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Electrophoretic Deposition and Characterization of Chitosan/45S5 Bioactive Glass Composite Coatings on Porous Titanium for Biomedical Applications

S. Borjas、Eladio Gil、L. Cordero 等 7 位作者2015-07-15Key engineering materials

Porous titanium samples of cp Ti grade IV were obtained by space-holder technique (50%vol of NH4HCO3, 800 MPa, 1250 oC during 2h in high vacuum), producing a good balance between stiffness and mechanical strength. The samples were coated with chitosan/45S5 bioactive glass composite by electrophoretic deposition. Homog…

Bone Tissue Engineering MaterialsLayered Double Hydroxides Synthesis and ApplicationsElectrophoretic Deposition in Materials Science

Chemical Characteristics of Hydroxyapatite from Oyster Shell by Thermo-Chemical Process

Md. Hasan Mahmud, Kazi Abdus S alam, M. A. Gafur2015-07-15International Journal of Innovative Research in Science Engineering and Technology

Oyster shell is basically made of calcium carbonate. An attempt is made to convert calcium carbonate of oyster shell to hydroxyapatite (HA), a substitute material for bone and teeth in orthopedic and dentistry field due to their chemical and biological similarity to human hard tissue. In the present work, hydroxyapati…

Bone Tissue Engineering MaterialsAdditive Manufacturing and 3D Printing TechnologiesCalcium Carbonate Crystallization and Inhibition

Microstructure and deformation behaviour of laser welded dissimilar dual phase steel joints

Danyang Dong、Yang Liu、L. Wang 等 7 位作者2015-07-15Science and Technology of Welding & Joining

The microstructure, microhardness, tensile properties, deformation and fracture behaviour of the Nd:YAG laser welded dissimilar joints between 780 and 980 MPa dual phase steels over a wide strain rate range were investigated. The welded joint shows hardening in fusion zone, supercritical and intercritical heat affecte…

Microstructure and Mechanical Properties of SteelsWelding Techniques and Residual StressesMetal Alloys Wear and Properties

Effects of potassium titanate whiskers on the mechanical and thermal properties of poly (para‐phenylene terephthalamide) paper sheet

Bin Yang、Meiyun Zhang、Zhaoqing Lu2015-07-15Polymer Composites

In this work, poly(para‐phenylene terephthalamide) (PPTA) paper sheets composed of PPTA fibers and PPTA fibrids filled with highly crystalline and high ratio of length to diameter potassium titanate whiskers (PTW) were investigated in view of possible employment as reinforcement and cost‐reducing materials. The morpho…

Advanced Sensor and Energy Harvesting MaterialsNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Sensitivity Enhancement in Nickel Hydroxide/3D‐Graphene as Enzymeless Glucose Detection

Iman Shackery、Umakant M. Patil、Min‐Jung Song 等 10 位作者2015-07-15Electroanalysis

Abstract A nickel hydroxide (Ni(OH)2)/3D‐graphene composite is used as monolithic free‐standing electrode for enzymeless electrochemical detection of glucose. Ni(OH)2 nanoflakes are synthesized by using a simple solution growth procedure on 3D‐graphene foam which was grown by chemical vapor deposition (CVD). The pore…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Interfacial improvement of carbon fiber-reinforced methylphenylsilicone resin composites with sizing agent containing functionalized carbon nanotubes

Guangshun Wu、Lichun Ma、Li Liu 等 5 位作者2015-07-15Journal of Adhesion Science and Technology

A liquid sizing agent containing multiwall carbon nanotubes (MWCNTs) was prepared for carbon fiber (CF) reinforced methylphenylsilicone resin (MPSR) composite applications. In order to improve the dispersion of MWCNTs in the sizing agent and interfacial adhesion between CF and MPSR, MWCNTs and CF were functioned by th…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Morphological and Structural Evolutions of Metal–Organic Framework Particles from Amorphous Spheres to Crystalline Hexagonal Rods

Hee Jung Lee、Junghun We、Juno Kim 等 8 位作者2015-07-15Angewandte Chemie

Abstract Compositions as well as morphologies and structures of particles are vital factors that define their properties and applications. However, the morphology and structure changes associated with the composition change of metal–organic frameworks (MOFs) are barely studied. Herein, we report the morphology and str…

Metal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Enhancement of Low-Cycle Fatigue Performance From Tailored Microstructures Enabled by Electron Beam Melting Additive Manufacturing Technology

Philip Morton、Jorge Mireles、Heimdall Mendoza 等 6 位作者2015-07-15Journal of Mechanical Design

Electron beam melting (EBM) additive manufacturing (AM) technology has allowed the layerwise fabrication of parts from metal powder precursor materials that are selectively melted using an electron beam. An advantage of EBM technology over conventional manufacturing processes has been the capability to change processi…

Additive Manufacturing Materials and ProcessesAdditive Manufacturing and 3D Printing TechnologiesTitanium Alloys Microstructure and Properties

Synthesis and Design of Programmable Subwavelength Coil Array for Near-Field Manipulation

Fei Gao、Fu‐Shun Zhang、Hiroki Wakatsuchi 等 4 位作者2015-07-15IEEE Transactions on Microwave Theory and Techniques

We present the design and experimental demonstration of a programmable subwavelength coil array, which can manipulate the evanescent magnetic field leading to a precisely controlled electric-field pattern at an image plane in the near-field zone. A synthesis methodology is outlined for 2-D near-field manipulations. Si…

Metamaterials and Metasurfaces ApplicationsEnergy Harvesting in Wireless NetworksNear-Field Optical Microscopy

Implications of Multichromophoric Arrays in Organic Photovoltaics

Patrick Erwin、Sarah M. Conron、Jessica H. Golden 等 5 位作者2015-07-15Chemistry of Materials

A covalently linked multichromophoric array (BDP-Por) was used as the donor layer in planar heterojunction organic photovoltaic (OPV) cells with the structure ITO/BDP-Por/C 60 /BCP/Al (BCP = bathocuproine). BDP-Por is a platinum tetrabenzoporphyrin (PtTPBP) core bonded through the phenyl groups to the meso position of…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Colossal magnetocaloric effect in magneto-auxetic systems

Mirosław R. Dudek、Krzysztof W. Wojciechowski、Joseph N. Grima 等 5 位作者2015-07-15Smart Materials and Structures

We show that a mechanically driven magnetocaloric effect (MCE) in magneto-auxetic systems (MASs) in the vicinity of room temperature is possible and the effect can be colossal. Even at zero external magnetic field, the magnetic entropy change in this reversible process can be a few times larger in magnitude than in th…

Cellular and Composite StructuresShape Memory Alloy TransformationsAdvanced Materials and Mechanics

Acidic and Basic Functionalized Carbon Nanomaterials as Electrical Bridges in Enzyme Loaded Chitosan/Poly(styrene sulfonate) Self‐Assembled Layer‐by‐Layer Glucose Biosensors

Melinda David、Mădălina M. Bârsan、Monica Florescu 等 4 位作者2015-07-15Electroanalysis

Abstract Glucose oxidase (GOx) was incorporated in a self‐assembled multilayer modified gold electrode, based on electrostatic interaction between positively charged chitosan polymer, containing GOx, and negatively charged poly(styrene sulfonate). Good electronic communication between electrode and enzyme was ensured…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Catalyst-free Growth of Single Crystalline Bi2Se3 Nanostructures for Quantum Transport Studies

Christian Nowka、Louis Veyrat、Sandeep Gorantla 等 11 位作者2015-07-15Crystal Growth & Design

In this work we report on the growth of single crystalline Bi 2 Se 3 nanostructures (nanoribbons, nanoflakes, and nanowires) by catalyst-free decomposition sublimation in sealed silica ampules. The nanostructures directly grow on Si/SiO 2 substrates by a vapor–solid growth mechanism and show high degree of crystallini…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesTopological Materials and Phenomena

Realgar quantum dots induce apoptosis and necrosis in HepG2 cells through endoplasmic reticulum stress

Yu Qin、Huan Wang、Zhengyun Liu 等 5 位作者2015-07-15Biomedical Reports

) has been used in traditional Chinese medicines for treatment of malignancies. However, the poor water solubility of realgar limits its clinical application. To overcome this problem, realgar quantum dots (RQDs; 5.48±1.09 nm) were prepared by a photoluminescence method. The mean particle size was characterized by hig…

Advanced biosensing and bioanalysis techniquesEndoplasmic Reticulum Stress and DiseaseCarbon and Quantum Dots Applications

Preparation of Silver Carbonate and its Application as Visible Light‐driven Photocatalyst Without Sacrificial Reagent

Wei Jiang、Yachao Zeng、Xiaoyan Wang 等 7 位作者2015-07-15Photochemistry and Photobiology

Visible light-driven photocatalyst is the current research focus and silver oxyacid salts with p-block elements are the promising candidates. In this research, Ag2 CO3 was prepared by a facile precipitation method and used to degrade the pollutants from waters. The results revealed that the silver carbonate with monoc…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsAdvanced Nanomaterials in Catalysis

Spatial, Hysteretic, and Adaptive Host–Guest Chemistry in a Metal–Organic Framework with Open Watson–Crick Sites

Hong Cai、Mian Li、Xiaorong Lin 等 7 位作者2015-07-15Angewandte Chemie

Abstract Biological and artificial molecules and assemblies capable of supramolecular recognition, especially those with nucleobase pairing, usually rely on autonomous or collective binding to function. Advanced site‐specific recognition takes advantage of cooperative spatial effects, as in local folding in protein–DN…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesSupramolecular Self-Assembly in Materials

An Inexpensive Co-Intercalated Layered Double Hydroxide Composite with Electron Donor-Acceptor Character for Photoelectrochemical Water Splitting

Shufang Zheng、Jun Lu、Dongpeng Yan 等 7 位作者2015-07-15Scientific Reports

In this paper, the inexpensive 4,4-diaminostilbene-2,2-disulfonate (DAS) and 4,4-dinitro-stilbene-2,2- disulfonate (DNS) anions with arbitrary molar ratios were successfully co-intercalated into Zn2Al-layered double hydroxides (LDHs). The DAS(50%)-DNS/LDHs composite exhibited the broad UV-visible light absorption and…

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsLayered Double Hydroxides Synthesis and Applications

[Fe19] “Super‐Lindqvist” Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol

Olaf Nachtigall、M. Kusserow、Rodolphe Clérac 等 8 位作者2015-07-15Angewandte Chemie International Edition

The syntheses, crystal structures, and physical properties of [HFe19 O14 (OEt)30 ] and {Fe11 (OEt)24 }∞ are reported. [HFe19 O14 (OEt)30 ] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6 -oxo ligands is arranged in the rock salt structure. {Fe11 (OEt)24 }∞ is a mixed-valence coordina…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Hydroxybenzaldoximes Are D ‐GAP‐Competitive Inhibitors of E. coli 1‐Deoxy‐ D ‐Xylulose‐5‐Phosphate Synthase

David Bartee、Francine Morris、Amer Al‐khouja 等 4 位作者2015-07-15ChemBioChem

1-Deoxy-D-xylulose 5-phosphate (DXP) synthase is the first enzyme in the methylerythritol phosphate pathway to essential isoprenoids in pathogenic bacteria and apicomplexan parasites. In bacterial pathogens, DXP lies at a metabolic branch point, serving also as a precursor in the biosynthesis of vitamins B1 and B6, wh…

Microbial Natural Products and BiosynthesisEnzyme Structure and FunctionPlant biochemistry and biosynthesis

Improving the performance of gold nanohole array biosensors by controlling the optical collimation conditions

J. W. Menezes、Anderson Thesing、Chiara Valsecchi 等 5 位作者2015-07-15Applied Optics

An experimental investigation on how the bulk and surface sensitivities of gold nanohole arrays fabricated by interference lithography affect the degree of white light beam collimation is presented. The optical transmission response of nanohole arrays has been recorded by focused and collimated beam transmission spect…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanowire Synthesis and Applications