Materials Literature
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Some experimental results on the macroscopic spreading of hanging and sessile drops on smooth surfaces are presented. The results for sessile drops nicely corroborate the main aspects of the spreading theory of de Gennes and Joanny. However, it is shown that one assumption of the theory, namely the retainment of a sel…
Tetragonal‐to‐rhombohedral stress‐induced phase transformation was studied by X‐ray diffraction on the ground surfaces of tetragonal zirconia polycrystals and partially stabilized zirconia containing 2.0 to 5.0 mol% Y 2 O 3 prepared by hot isostatic pressing. The rhombohedral phase increased with Y 2 O 3 content and a…
The bond energies of ennea- and octa-aqua-coordinated polyhedra of lanthanoid ions have been calculated on the electrostatic model. Sums of coordination bond energies and Born hydration enthalpies of the aqua complexes predict an exclusive stabilization of the enneahydrate regardless of whether the central metal ion i…
The speed and precision of salt fog contamination testing of insulators is improved using stepwise voltage application to give numerous flashovers in a single test. A similar technique for the clean fog method, which gives comparable results to conventional tests at constant voltage, is proposed. Valuable information…
The validity of using artificial seawater and seawater transported to the laboratory to predict the performance of stainless steel alloys in natural seawater service has been investigated. Crevice corrosion tests on a range of alloys showed damage to be dramatically less in artificial seawater than natural seawater. T…
A scenario is presented to explain the Vogel-Fulcher "law" which describes the slowing down of relaxation processes associated with many glasses: ${\ensuremath{\tau}}^{\ensuremath{-}1}=\ensuremath{\tau}_{0}^{\ensuremath{-}1}\mathrm{exp}[\frac{\ensuremath{-}E}{(T\ensuremath{-}{T}_{0})}]$. It assumes that relaxation pro…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of electron-withdrawing groups on carbonyl O-oxides. Trifluoroacetophenone O-oxide and hexafluoroacetone O-oxideWolfram W. SanderCite this: J. Org. Chem. 1988, 53, 1, 121–126Publication Date (Print):January 1, 1988Publication History Published online1 May 2002Publish…
Submicron powders of SiC were synthesized at different temperatures (1700°-2000°C) by reaction of a mixed powder of carbon and silicon dioxide prepared by the spray thermal decomposition method. The structural and quantitative analyses of the synthesized SiC were carried out using the Rietveld method on the basis of t…
The intergranular fracture (IGF) in high purity molybdenum and high purity iron are discussed together with the effects of interstitial and substitutional solutes on it.Recrystallized molybdenum is inherently susceptible to IGF. Purification does not improve it. Grain boundary segregation of carbon increases the grain…
Description This volume continues to document progress in composite materials testing. Twenty-seven papers represent the following areas: Analysis; Impact and Compression; Materials Characterization; Failure Mechanisms; Nondestructive Evaluation; and Filament Wound and Woven Composites.
This book considers the technological processes which are involved in the manufacture of coated materials, substances which play an important role in modern industry. The quality of textile materials depends on the fibrous component and fabric manufacturing method and most importantly on the preparation applied during…
Three new pregnane glycosides, named periplocosides A, B and C, have been isolated from the antitumor fraction, which was obtained by subjecting the CHCl3 extract of Periploca sepium to column chromatography over silica gel and eluting with CHCl3-MeOh (10 : 1). Their structures were established by various nuclear magn…
The solubility of hydrogen in liquid pure aluminium has been redetermined for temperatures from 943 to 1123 K and pressures from 67 to 113 kPa (0·66 to 1·12 atm), using an appropriate version of Sieverts' method. The results fit the Van't Hoff isobar and Sieverts' isotherm. Recommended values for the solubility (S) ar…
It was found that pigeon lysozyme binds one calcium ion, as does equine lysozyme. The protein was eluted with equimolar calcium ions from a Bio-Gel P-60 column. The binding constants of equine and pigeon lysozymes were determined to be 2 x 10(6) and 1.6 x 10(7) M-1, respectively, in 0.1 M KCl at pH 7.1 and 20 degrees…
Research Article| April 01, 1988 Diatoms in Antarctic ice cores: Some implications for the glacial history of Antarctica L. H. Burckle; L. H. Burckle 1Lamont-Doherty Geological Observatory, Palisades, New York 10964 Search for other works by this author on: GSW Google Scholar R. I. Gayley; R. I. Gayley 2Department of…
Long-chain conjugated polymers are described which have electronic transitions with energies of approximately 2–4 eV. Excitation of these transitions by electromagnetic radiation results in strong absorption bands in the visible region of the spectrum and hence a coloured appearance to the polymer. It is shown that th…
The hydrodynamic aspects of lubrication by the smectic A liquid crystal octylcyanobiphenyl (8CB) were investigated in a thrust bearing and in the concentrated ball-on-flat contact. Both bearings were run with a Newtonian mineral basestock for comparison and performed as expected; friction followed the Stribeck curve i…
Abstract The title compound crystallizes in the triclinic space group P1̅ with lattice parameters a = 13.129 Å, b = 14.156 Å, c = 14.843 Å and α= 88.34°, β = 74.43°, γ = 70.86°. The polyanion evidently is the predominant species in pseudometatungstate phases the exact composition of which has not previously been deter…
The effects of conducting particles in gas-insulated switchgear (GIS) on insulation performance were investigated. The objective was to recognise the relationship between the length of conducting particles and AC impulse flashover voltages. The data showed that the minimum harmful length of conducting particles at var…
Abstract The properties of a new immobilized glucose isomerase, produced by a selected strain of Streptomyces murinus , are described. The major advantages of the new immobilized enzyme are a productivity of more than 10,000 kg syrup dry substance per kg enzyme under optimal industrial conditions, increased activity a…