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Studies on borate esters IV. Structural analysis of borate esters of polyhydroxycarboxylates in water using 13C and 1H NMR spectroscopys

Martin van Duin、Joop A. Peters、A. P. G. Kieboom 等 4 位作者1986-01-01Recueil des Travaux Chimiques des Pays-Bas

Abstract A combined 13 C and 1 H NMR study on borate esters of a series of polyhydroxycarboxylates is presented. 13 C substituent effects upon borate ester formation, as obtained from a set of model compounds, established that borate esters of the threo ‐3,4‐diol functions of gluconate, glucarate, idarate and probably…

biodegradable polymer synthesis and propertiesOrganoboron and organosilicon chemistrySynthetic Organic Chemistry Methods

Thermal decomposition of solid sodium bicarbonate

Matthew C. Ball、Christine M. Snelling、Alec N. Strachan 等 4 位作者1986-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The thermal decomposition of solid sodium bicarbonate has been studied in the temperature range 360–500 K over a range of partial pressures of carbon dioxide. The effect of water vapour has also been studied. Above 440 K the reaction follows contracting-cube kinetics with an activation energy of 32 kJ mol–1 and a freq…

Combustion and Detonation ProcessesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Scanning electron microscopy of uncoated fossils

Taylor, Paul D.1986-01-01Biodiversity Heritage Library (Smithsonian Institution)

(Uploaded by Plazi from the Biodiversity Heritage Library) No abstract provided.

Iron oxide chemistry and applicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Ecological studies on the littoral attaching micro-algae. VII. Adhesive strength of epiphytic diatoms on various seaweeds.

Nobuhiko Tanaka1986-01-01NIPPON SUISAN GAKKAISHI

Epiphytic diatoms on the natural seaweeds (seven brown-algae, two red-algae and one green alga) were fractionated by the five step separating treatments of shaking and rubbing. The order of adhesive strength of diatom species was determined from the recovery patterns of each diatom obtained through the five step separ…

Marine and coastal plant biologyMarine Biology and Ecology ResearchDiatoms and Algae Research

Inhibition of Pitting of Type 304L Stainless Steel by N‐Lauroylsarcosine

David W. DeBerry、Alfred Viehbeck1986-01-01Journal of The Electrochemical Society

The resistance of Type 304L SS to localized corrosion by aqueous chloride solutions is increased by addition of N‐lauroylsarcosine (NLS). The effects of N‐lauroylsarcosine concentration, chloride concentration, p H, and metal surface prepassivation on the efficiency of pitting inhibition were investigated. Linear curr…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Structural Study on the Cubic to Tetragonal Transformation in Arc-melted ZrO<SUB>2</SUB>-3 mol%Y<SUB>2</SUB>O<SUB>3</SUB>

M. Hayakawa、Mizuki Tada、Hiroshi Okamoto 等 4 位作者1986-01-01Transactions of the Japan Institute of Metals

A herringbone structure observed in an as arc-melted specimen was investigated using XRD, TEM and surface relief study. The specimen was cooled on a water cooled copper hearth and the grain size was approximately 1 mm. The results confirmed the crystal structure to be tetragonal (at=0.5100 and ct=0.5166 nm, c⁄a=1.0129…

Advanced ceramic materials synthesisAdvanced materials and compositesX-ray Diffraction in Crystallography

Properties of Mullite Powder Prepared by Coprecipitation and Microstructure of Fired Bodies

Kenya HAMANO、Takashi Satō、Zenbe-e NAKAGAWA1986-01-01Journal of the Ceramic Association Japan

A mullite powder was prepared from aluminum isopropoxide and methyl silicate by coprecipitation using a dilute ammonium aqueous solution. Properties and microstructure of fired bodies were examined. The results were compared with those from a sol mixture (SM) and oxide mixture (OX). The coprecipitated powder (Cp), the…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesIntermetallics and Advanced Alloy Properties

Mechanism for the Dehydroxylation of Kaolinite, Dickite, and Nacrite from Room Temperature to 455°C

P. R. Suitch1986-01-01Journal of the American Ceramic Society

The mechanism for the dehydroxylation of Keokuk kaolinite, dickite, and nacrite (Al 2 Si 2 O 5 (OH) 4 ) was investigated in detail with the aid of powder X‐ray diffraction, the Rietveld method, and infrared spectroscopy. It was determined that these polymorphic clay minerals dehydroxylate via an inhomogeneous mechanis…

Glass properties and applicationsCrystal Structures and PropertiesClay minerals and soil interactions

THE NUCLEATION OF MICROCELLULAR THERMOPLASTIC FOAM: PROCESS MODEL AND EXPERIMENTAL RESULTS

Jonathan S. Colton、Nam P. Suh1986-01-01Advanced Manufacturing Processes

Microcellular polymer foams exhibit greatly improved mechanical properties compared to standard foams due to the formers' small bubble size. Typical microcellular foams have bubbles with diameters on the order of 10 microns and volume reductions of 30 to 40%. The presence of these bubbles acts to increase the impact s…

Cellular and Composite StructuresAdditive Manufacturing and 3D Printing TechnologiesPolymer Foaming and Composites

Structure–magnetism correlation in dimeric copper( II ) carboxylates: crystal and molecular structure of tetra-µ-(propanoato-O,O′)-bis[aquacopper( II )]

L. P. BATTAGLIA、Anna Bonamartini Corradi、Ledi Menabue1986-01-01Journal of the Chemical Society Dalton Transactions

The dimeric copper(II) carboxylates [{Cu(O2CR)2(H2O)}2] and [{Cu(O2CR)2}2](R = Et or Prn) have been prepared and characterized by means of spectroscopic, magnetic, and thermogravimetric analyses. For [{Cu(O2CEt)2(H2O)}2] the crystal and molecular structure has also been determined. The crystals are monoclinic, space g…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Structural Investigation of Rapidly Quenched Li<sub>2</sub>O-B<sub>2</sub>O<sub>3</sub> Glasses by Raman Spectroscopy

Masahiro Tatsumisago、Masanari Takahashi、Tsutomu Minami 等 6 位作者1986-01-01Journal of the Ceramic Association Japan

Glasses were prepared over a wide range of composition in the system Li2O-B2O3 using a rapid quenching technique. The glass-forming region was extended up to the composition of 70mol% Li2O. Raman spectra of the glasses were measured; drastic spectral changes were observed in the glasses containing more than 50mol% Li2…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsChemical Synthesis and Characterization

Structural change of orthorhombic-Itridymite with temperature: A study based on second-order thermal-vibrational parameters

K. Kihara、Takeo MATSUMOTΟ、Moritaka Imamura1986-01-01Zeitschrift für Kristallographie

X-ray studies of orthorhombic- I tridymite, especially focussed on atomic mean-square displacements (m.s.d.'s) at 443, 493, 573, 653 and 693 K respectively, were carried out on the basis of the usual second-order refinement of the Dollase model. The m.s.d.'s for O are highly anisotropic, and large in the planes perpen…

Zeolite Catalysis and SynthesisThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Na5FeS4 – das erste Thioferrat(III) mit diskreten tetraedrischen Anionen

Kurt O. Klepp、W. Bronger1986-01-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Rubinrote Kristalle der Verbindung Na 5 FeS 4 lassen sich durch Umsetzung von Natriumsulfid mit Eisen und Schwefel bei 970 K darstellen. Röntgenographische Strukturuntersuchungen an einem Einkristall führten zu einer dem ternären Oxid Na 5 GaO 4 entsprechenden Atomanordnung [1]. Na 5 FeS 4 kristallisiert rhom…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsInorganic Chemistry and Materials

Collagen and Elastin Synthesis in Human Stroma and Breast Carcinoma Cell Lines: Modulation by the Extracellular Matrix

Richard T. Kao、Jackson Hall、Robert Stern1986-01-01Connective Tissue Research

The desmoplastic response to breast carcinoma is being studied. The stimulation of stromal cell proliferation by a preformed breast tumor matrix was shown. An additional mechanism for stimulating scleroprotein deposition is described here. On a per-cell basis, the synthesis of collagen and elastin was increased by 50%…

Cellular Mechanics and InteractionsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Charge-density wave transport

J. C. Gill、H. H. Wills1986-01-01Contemporary Physics

The unusual electrical properties of certain inorganic compounds which behave as quasi-one-dimensional metals are reviewed, with emphasis on the evidence which they provide for conduction by the cooperative mechanism, involving the motion of incommensurate charge-density waves (CDWs), first suggested by Frohlich (1954…

Mechanical and Optical ResonatorsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Particle-Initiated Breakdown Characteristics and Reliability Improvement in SF6 Gas Insulation

Masao Hosokawa、F. Endo、T. Yamagiwa 等 4 位作者1986-01-01IEEE Transactions on Power Delivery

Particle-initiated breakdown characteristics in SF6 gas are investigated. Breakdown voltages are greatly influenced by particle diameter especially for AC voltages, and for very fine metallic wire particles are much higher than those for moderately thick ones. The breakdown stress of a gas gap is obtained as a functio…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Ordered solution structure of a monodispersed polystyrene latex as studied by the transmitted light spectrum method

Tsuneo Okubo1986-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The microstructure of monodispersed polystyrene latices in deionized solution has been systematically investigated by the transmitted light spectrum method. Latices used are between 85 and 246 nm in diameter and the charge density of the latex surface is between 1.0 and 36 µC cm–2. Clear peaks showing the selective Br…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesMaterial Properties and Processing

Binuclear nickel( II ) and cobalt( II ) complexes of the novel binucleating ligand 3,6-bis(1′-pyrazolyl)pyridazine. Crystal and molecular structure and magnetism of bis[µ-3,6-bis(1′-pyrazolyl)pyridazine-N 1 (Ni 1 )N 2 ′(Ni 1 )N 2 (Ni 2 )N 2 ″(Ni 2 )]bis[diaquanickel( II )] tetrachloride dihydrate

Lisa Rosenberg、Laurence K. Thompson、Eric J. Gabe 等 4 位作者1986-01-01Journal of the Chemical Society Dalton Transactions

Reaction of the ligand 3,6-bis(1′-pyrazolyl)pyridazine (ppd) with nickel(II) and cobalt(II) salts produces binuclear derivatives in which the two pseudo-octahedral metal centres are bound simultaneously between two adjacent ligands in a doubly bridged structure. The complex [Ni2(ppd)2(H2O)4]Cl4·2H2O (1) crystallizes i…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Solidification Microstructure of Y<SUB>2</SUB>O<SUB>3</SUB>-Added Al<SUB>2</SUB>O<SUB>3</SUB>&ndash;ZrO<SUB>2</SUB> Eutectic

J. Echigoya、Y. Takabayashi、Keiichi Sasaki 等 5 位作者1986-01-01Transactions of the Japan Institute of Metals

The microstructure of the Al2O3–ZrO2 eutectic with addition of a small amount of Y2O3 has been studied. The eutectic composition was determined as 59 mol%Al2O3–36.8 mol%ZrO2–4.2 mol%Y2O3. The added Y2O3 (2.1–5.3 mol%) dissolved only in the ZrO2 phase and the crystal structure of this phase changed from monoclinic to t…

Advanced ceramic materials synthesisGlass properties and applicationsNuclear materials and radiation effects