Materials Literature
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Electron beam melting (EBM) additive manufacturing (AM) technology has allowed the layerwise fabrication of parts from metal powder precursor materials that are selectively melted using an electron beam. An advantage of EBM technology over conventional manufacturing processes has been the capability to change processi…
We present the design and experimental demonstration of a programmable subwavelength coil array, which can manipulate the evanescent magnetic field leading to a precisely controlled electric-field pattern at an image plane in the near-field zone. A synthesis methodology is outlined for 2-D near-field manipulations. Si…
A covalently linked multichromophoric array (BDP-Por) was used as the donor layer in planar heterojunction organic photovoltaic (OPV) cells with the structure ITO/BDP-Por/C 60 /BCP/Al (BCP = bathocuproine). BDP-Por is a platinum tetrabenzoporphyrin (PtTPBP) core bonded through the phenyl groups to the meso position of…
We show that a mechanically driven magnetocaloric effect (MCE) in magneto-auxetic systems (MASs) in the vicinity of room temperature is possible and the effect can be colossal. Even at zero external magnetic field, the magnetic entropy change in this reversible process can be a few times larger in magnitude than in th…
Abstract Glucose oxidase (GOx) was incorporated in a self‐assembled multilayer modified gold electrode, based on electrostatic interaction between positively charged chitosan polymer, containing GOx, and negatively charged poly(styrene sulfonate). Good electronic communication between electrode and enzyme was ensured…
In this work we report on the growth of single crystalline Bi 2 Se 3 nanostructures (nanoribbons, nanoflakes, and nanowires) by catalyst-free decomposition sublimation in sealed silica ampules. The nanostructures directly grow on Si/SiO 2 substrates by a vapor–solid growth mechanism and show high degree of crystallini…
) has been used in traditional Chinese medicines for treatment of malignancies. However, the poor water solubility of realgar limits its clinical application. To overcome this problem, realgar quantum dots (RQDs; 5.48±1.09 nm) were prepared by a photoluminescence method. The mean particle size was characterized by hig…
Visible light-driven photocatalyst is the current research focus and silver oxyacid salts with p-block elements are the promising candidates. In this research, Ag2 CO3 was prepared by a facile precipitation method and used to degrade the pollutants from waters. The results revealed that the silver carbonate with monoc…
Abstract Biological and artificial molecules and assemblies capable of supramolecular recognition, especially those with nucleobase pairing, usually rely on autonomous or collective binding to function. Advanced site‐specific recognition takes advantage of cooperative spatial effects, as in local folding in protein–DN…
In this paper, the inexpensive 4,4-diaminostilbene-2,2-disulfonate (DAS) and 4,4-dinitro-stilbene-2,2- disulfonate (DNS) anions with arbitrary molar ratios were successfully co-intercalated into Zn2Al-layered double hydroxides (LDHs). The DAS(50%)-DNS/LDHs composite exhibited the broad UV-visible light absorption and…
The syntheses, crystal structures, and physical properties of [HFe19 O14 (OEt)30 ] and {Fe11 (OEt)24 }∞ are reported. [HFe19 O14 (OEt)30 ] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6 -oxo ligands is arranged in the rock salt structure. {Fe11 (OEt)24 }∞ is a mixed-valence coordina…
1-Deoxy-D-xylulose 5-phosphate (DXP) synthase is the first enzyme in the methylerythritol phosphate pathway to essential isoprenoids in pathogenic bacteria and apicomplexan parasites. In bacterial pathogens, DXP lies at a metabolic branch point, serving also as a precursor in the biosynthesis of vitamins B1 and B6, wh…
An experimental investigation on how the bulk and surface sensitivities of gold nanohole arrays fabricated by interference lithography affect the degree of white light beam collimation is presented. The optical transmission response of nanohole arrays has been recorded by focused and collimated beam transmission spect…
We numerically analyzed the power-coupling characteristics between a high-index-contrast dielectric slot waveguide and a metal-insulator-metal (MIM) plasmonic slot waveguide as functions of structural parameters. Couplings due mainly to the transfer of evanescent components in two waveguides generated high transmissio…
Relative cross sections for photoionization of endohedral fullerene ions ${\mathrm{Lu}}_{3}\mathrm{N}@{\mathrm{C}}_{80}{}^{q+}$ $(q=1,2,3)$ have been measured employing the photon-ion merged-beam technique. The investigations include various ionization channels ${\mathrm{Lu}}_{3}\mathrm{N}@{\mathrm{C}}_{80}{}^{+q\ensu…
Purpose – The purpose of this paper is to describe several novel techniques for implementing a crystal plasticity (CP) material model in a large deformation, implicit finite element framework. Design/methodology/approach – Starting from the key kinematic assumptions of CP, the presentation develops the necessary CP co…
Synchrotron X-rays have been used to study the oxidation of uranium and uranium hydride when encapsulated in grout and stored in de-ionised water for 10 months. Periodic synchrotron X-ray tomography and X-ray powder diffraction have allowed measurement and identification of the arising corrosion products and the rates…
Cell labeling with magnetic iron oxide nanoparticles (IONPs) is increasingly a routine approach in the cell-based cancer treatment. However, cell labeling with magnetic IONPs and their leading effects on the biological properties of human lung carcinoma cells remain scarcely reported. Therefore, in the present study t…
Proteins collapse and fold because intramolecular interactions and solvent entropy, which favor collapse, outweigh solute-solvent interactions that favor expansion. Since the protein backbone actively participates in protein folding and some intrinsically disordered proteins are glycine rich, oligoglycines are good mo…
The effect of multi-axial loading on single Kevlar® KM2 fibers is explored with an emphasis on correlating the results to fiber/yarn transverse impact. A 0.30 caliber fragment simulation projectile (FSP) is slightly modified to act as a transverse loading indenter. Fiber failure angles are forced between ∼0° and 50° i…