Materials Literature
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This work introduces a tutorial series on material failure mechanisms and damage models to familiarize nonspecialists with the fundamentals of failure mechanisms in engineering assemblies. Since failure is a complicated concept, four simple conceptual models for failure are discussed: stress-strength, damage-endurance…
Since the discovery of long-lived oligomeric silver clusters in aqueous polyanion solutions it has become possible to investigate the chemical reactivity of silver aggregates over a wide size range, especially in the range where the transition from the atom to the metal takes place.Both oligomeric and metallic particl…
STRUCTURE AND COMPOSITION OF ELECTRODES AND ELECTROLYTES: Techniques for the Study of Solid Ionic Conductors Ellipsometry as an In Situ Probe for Study of Electrode Processes In Situ Characterization of Electrode Processes by Photothermal Deflection Spectroscopy Surface X-Ray Absorption Spectroscopy, EXAFS and NEXAFS…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and ultrastructural studies of styrene-divinylbenzene Polyhipe polymersP. Hainey, I. M. Huxham, B. Rowatt, D. C. Sherrington, and L. TetleyCite this: Macromolecules 1991, 24, 1, 117–121Publication Date (Print):January 1, 1991Publication History Published online1 Ma…
The structure of the cobalt present in carbon-supported Co and Co-Mo sulfide catalysts was studied by means of X-ray\nabsorption spectroscopy at the Co K-edge and by X-ray photoelectron spectroscopy (XPS). Thiophene hydrodesulfurization\nactivities were used to measure the catalytic properties of these catalysts. By c…
Manganese(II)-N,N'-dipyridoxylethylenediamine-N,N'-diacetate-5,5'-bis (phosphate) (MnDPDP) is a paramagnetic complex designed for use as a hepatobiliary agent. The T1 relaxivity of MnDPDP (2.8 [mmol/L]-1.sec-1 in aqueous solution) was similar to that of gadolinium diethylenetriaminepentaacetic acid (DTPA) (4.5 [mmol/L…
Near the sol-gel transition, gelling systems exhibit an extremely slow relaxation of thermally driven density fluctuations. We have made a detailed quasielastic light scattering study of the decay of density fluctuations in reacting silica sol-gels in the pre- and post-gel regimes, and at the gel point. In the pre-gel…
Abstract The harmonic balance method is a technique for the numerical solution of nonlinear analog circuits operating in a periodic, or quasi‐periodic, steady‐state regime. The method can be used to efficiently derive the continuous‐wave response of numerous nonlinear microwave components including amplifiers, mixers,…
An approach to molecular wires based on quasi-one-dimensional linearly conjugated poly-porphyrin systems is outlined and a rationally designed synthesis of the tetrakisporphyrin 9, a strand some 65 Å in length, via the bis(porphyrin)tetraone 2 is described.
The author presents a bibliography and survey of the literature concerned with theory and measurement of the stochastic behavior of pulsating partial-discharge (PD) phenomena that can occur when insulation is subjected to electrical stress. The types of PD phenomena considered include AC and DC generated electron aval…
Erbium-doped fiber has become the central component of nearly all optical amplifiers. Applications reported include repeaters, power amplifiers, preamplifiers, and distributed amplifiers. To date, nearly all the fiber used in these devices has been silica based and fabricated by variations on the major telecommunicati…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoinduced electron transfer in the solid state: rate vs. free energy dependence in fixed-distance porphyrin-acceptor moleculesGeorge L. Gaines III, Michael P. O'Neil, Walter A. Svec, Mark P. Niemczyk, and Michael R. WasielewskiCite this: J. Am. Chem. Soc. 1991, 113, 2, 71…
The journal consistently attracts the most important and highly innovative papers from the current research; our commitment to rapid publication ensures that these are published in the fastest time possible. In addition to primary papers from world-renowned experts, the Journal contains authoritative reviews that summ…
Thermodynamics and phase diagrams of materials, A.D.Pelton diffusion in crystalline solids, G.E.Murch statistical theories of phase transitions, K.Binder homogeneous second phase precipitation, R.Wagner transformations involving interfacial diffusion, G.R.Purdy diffusionless transformations, L.Delaey spinodal decompos…
Polyhydroxyalkanoic acids (PHA) are water-insoluble polyesters of alkanoic acids containing a hydroxyl group as at least one functional group in addition to the carboxy group, and possess the general formula shown in Fig. 1. Although some of these polymers are also available from chemical synthesis, many of them are s…
Chirality has become arguably the most important and complex topic of research in liquid crystals today. The reduced symmetry in these organized phases leads to a variety of novel phase structures, properties, and applications. Molecular asymmetry imparts form chirality to liquid-crystalline phases, which is manifeste…
The free-base octabromotetraphenylporphyrin (H2OBP) has been prepared by a novel bromination reaction of (meso-tetraphenylporphyrinato)copper(II). The metal [V(IV)O, Co(II), Ni(II), Cu(II), Zn(II), Pd(II), Ag(II), Pt(II)] derivatives exhibit interesting electronic spectral features and electrochemical redox properties…
The aim of the present study was to investigate whether angiotensin II, by increasing extracellular matrix synthesis, contributed to the vascular wall thickening observed in hypertension. Thus, we examined the direct effects of angiotensin II on collagen and fibronectin synthesis in cultured rat vascular smooth muscle…
The structure of pressure-densified vitreous ${\mathrm{SiO}}_{2}$ has been investigated using neutron-diffraction and molecular-dynamics techniques. After compression to 16 GPa at room temperature, recovered samples have densities 20% higher than normal vitreous ${\mathrm{SiO}}_{2}$ and show substantial changes in the…
The sol–gel process enables on to prepare oxide glasses at room temperature with little or no heating. By using this method, it is possible to encapsulate a wide variety of organic and organometallic molecules in the inorganic matrix. Studies of this new type of organic/inorganic composite have evolved towards two dif…