Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular-Scale Structure of the Cation Modified Muscovite Mica Basal PlaneS. Nishimura, S. Biggs, P. J. Scales, T. W. Healy, K. Tsunematsu, and T. TateyamaCite this: Langmuir 1994, 10, 12, 4554–4559Publication Date (Print):December 1, 1994Publication History Published onlin…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAutophobic Pinning of Drops of Alkanethiols on GoldHans A. Biebuyck and George M. WhitesidesCite this: Langmuir 1994, 10, 12, 4581–4587Publication Date (Print):December 1, 1994Publication History Published online1 May 2002Published inissue 1 December 1994https://pubs.acs.org…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic Distinction between Porphyrins and Tetraazaporphyrins. Insights from X-Ray Photoelectron Spectra of Free Base Porphyrin, Porphyrazine, and Phthalocyanine LigandsAbhik Ghosh, Jeffrey Fitzgerald, Paul G. Gassman, and Jan AlmlofCite this: Inorg. Chem. 1994, 33, 26, 6…
Detailed, ab initio quality electron density calculations are reported for the elements of the tertiary structure of bovine insulin, a protein containing 773 atoms in 51 residues. The high resolution 3D images of the molecular body and tertiary structure elements of insulin are computed using the new Molecular Electro…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal Structure and Magnetic Properties of [{Ni2(dpt)2(.mu.-ox)(.mu.-N3)}n](PF6)n: A New Strategy To Obtain S = 1 Alternating ChainsAlbert Escuer, Ramon Vicente, Xavier Solans, and Merce Font-BardiaCite this: Inorg. Chem. 1994, 33, 26, 6007–6011Publication Date (Print):Dec…
A series of new ‘inclusion’ materials based on tetra-4-methoxyphenyl, tetra-4-hydroxyphenyl and tetra-4-chlorophenyl derivatives of the metalloporphyrin system, in combination with a wide variety of guest molecules and ligands, have been prepared, and their structural systematics analysed. Crystallographic investigati…
Excitation of the transition $^{3}$${\mathit{H}}_{4}$${\ensuremath{\rightarrow}}^{1}$${\mathit{D}}_{2}$ in a ${\mathrm{Pr}}^{3+}$-doped fluoroindate glass at \ensuremath{\sim}588 nm results in efficient blue emission at \ensuremath{\sim}480 nm which is ascribed to the $^{3}$${\mathit{P}}_{0}$${\ensuremath{\rightarrow}…
The analysis of gratings of arbitrary depth, profile, and permittivity is conducted by cutting the modulated region into different slices for which the differential theory of gratings is able to compute the diffracted field for both TE and TM polarization without numerical instabilities. The use of a suitable transiti…
A recent method for treating colloid-polymer mixtures is extended to study the phase behaviour of hard-sphere mixtures. It is shown that, for small size ratios ξ r 2 / r 1 , the addition of small spheres (radius r 2 ) to a system of large spheres (radius r 1 ) induces bulk phase separation into coexisting crystal and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExchange Interaction in Metal-Radical Systems: Chloro(meso-tetraphenylporphyrinato)chromium(III)'s and (Hexafluoroacetylacetonato)manganese(II) Ligated with 3- and 4-(N-Oxy-N-tert-butylamino)pyridinesMakoto Kitano, Yoichiro Ishimaru, Katsuya Inoue, Noboru Koga, and Hiizu Iwa…
Single crystals of ${\mathrm{Cs}}_{3}$${\mathrm{Lu}}_{2}$${\mathrm{Br}}_{9}$:1%${\mathrm{Er}}^{3+}$ were grown using the Bridgman technique. The low phonon energy of \ensuremath{\le}190 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ strongly suppresses multiphonon relaxation in this host. For a series of excited states ra…
Previously, twin systems of [111] were reported in L1[sub 0] TiAl. No pseudo twinning was observed in TiAl. This is probably due to the fact that the pseudo twins, [111], [211] or [121], result in L1[sub 1] like structure which has a higher energy in TiAl. Nevertheless, it was suggested that the pseudo-twinning might…
The incommensurate room-temperature (RT) structure of NbTe 4 undergoes a phase transition into an intermediate incommensurate low-temperature (LT) phase at low temperatures, before the lock-in transition into the commensurate low-temperature (C) phase occurs at ca 50 K. In an X-ray experiment, the additional satellite…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLigand Binding to Four-Atom-Linked Capped PorphyrinsNilkamal Bag, Tammy M. Grogan, Douglas Magde, Carla Slebodnick, Martin R. Johnson, and James A. IbersCite this: J. Am. Chem. Soc. 1994, 116, 26, 11833–11839Publication Date (Print):December 1, 1994Publication History Publis…
Abstract : This study was carried out to investigate the elevated temperature behavior of the SiC-MAS5 cross- ply (O/9O)4S ceramic matrix composite manufactured by Corning Inc. to fatigue with loading waveforms that combine the characteristics of stress rupture and high cycle fatigue. The test results were compiled in…
Abstract Proton spin diffusion measurements were made using the Goldman—Shen technique of bisphenol‐A polycarbonate containing 10 wt% trioctyl phosphate at temperatures below the glass transition temperature. The proton lineshapes reveal the existence of dynamic heterogeneities in the glass and spin diffusion can be o…
Alkalimetric and acidimetric titrations of montmorillonite suspensions were performed at ionic strengths varying from 0.005 to 0.5 M (NaNO<sub>3</sub>). Deprotonation of surface hydroxyl groups exposed at the edge sites of montmorillonite platelets causes an overall negative charge in the alkaline pH range. The PZNPC…
Abstract Neutron powder diffraction data of α -MnMoO 4 (space group C 2/ m ) are presented, which were collected with the diffractometer DN5 at the CEN Grenoble at T = 50 K and between 13 K and 5.5 K. Below T = 15.3 K, α -MnMoO 4 is antiferromagnetically ordered. The translational symmetry of the magnetic structure is…
The temperature dependence of the lattice constant for the parent phase in metallic sodium, which has a body-centred cubic (b.c.c.) structure, has been measured by an X-ray single-crystal diffraction method over a range of 20 to 293 K. An abnormal change of the lattice constant at around 40 K is shown, which is attrib…
Abstract Crosslinked cationic latexes based on polystyrene, poly[styrene‐ co ‐(methyl methacrylate)] and poly(methyl methacrylate) were prepared by an emulsion polymerization process using 2 mol‐% of a quaternary ammonium surfactant monomer. Phthalocyaninatocobalt(II)tetrasulfonate (CoPcTs) bound to these latexes were…