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Theoretical investigation of the influence of space charges on ferroelectric properties of PbZrTiO3 thin film capacitor

L. Baudry1999-07-15Journal of Applied Physics

During ion etching (IE) processes used for making a Pt electrode in the fabrication of ferroelectric capacitors, the film is exposed to radiation and energetic ion bombardment. The influence of such processes on polarization-electric field characteristics of lead zirconate titanate thin film capacitor has been reporte…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Calculation of low-energy-electron lifetimes

E. Zarate、P. Apell、P. M. Échenique1999-07-15Physical review. B, Condensed matter

The effect of the density of states on the lifetime of low-energy electrons in metals has been studied using a golden rule approach. Simple approximations to the real density of states of metals have been used allowing analytical results, which show that the free-electron scaling $(E\ensuremath{-}{E}_{F}{)}^{\ensurema…

Advanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Sensitized Ho3+ up-conversion luminescence in Nd3+–Yb3+–Ho3+ co-doped ZrF4-based glass

Jianbei Qiu、Masanori Shojiya、Yuki KAWAMOTO1999-07-15Journal of Applied Physics

As previously reported, a selectively strong green emission due to the Ho3+: (5F4, 5S2)→5I8 transitions is observed in Nd3+–Ho3+ co-doped ZrF4-based fluoride glasses under 800 nm excitation. As an attempt to more enhance Ho3+ up-conversion luminescences in the Nd3+–Ho3+ co-doped ZrF4-based glasses, Yb3+ ions were adde…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Polarization-dependent resonant-x-ray diffraction in charge- and orbital-ordering phase ofNd1/2Sr1/2MnO3

K. Nakamura、T. Arima、Atsushi Nakazawa 等 5 位作者1999-07-15Physical review. B, Condensed matter

A study of resonant-x-ray scattering in a charge-ordered perovskite manganese oxide ${\mathrm{Nd}}_{1/2}{\mathrm{Sr}}_{1/2}{\mathrm{MnO}}_{3}$ was performed. Dipole-resonant superlattice reflections originating from the orderings of the charge and orbital with ${Q}_{\mathrm{charge}}=(0,1,0)$ and ${Q}_{\mathrm{orbital}…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Finite field treatment of vibrational polarizabilities and hyperpolarizabilities: On the role of the Eckart conditions, their implementation, and their use in characterizing key vibrations

Josep M. Luis、Miquel Duran、José L. Andrés 等 5 位作者1999-07-15The Journal of Chemical Physics

In the finite field (FF) treatment of vibrational polarizabilities and hyperpolarizabilities, the field-free Eckart conditions must be enforced in order to prevent molecular reorientation during geometry optimization. These conditions are implemented for the first time. Our procedure facilities identification of field…

Nonlinear Optical Materials ResearchAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Direct Observation of Orbital Order in Manganites by MEM Charge-Density Study

Masaki Takata、Eiji Nishibori、Kenichi Kato 等 5 位作者1999-07-15Journal of the Physical Society of Japan

We have investigated the charge-density distribution of an antiferromagnetic bi-layered manganite, NdSr 2 Mn 2 O 7 , by the maximum entropy method (MEM) using the synchrotron X-ray powder data. The magnetic structure below T N =150 K is known to be a layered-type (A-type). We have found a significant change of the ele…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Modeling of the fluid-phase interfacial effect on the growth morphology of crystals

Xiangyang Liu1999-07-15Physical review. B, Condensed matter

The interfacial effect of the fluid phase on the growth morphology of crystals is very difficult to describe. This is particularly so for crystallization systems with complicated growth units. Based on newly developed morphological theories, a new approach, the so-called interfacial structure (IS) analysis is develope…

Solidification and crystal growth phenomenaCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

HfTe5andZrTe5: Possible polaronic conductors

Mark Rubinstein1999-07-15Physical review. B, Condensed matter

The interpretation of the published electrical transport data of the group IVB transition-metal pentatellurides, ${\mathrm{ZrTe}}_{5}$ and ${\mathrm{HfTe}}_{5},$ have been reconsidered. These materials evince a strong resistivity peak at a temperature where the Hall effect and the thermopower manifest a change in sign…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsInorganic Chemistry and Materials

Optical transitions of paramagnetic Ge sites created by x-ray irradiation of oxygen-defect-free Ge-dopedSiO2by the sol-gel method

N. Chiodini、F. Meinardi、Franca Morazzoni 等 5 位作者1999-07-15Physical review. B, Condensed matter

Optical transitions of radiation-induced paramagnetic Ge centers have been investigated in Ge-doped ${\mathrm{SiO}}_{2}$ samples containing a negligible amount of native oxygen coordination defects, whose optical absorption usually dominates the UV spectral range. The analysis of optical and electron paramagnetic reso…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhotochemistry and Electron Transfer Studies

Chemical trapping experiments support a cation-radical mechanism for the oxidative polymerization of aniline

Yong Ding、Anne Buyle Padías、H. K. Hall1999-07-15Journal of Polymer Science Part A Polymer Chemistry

The oxidative polymerization of aniline in aqueous acidic solution was carried out in the presence of a variety of organic compounds as potential traps for postulated intermediates. The polymerization was inhibited by hindered phenols and electron-rich alkenes, traps for cation-radicals. However, polyaniline was still…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Correlation between rare-earth oscillator strengths and rare-earth–valence-band interactions in neodymium-dopedYMO4(M=V,P, As),Y3Al5O12,andLiYF4matrices

O. Guillot-Noël、B. Bellamy、Bruno Viana 等 4 位作者1999-07-15Physical review. B, Condensed matter

${\mathrm{Nd}}^{3+}{:\mathrm{Y}\mathrm{V}\mathrm{O}}_{4}$ is one of the more promising laser hosts for micro and diode-pumped solid-state lasers. At room temperature, ${\mathrm{Nd}}^{3+}$ ions in this matrix exhibit strong absorption cross sections sixfold higher than in ${\mathrm{Y}}_{3}{\mathrm{Al}}_{5}{\mathrm{O}}_…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Size-dependent dynamics of coherent acoustic phonons in nanocrystal quantum dots

Giulio Cerullo、S. De Silvestri、Uri Banin1999-07-15Physical review. B, Condensed matter

Confined acoustic phonons in InAs nanocrystals are observed in the time domain by femtosecond pump-probe spectroscopy. The size dependence of both frequency and damping time is investigated for InAs. The frequency of the discrete modes varies between 18 and 30 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ for a nanocryst…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNear-Field Optical Microscopy

Electronic structure of a grain-boundary model inSrTiO3

Shang‐Di Mo、W. Y. Ching、Matthew F. Chisholm 等 4 位作者1999-07-15Physical review. B, Condensed matter

It is known that grain boundaries (GB's) in strontium titanate $({\mathrm{SrTiO}}_{3})$ play an important and often a controlling role in determining the material's electrical properties. To understand how their electronic structures are related to the GB structures, we have examined two structure models of the \ensur…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Beneficial effect of triphenylphosphine on the bulk polymerization of L , L ‐lactide promoted by 2‐ethylhexanoic acid tin (II) salt

Philippe Degée、Philippe Dúbois、Svein Jacobsen 等 5 位作者1999-07-15Journal of Polymer Science Part A Polymer Chemistry

The ring-opening polymerization of L,L-lactide has been studied in bulk using 2-ethylhexanoic acid tin (II) salt, Sn(Oct)2, as a catalyst over a wide range of temperature and monomer to Sn(Oct)2 molar ratio. Although Sn(Oct)2 was known to initiate a fast polymerization, it is reported now that some Lewis bases, partic…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Energy transfer with migration. Generalization of the Yokota–Tanimoto model for any kind of multipole interaction

Inocencio R. Martín、V.D. Rodrı́guez、Ulises R. Rodríguez‐Mendoza 等 6 位作者1999-07-15The Journal of Chemical Physics

The dynamics of luminescence decay is analyzed within the general scenario of randomly distributed ions with whatever multipole interaction, taking into account energy transfer and migration processes among them. By applying Padé approximants to the Allinger and Blumen expression for the excited state population, a si…

Glass properties and applicationsQuantum optics and atomic interactionsRandom lasers and scattering media

Ab initiocalculation of titanium silicon carbide

Zhimei Sun、Yanchun Zhou1999-07-15Physical review. B, Condensed matter

The electronic structure and properties of the layered ceramic ${\mathrm{Ti}}_{3}{\mathrm{SiC}}_{2}$ have been examined by ab initio linear combination of atomic orbital calculations. With the calculated results we predict that the electronic conductivity of ${\mathrm{Ti}}_{3}{\mathrm{SiC}}_{2}$ is metallic and anisot…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Temperature and field dependence of microwave losses in manganite powders

V. V. Srinivasu、S. E. Lofland、S.M. Bhagat 等 5 位作者1999-07-15Journal of Applied Physics

We report systematic measurements of the temperature and field dependence of microwave losses in micron-size powders (∼3 μm) of the manganites Nd0.7Sr0.3MnO3, La0.7Ca0.3MnO3, La0.8Ba0.2MnO3, and La1.4Ca1.6Mn2O7. We fully confirm previous findings of a large increase in zero-field absorption, in La0.7Ba0.3MnO3 and La0.…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsMagnetic Properties of Alloys

Variable range hopping conduction in bulk samples composed of single-walled carbon nanotubes

Yositaka Yosida、I. Oguro1999-07-15Journal of Applied Physics

An experimental study of the electrical transport phenomena in magnetic fields H up to 15 T in pressed samples of a porous system composed of single-walled carbon nanotubes in the temperature range 1.39 K <T<300 K is reported. Below 60 K, the exp[1/T1/4] temperature dependence of the direct current elect…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Effect of hydrogen partial pressure on optoelectronic properties of indium tin oxide thin films deposited by radio frequency magnetron sputtering method

Keran Zhang、Furong Zhu、C. H. A. Huan 等 4 位作者1999-07-15Journal of Applied Physics

In this study, indium tin oxide (ITO) films were made from an oxidized target with In2O3 and SnO2 in a weight proportion of 9:1 using the radio frequency magnetron sputtering method. Hydrogen was added to the gas mixture during the preparation of the ITO films. In order to study the effect of hydrogen partial pressure…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsThin-Film Transistor Technologies

The efficient export of NADP‐containing glucose‐fructose oxidoreductase to the periplasm of Zymomonas mobilis depends both on an intact twin‐arginine motif in the signal peptide and on the generation of a structural export signal induced by cofactor binding

Dirk Halbig、Thomas Wiegert、Natascha Blaudeck 等 5 位作者1999-07-15European Journal of Biochemistry

The periplasmic, NADP-containing glucose-fructose oxidoreductase of the gram-negative bacterium Zymomonas mobilis belongs to a class of redox cofactor-dependent enzymes which are exported with the aid of a signal peptide containing a so-called twin-arginine motif. In this paper we show that the replacement of one or b…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionPorphyrin Metabolism and Disorders