencing factors. Natural wood is nonhomogeneous biological material, so each species of wood requires different machining conditions and tools. Understanding of wood properties, proper selection of cutting tools and…

Advanced machining processes and optimizationMetal Alloys Wear and PropertiesTunneling and Rock Mechanics

- Functionalization Methods of Graphene

Daniela Iannazzo、Alessandro Pistone、Signorino Galvagno2015-07-15OpenAlex

Graphene is considered today the most amazing and versatile substance available to mankind, and since its discovery in 2004, it is without any doubt the most intensively studied material [1,2]. From a chemical point of view, it is constituted by a single atomic layer of sp2-hybridized carbon atoms, with a molecule bon…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Ultrasensitive molecular absorption detection using metal slot antenna arrays

Kwang Jun Ahn、Young‐Mi Bahk、Dai‐Sik Kim 等 5 位作者2015-07-15Optics Express

We theoretically study the transmission reduction of light passing through absorptive molecules embedded in a periodic metal slot array in a near infrared wavelength regime. From the analytically solved transmitted light, we present a simple relation given by the attenuation length of light at the resonance wavelength…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Rolling at Small Scales

K.L. Nielsen、Christian F. Niordson、John W. Hutchinson2015-07-15Journal of Manufacturing Science and Engineering

The rolling process is widely used in the metal forming industry and has been so for many years. However, the process has attracted renewed interest as it recently has been adapted to very small scales where conventional plasticity theory cannot accurately predict the material response. It is well-established that gra…

Microstructure and mechanical propertiesNonlocal and gradient elasticity in micro/nano structuresMechanical stress and fatigue analysis

Cleaning Spent Bleaching Clay through Using Solvent Extraction Method and RSM Statistical Approach

Mahsa Shahi、Mohammad Reza Sabour、Alahyar Amiri 等 4 位作者2015-07-15Cumhuriyet Science Journal

Bleaching clay refers to clays that in their natural or activated state have the capacity to absorb dyes and other remaining undesirable ingredients from edible oil during its purification processes. Thus, the most important function of bleaching clay is to improve the appearance, flavor, odor, and stability of the fi…

Clay minerals and soil interactionsGeochemistry and Geologic MappingNatural Products and Applications

Analysis of the permeability tensor and the correlation length of heterogeneities in paper using X-ray microtomography

S. Lavrykov、Sanjeeva Kumar Singh、Bandaru V. Ramarao 等 5 位作者2015-07-15Drying Technology

A technique to determine the permeability from X-ray microtomographic images was developed and applied to paper structures. The images are thresholded and a skeleton of the pore space is obtained from the images. The skeleton is represented by means of a network of resistances. The total resistance of the network alon…

High voltage insulation and dielectric phenomenaNon-Destructive Testing TechniquesMaterial Properties and Processing

Fabrication of Solid Oxide Fuel Cells (SOFCs) Electrolytes by Electrophoretic Deposition (EPD) and Optimizing the Process

Iman Azarian Borojeni、Babak Raissi、Amir Maghsoudipour 等 5 位作者2015-07-15Key engineering materials

Fabrication of Solid Oxide Fuel Cells (SOFCs) electrolytes by Electrophoretic Deposition (EPD) was the target of our study. For such purpose, thin layers of Yttria Stabilized Zirconia (YSZ) were electrophoritically deposited on pre-sintered NiO-YSZ pellets. A thin graphite film on each pellet was painted to make it co…

TiO2 Photocatalysis and Solar CellsAdvancements in Solid Oxide Fuel CellsElectrophoretic Deposition in Materials Science

Novel Thermoresponsive Biodegradable Nanocomposite Hydrogels for Dual Function in Biomedical Applications

M. N. Prabhakar、P. Sudhakara、M. C. S. Subha 等 5 位作者2015-07-15Polymer-Plastics Technology and Engineering

Nanocomposite hydrogels were prepared through a blend solution of poly(lactic acid) and poly(N-isopropylacrylamide)-co-acrylamide via free radical polymerization. Plant extractions were used for the synthesis of Ag nanoparticles to study the antibacterial activity of the hydrogels. Similarly, 5-Fluorouracil drug was l…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsGraphene and Nanomaterials Applications