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Valence instability and photochemical reaction at surface of strongly correlated MgTi2O4

H. Fujiwara、Yusuke Ishige、T. Mizokawa 等 6 位作者2013-08-01APL Materials

We have studied surface electronic structure and light illumination effect of spinel-type MgTi2O4 with Ti3+(d1) electronic configuration. Ti4+ species are found at surfaces of MgTi2O4, which show photo-induced effect similar to the Ti4+-oxide semiconductors with surface depletion layer. MgTi2O4 with the surface Ti4+ s…

Luminescence Properties of Advanced MaterialsFerroelectric and Piezoelectric MaterialsElectronic and Structural Properties of Oxides

Paramagnetism in Metal-Metal Bonded Paddlewheel Complexes

Elizabeth A. Hillard2013-08-01Current Inorganic Chemistry

The pairing of metal-based electrons to form metal-metal bonds in paddlewheel complexes would suggest that this chemistry is limited to diamagnetic complexes. However, a wide variety of paramagnetic complexes exist in this geometry. Whether obtained by oxidation or reduction of the divalent dinuclear species, as a res…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesSynthesis and Properties of Aromatic Compounds

The effect of temperature and oxygen partial pressure on the reduction mechanism in the Pr2CuO4/Ce0.9Gd0.1O1.95 system

Н. В. Лысков、Г. Н. Мазо、Л. С. Леонова 等 6 位作者2013-08-01Russian Journal of Electrochemistry

The electrochemical behavior of a porous electrode based on Pr 2 CuO 4 (PCO) screen printed on the surface of Ce 0.9 Gd 0.1 O 1.95 (CGO) solid electrolyte is studied by impedance spectroscopy. The rate-determining stages of the oxygen reduction reaction at the PCO/CGO interface are found for the oxygen partial pressur…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Interlayer water molecules in organocation-exchanged vermiculite and montmorillonite: A case study of tetramethylammonium

Rubén Martos-Villa、Stephen Guggenheim、C. Ignacio Sainz‐Díaz2013-08-01American Mineralogist

Organoclays, unlike natural clays with inorganic cations that often have a hydration shell of H 2 O molecules, are organophylic and less adsorptive of H 2 O. These clays, therefore, are potentially important to remove organic contaminants from water; they are of great interest in industry for herbicide manufacture and…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Electric field distribution around the chain of composite nanoparticles in ferrofluids

Chunzhen Fan、Junqiao Wang、Yongguang Cheng 等 6 位作者2013-08-01Chinese Physics B

Composite nanoparticles (NPs) have the ability of combining materials with different properties together, thus receiving extensive attention in many fields. Here we theoretically investigate the electric field distribution around core/shell NPs (a type of composite NPs) in ferrofluids under the influence of an externa…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCharacterization and Applications of Magnetic Nanoparticles

Drug Delivery System in Nano Greens

M. Padmavathi2013-08-01International Journal of Herbal Medicine

Herbal medicines have been widely used all over the world since ancient times and have been recognized by physicians and patients for their better therapeutic value as they have fewer adverse effects as compared with modern medicines. Herbal therapeutics can be achieved by Drug Delivery systems. This herbal treatment…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

The Investigation of Colored Normal-Temperature Asphalt Concrete

Chou Fu Liang、Hung Yu Wang、Jun Kai Lu 等 4 位作者2013-08-01Advanced materials research

Colored asphalt concrete refers to asphalt concrete pavement that pigments are added in or colorful stones are mixed with, pigments added de-colored petroleum resin asphalt pavement, or modified asphalt pavement with water permeability sprayed with colorful resin coating. It is indispensable to develop traffic safety…

Asphalt Pavement Performance EvaluationMaterial Selection and Properties

High sensitive biosensor based on aSRR and high-impedance microstrip line

Jinhu Zhou、Peng Jia、Yanqin Zhang 等 4 位作者2013-08-01OpenAlex

In this paper, biosensor based on an asymmetric single split resonator (SRR) which is excited by a high-impedance microstrip line at microwave frequencies is presented. According to the previously obtained results, good resonance peaks have been demonstrated in the symmetric SRR, but the Q value of SRR is still lower.…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAcoustic Wave Resonator Technologies

Calculation of Thermal Residual Stresses in Multilayer Composite Materials

S. I. Petrushin2013-08-01Applied Mechanics and Materials

Determination of thermal residual stresses induced by manufacturing technology heating on the layer interfaces in multilayer composite materials has been considered. The fracture elimination condition has been proposed together with application aspects.

Industrial Engineering and TechnologiesMaterial Properties and ApplicationsEngineering and Environmental Studies

Chemical Composition Distribution and Temperature Rising Elution Fractionation of Linear Olefin Block Copolymers

Siripon Anantawaraskul、Suwicha Sottesakul、Ekaphol Siriwongsarn 等 4 位作者2013-08-01Macromolecular Symposia

Summary Linear olefin block copolymers (OBCs) have statistical multi‐block structures and exhibit unique properties that are different from those of other polyolefin elastomers. In this work, the microstructure details of OBCs were investigated using a Monte Carlo model. Theoretical TREF profiles for these materials w…

Organometallic Complex Synthesis and CatalysisPolymer crystallization and propertiesbiodegradable polymer synthesis and properties

Note: A multifunctional electrospinning system for manufacturing diversified nanofibrous structures

Changhai Ru、Feilong Wang、Cuicui Ge 等 4 位作者2013-08-01Review of Scientific Instruments

A multifunctional electrospinning system has been developed to fabricate diversified nanofibrous structures. It consists of a high voltage power supply, a syringe pump, and a cage like collector that are dominated via the controller by setting parameters from a touch screen. As the key component, speed, and diameter o…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Binding of pro-migratory serum factors to electrospun PLLA nano-fibers

Saman Eghtesad、Maria V. Nurminskaya2013-08-01Journal of Biomaterials Science Polymer Edition

Architecture of the poly(l-lactic acid) (PLLA) scaffolds is known to affect protein affinity and binding strength. Here, we demonstrate that nanofibrous electrospun PLLA scaffolds reversibly absorb the pro-migratory serum factors that stimulate migration of vascular smooth muscle via an NFkB-dependent mechanism. Furth…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsTissue Engineering and Regenerative Medicine

Synthesis, characterization and hydrogen sorption studies of mixed sodium‐potassium alanate

Ashish Bhatnagar、Sunita K. Pandey、Rohit R. Shahi 等 6 位作者2013-08-01Crystal Research and Technology

Abstract The aim of the present investigation is to synthesize mixed sodium potassium alanate (K 2 NaAlH 6 ) and to explore its hydrogen sorption characteristics. K 2 NaAlH 6 is synthesized through ball milling of KH and NaAlH 4 in the molar ratio 2:1 under hydrogen pressure of 10 bar. The temperature programmed desor…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

A Density Functional Theory Study of Half-Metallic Ferromagnets (HMFs) Behavior in Co2YSb (Y=Sc, Ti)

P. Raics、R. K. Thapa2013-08-01Chinese Journal of Physics

Based on the density functional theory (DFT) calculations, the electronic and magnetic properties of Heusler compounds Co2YSb (Y = Sc, Ti) were investigated using the generalized gradient approximation (GGA). Amongst the systems under investigation Co2ScSb gives 100% spin polarization at EF. Co2ScSb is the most stable…

Intermetallics and Advanced Alloy PropertiesBoron and Carbon Nanomaterials ResearchHeusler alloys: electronic and magnetic properties

Oxygen Ion Implantation Enhanced Silicon-Vacancy Photoluminescence and n-Type Conductivity of Ultrananocrystalline Diamond Films

Xiaojun Hu、Nian Li2013-08-01Chinese Physics Letters

We report the enhanced silicon-vacancy (Si-V) photoluminescence (PL) intensity and n-type conductivity of ultrananocrystalline diamond (UNCD) films by oxygen ion (O + ) implantation. With O + dose increasing from 10 14 to 10 15 cm −2 , the PL intensity and n-type conductivity significantly increase by 6 and 45 times,…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Photoemission study of iron-based superconductor

Zhonghao Liu、Yipeng Cai、Yurou Zhao 等 5 位作者2013-08-01Chinese Physics B

The iron-based superconductivity (IBSC) is a great challenge in correlated system. Angle-resolved photoemission spectroscopy (ARPES) provides electronic structure of the IBSCs, the pairing strength, and the order parameter symmetry. Here, we briefly review the recent progress in IBSCs and focus on the results from ARP…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Luminescence properties of ZnS:Cu, Eu semiconductor nanocrystals synthesized by a hydrothermal process

Mei Xin、Lizhong Hu2013-08-01Chinese Physics B

ZnS:Cu, Eu nanocrystals with an average diameter of ∼ 80 nm are synthesized using a hydrothermal approach at 200 °C. The photoluminescence (PL) properties of the ZnS:Cu, Eu nanocrystals before and after annealing, as well as the doping form of Eu, are studied. The as-synthesized samples are characterized by X-ray diff…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications