Materials Literature
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OBJECT: Clinical application of the convection-enhanced delivery (CED) technique is currently limited by low infusion speed and reflux of the delivered agent. The authors developed and evaluated a new step-design cannula to overcome present limitations and to introduce a rapid, reflux-free CED method for future clinic…
[reaction: see text] Three organoboron compounds are shown to be two-photon fluorescent sensors for fluoride anion with high sensitivity and selectivity. The recognition mechanism is attributed to the unique steric structure of the bulky dimesitylboryl group and the Lewis acid-base interaction between trivalent boron…
We report for the first time that boron nitride nanotubes (BNNTs) may be dissolved in organic solvents by wrapping them with a polymer. Transmission electron microscopy and cathodoluminescence studies indicate the strong pi-pi interactions between BNNTs and the polymer. A band gap ranging from 5.2 to 5.5 eV was docume…
Nonspecific binding is a frequently encountered problem with fluorescent labeling of tissue cultures when labeled with quantum dots. In these studies various cell lines were examined for nonspecific binding. Evidence suggests that nonspecific binding is related to cell type and may be significantly reduced by function…
Composite materials consisting of polyaniline nanofibers decorated with noble-metal (Ag or Au) nanoparticles were synthesized with γ radiolysis. Aqueous solutions of aniline, a free-radical oxidant, and/or a metal salt were irradiated with γ rays. Exposure of the solutions to γ rays caused aniline to polymerize as ver…
Twenty‐five years of diesel particulate filter (DPF) developments have shown that ceramic materials are well‐suited candidates to fulfill the harsh requirements of exhaust after treatment. The introduction of DPF in passenger cars in Europe in 2000 was a real breakthrough from both a scientific and a commercial point…
An oxygen-assisted hydrocarbon chemical vapor deposition method is developed to afford large-scale, highly reproducible, ultra-high-yield growth of vertical single-walled carbon nanotubes (V-SWNTs). It is revealed that reactive hydrogen species, inevitable in hydrocarbon-based growth, are damaging to the formation of…
Fundamental properties of dipole transmitting antennas formed by carbon nanotubes are investigated. Since carbon nanotubes can be grown to centimeter lengths, and since they can be metallic, the properties of carbon nanotubes as antenna elements are of fundamental interest. In this paper, dipole carbon nanotube antenn…
An efficient pH-responsive carrier system has been constructed by oppositely charged ionic interaction between carboxylic acid modified SBA-15 silica rods and polyelectrolyte. Active molecules such as vancomycin can be stored and released from the pore voids of SBA-15 by changing pH values at will. The amount of vanco…
This review is devoted to the most recent developments (2000–2005) of sol–gel materials at the interface with biology. In the context of bioencapsulation in mineral hosts, novel synthetic approaches have been designed, allowing the immobilization of numerous proteins, enzymes and immune molecules as well as poly-sacch…
The title compound, [Cs(C12H24O6)]2[As2Se6], contains two independent centrosymmetric [As2Se6]2− counter-anions, in which AsSe3 pyramids are linked by two Se—Se bonds into a chair-shaped six-membered ring. Four of the Se atoms of the first [As2Se6]2− anion coordinate the Cs atoms of dimeric [{Cs(18-crown-6)}2(μ-As2Se6…
Abstract A series of extended 6‐substituted quinoxaline AB monomer mixtures, 2‐(4‐fluorophenyl)‐3‐[4‐(4‐hydroxyphenoxy)phenyl]‐6‐substituted quinoxaline and 3‐(4‐fluorophenyl)‐2‐[4‐(4‐hydroxyphenoxy)phenyl]‐6‐substituted quinoxaline, were prepared and polymerized to afford phenylquinoxaline oligomers. High‐molecular‐w…
Abstract In this study, Fourier‐transform Raman (FT‐RS) and infrared (FT‐IR) absorption spectroscopies were employed to characterize the molecular structures of L ‐Ala‐(3,4‐dimethoxy)‐ L ‐Phe‐PO 3 H 2 (A) and L ‐Ala‐(3,4‐dimethoxy)‐(des‐CH 2 )‐ L ‐Phe‐PO 3 H 2 (B) phosphonodipeptides, where L ‐Phe denotes L ‐phenylala…
Abstract Both linear and nonlinear viscoelastic properties of ionic polymer composites reinforced by soy protein isolate (SPI) were studied. Viscoelastic properties were related to the aggregate structure of fillers. The aggregate structure of SPI is consisted of submicron size of globule protein particles that form a…
The experimental data and theoretical views on the relations between the relaxation properties and structure of polymers are generalised. The attention is focused on the topological structural level, in particular, characteristics including the molecular mass, the molecular mass distribution, the degree of branching,…
Abstract The morphology of ionic aggregates in semicrystalline Zn‐ and Na‐neutralized poly(ethylene‐ ran ‐methacrylic acid) (EMAA) ionomer blown films has been explored with scanning transmission electron microscopy (STEM) and small angle X‐ray scattering. The ionic aggregates of Zn‐EMAA are spherical, monodisperse, a…
Abstract A boron‐containing styrenic monomer, 5‐benzyl‐2‐phenyl‐5‐(4‐vinylbenzyl)‐[1,3,2]‐dioxaborinane, was synthesized to study the influence of boron on the properties of the homopolymer and copolymer with styrene. A similar monomer without boron was also prepared and polymerized so that the properties of its polym…
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Field emission of carbon nanotubes (CNTs) grown on carbon cloth under various growth conditions has been studied. Iron sulfate or stainless steel was used as the catalyst, acetylene (C2H2) or methane (CH4) was used as the carbon source, and argon (Ar), hydrogen (H2), or ammonia (NH3) was used as the carrier gas. It is…
Abstract The fundamental components of Monte Carlo algorithms for the simulation of electron transport in matter are the differential and total cross sections for the relevant interaction mechanisms. We present different theoretical models and approximations to compute these cross sections for elastic scattering, inel…